• 한국분무공학회지
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• 제7권3호
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• pp.7-11
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• 2002

Comparison of the combustion characteristics of methane-air and gasoline-air mixtures has been conducted experimentally by a spherical bomb technique. The results indicate 1) the burning velocity of gasoline is slightly higher than that of methane, but their basic behavior of combustion characteristics, positive dependence on temperature and negative one on pressure, are the same, and 2) 20 vol.% addition of hydrogen to methane enhances the burning velocity by about 30%, but does not come to reverse the tendency of pressure dependence to that of pure hydrogen.

• 한국자동차공학회논문집
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• 제4권4호
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• pp.201-209
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• 1996

This study describes the combustion characteristics of methance-air mixture with various equivalence retio and initial conditions of mixture in constant volume combustion chamber. Combustion characteristics of methane-air mixture such as combustion pressure, combustion temperature, and heat release were investigated by the measurement of combustion pressure and temperature in the combustion chamber. The results show that maximum combustion pressure, gas temperature and rate of heat release have peaks at equivalence ratio of 1.1. Combustion duration is also the shortest at the equivalence ratio of 1.1 and it is shortened as initial mixture temperature increases.

• 에너지공학
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• 제12권2호
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• pp.124-130
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• 2003

본 연구에서는 정적연소실을 이용하여 차량용 대체연료로써 메탄 및 수소첨가 메탄의 연소특성을 수소첨가율, 점화위치 및 점화방법에 따라 고찰하였다. 그 결과 연소효율, 최고연소압력 등과 같은 연소특성을 악화시키지 않고 희박 혼합기 조건하에서도 MSCDI 장치 사용에 의해 전 연소시간과 NO 농도를 저감시킬 수 있었다. 또한, 수소를 천연가스의 주 성분인 메탄에 혼합함에 따라 전 연소시간은 순수 메탄만을 사용할 때에 비해 단축되었으며, 이와 동시에 연소촉진율도 순수 메탄만을 사용하였을 때에 비해 상당히 향상되었다.

• 한국응용과학기술학회지
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• 제24권1호
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• pp.67-73
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• 2007

Methane combustion over perovskite catalysts was investigated. For the preparation of catalysts, Co, Mn, Fe, and Ni were used as B-site components of the perovskite catalysts $(ABO_3)$ and La was used as A-site component. The effect of calcination temperature on methane combustion and perovskite structure was also investigated. The structure of perovskites, surface area, and adsorbed oxygen species were tested with XRD, BET apparatus, and $O_2-TPD$, respectively. The formation of perovskite structure was affected by the calcination temperature. The catalyst desorbing oxygen at a lower temperature showed better activity for the methane combustion, therefore, the oxygen species desorbing at lower temperatures is responsible for the methane combustion.

• 한국자동차공학회논문집
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• 제3권3호
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• pp.129-139
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• 1995

This study investigates the combustion characteristics of methane-hydrogen-air premixture in a constant volume combustion chamber. Primary factors of the combustion characteristics of methane- hydrogen-air premixture are the equivalence ratio and hydrogen supplement rate. In the case of $\phi$= 1.1, maximum combustion pressure and heat release rate have peaks, and they increase as the initial pressure and hydrogen supplement rate increase. The total burning time is also the shortest at the $\phi$= 1.1, it shorten by lowering the initial pressure and by increasing the hydrogen supplement rate. The maximum flame temperature is shown at the $\phi$= 1.0, and increasing the initial pressure and hydrogen supplement rate, it increases. The concentration of NO reveals the highest value at the $\phi$= 0.9, and it increases by increasing the initial pressure and hydrogen supplement rate. It is also found that the limit of lean inflammability of methane-hydrogen-air premixture is greatly widened by increasing the hydrogen supplement rate.

• 한국자동차공학회논문집
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• 제11권4호
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• pp.29-36
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• 2003

A cylindrical constant volume combustion chamber was used to investigate the flow characteristics at spark plug and the combustion characteristics of inhomogeneous charge methane-air mixture under several parameters. The flow characteristics such as mean velocity and turbulence intensity was analyzed by hot wire anemometer. Combustion pressure development measured by piezoelectric pressure transducer was used to investigate the effect of initial charge pressure, excess air ratio and ignition times on combustion pressure and combustion duration. Mean velocity and turbulence intensity had the maximum value at 200 or 300ms and then decreased to beneath 0.05m/s gradually at 3 seconds. Second mixture is accompanied by an increase in the combustion rate, and that the higher the mass which is added in the second stage injection, the faster the burn rate.

• 한국자동차공학회논문집
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• 제17권5호
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• pp.46-52
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• 2009

In this study the predictions of NOx in methane-air lean premixed combustion in PSR were carried out with GRI 3.0 methane-air combustion mechanism and Zeldovich, nitrous oxide, prompt, and NNH NO formation mechanism by using CHEMKIN code. The results are compared to the JSR experimental data of Rutar for the validation of the model. This study concerns about the importance of the chemical pathways. The chemical pathway most likely to form the NO in methane-air lean-premixed combustion was investigated. The results obtained with the 4 different NO mechanisms for residence time(0.5-1.6ms) and pressure(3, 4.7, 6.5 atm) are compared and discussed.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2014년도 제49회 KOSCO SYMPOSIUM 초록집
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• pp.387-389
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• 2014

Laminar lifted methane jet flame diluted with nitrogen and helium in co-flow air has been investigated experimentally. This paper examines the role of chemistry, intermediate species responsible for stabilization of lifted flame. To elucidate the stabilization mechanism in lifted methane jet flames with Sc<1, the chemiluminescence intensities of $CH^*$ and $OH^*$ were measured using ICCD camera at various nozzle exit velocities and fuel mole fractions. It has been observed that the $OH^*$ species can play an important role in stabilization of lifted methane jet flame as they are good indicators of heat release rate which can affect on flame speed and increase stability through reduction in ignition delay time.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2014년도 제49회 KOSCO SYMPOSIUM 초록집
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• pp.125-128
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• 2014

Laminar lifted methane jet flame diluted with nitrogen and helium in co-flow air has been investigated experimentally. This paper examines the role of chemistry, intermediate species responsible for stabilization of lifted flame. To elucidate the stabilization mechanism in lifted methane jet flames with Sc<1, the chemiluminescence intensities of $CH^*$ and $OH^*$ were measured using ICCD camera at various nozzle exit velocities and fuel mole fractions. It has been observed that the $OH^*$ species can play an important role in stabilization of lifted methane jet flame as they are good indicators of heat release rate which can affect on flame speed and increase stability through reduction in ignition delay time.

• 한국자동차공학회논문집
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• 제11권3호
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• pp.48-57
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• 2003

A cylindrical constant volume combustion chamber was used to investigate the flow characteristics at spark plug and the combustion characteristics of homogeneous charge methane-air mixture under various initial pressure, excess air ratio and ignition times in quiescent mixture. The flow characteristics such as mean velocity and turbulence intensity was analyzed by hot wire anemometer. Combustion pressure development measured by piezoelectric pressure transducer and flame propagation acquired by ICCD camera were used to investigate the effect of initial pressure, excess air ratio and ignition times on pressure, combustion duration, flame speed and burning velocity. Mean velocity and turbulence intensity had the maximum value at 200 or 300ms and then decreased to near 0 value gradually after 3 seconds. Combustion duration, flame speed and burning velocity were observed to be promoted with excess air ratio of 1.1, lower initial pressure and ignition time of 300ms.