• International Journal of Safety
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• v.2 no.1
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• pp.7-11
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• 2003

Structure of the counterflow nonpremixed flames were investigated by using Fire Dynamics Simulator(FDS) and OPPDIF to evaluate FDS for simulations of the diffusion flame. FDS, employed a mixture fraction formulation, were applied to the diluted axisymmetric methane-air nonpremixed counterflow flames. Fuel concentration in the mixture of methane and nitrogen was considered as a numerical parameter in the range from 20% to 100% increasing by 10% by volume at the global strain rates of $a_g = 20S^{-l} and 80S^{-1}$ respectively. In all the computations, the gravity was set to zero since OPPDIF is not able to compute the buoyancy effects. It was shown by the axisymmetric simulation of the flames with FDS that increasing fuel concentration increases the flame thickness and decreases the flame radius. The centerline temperature and axial velocity, and the peek flame temperature showed good agreement between the both methods.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.23 no.10
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• pp.1248-1253
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• 1999

This study is concerned about the combustion characteristics of methane-air and methane/hydrogen-air mainly the behavior of burning velocity including the effect of the ignition energy. The experiments were conducted in a spherical combustion bomb designed in this laboratory. The burning velocities were measured by the pressure-time history and the reaction rates were estimated theoretically. The experimental results showed that the burning velocity increased by 25 to 50 percent when hydrogen is added to methane by 20 percent.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.31 no.4
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• pp.384-391
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• 2007

Hydrogen-blending effects in flame structure and NO emission behavior are numerically studied with detailed chemistry in methane-air counterflow diffusion flames. The composition of fuel is systematically changed from pure methane to the blending fuel of methane-hydrogen through $H_2$ molar addition up to 30%. Flame structure, which can be described representatively as a fuel consumption layer and a $H_2$-CO consumption layer, is shown to be changed considerably in hydrogen-blending methane flames, compared to pure methane flames. The differences are displayed through maximum flame temperature, the overlap of fuel and oxygen, and the behaviors of the production rates of major species. Hydrogen-blending into hydrocarbon fuel can be a promising technology to reduce both the CO and $CO_2$ emissions supposing that NOx emission should be reduced through some technologies in industrial burners. These drastic changes of flame structure affect NO emission behavior considerably. The changes of thermal NO and prompt NO are also provided according to hydrogen-blending. Importantly contributing reaction steps to prompt NO are addressed in pure methane and hydrogen-blending methane flames.

• Transactions of the Korean Society of Mechanical Engineers
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• v.19 no.5
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• pp.1333-1339
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• 1995

Recently developed technique of measuring minor species concentration by using the modulation dip in broadband CARS has been applied to the flame structure study of methane/air premixed flames in a counterflow. This method used the modulation dip from the cold band CO Q-branch resonant signal superimposed on the nonresonant background. The measured CO concentration profile in a symmetric and unsymmetric methane/air premixed flames together with the velocity and temperature by using LDV and CARS have been compared with the numerical results adopting detailed chemistry modeling. The results show that there is a satisfactory agreement between the experimental data and numerical results for velocities, temperatures and CO concentrations. And the modulation dip technique of measuring minor species, such as CO is a viable tool for a quantitative measurement in a flame.

• Transactions of the Korean Society of Automotive Engineers
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• v.4 no.3
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• pp.156-167
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• 1996

The present work is a continuation of our previous study to investigate the effects of parameters such as equivalence ratio, hydrogen supplement rate and initial pressure on combustion characteristics in a disk-shaped constant volume combustion chamber. The main results obtained from the study can be summarized as follows. The flames in near stoichiometric mixture of methane-air are propagated with a spherical shape, but in excess rich or lean mixtures are propagated with a elliptical shape. And, they are changed to an unstable elliptical shape flame with very regular cells by increasing the hydrogen supplement rate. Also, flame is sluggishly propagated at increased initial pressure in combustion chamber. Volume fraction of burned gas and flame radius as the combustion characteristics are increased by increasing the hydrogen supplement rate, especially at the combustion middle period, but then are slowly increased by increasing the initial pressure.

• Transactions of the Korean hydrogen and new energy society
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• v.34 no.1
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• pp.38-46
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• 2023

Carbon neutrality policies have been strengthened to reduce emissions, and the importance of technology road maps has been emphasized. In the global industrial boiler market, carbon neutrality is implemented through fuel diversification of methane-hydrogen mixture gas. However, various problems such as flashback and flame unstability arise. There is a limit to implementing the actual system as it remains in the early stage. Therefore, it is necessary to secure the source technology of methane-hydrogen hybrid combustion system applicable to industrial fields. In this study, control program for methane-hydrogen fuel conversion was developed to expect various parameters. After determining the hydrogen mixing ratio and the input air flow, the fuel conversion control algorithm was constructed to get the parameters that achieve the target oxygen concentration in the exhaust gas. LabVIEW program was used to derive correlations among hydrogen mixing rate, oxygen concentration in exhaust gas, input amount of air and heating value.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.23 no.4
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• pp.259-264
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• 2011

Gas hydrate is formed by physical binding between water molecule and gas such as methane, ethane, propane, or carbon dioxide, etc., which is captured in the cavities of water molecule under the specific temperature and pressure. $1\;m^3$ hydrate of pure methane can be decomposed to the methane gas of $172\;m^3$ and water of $0.8\;m^3$ at standard condition. If this characteristic of hydrate is reversely utilized, natural gas is fixed into water in the form of hydrate solid. Therefore, the hydrate is considered to be a great way to transport and store of natural gas in large quantity. Especially the transportation cost is known to be 18~25% less than the liquefied transportation. However, when methane gas hydrate is artificially formed, its reaction time may be too long and the gas consumption in water becomes relatively low, because the reaction rate between water and gas is low. Therefore, for the practical purpose in the application, the present investigation focuses on the rapid production of hydrates and the increment of the amount of captured gas by adding zeolite into pure water. The results show that when the zeolite of 0.01 wt% was added to distilled water, the amount of captured gas during the formation of methane hydrate was about 4.5 times higher than that in distilled water, and the methane hydrate formation time decreased at the same subcooling temperature.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.14 no.10
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• pp.863-870
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• 2002

Fossil fuels have been depleted gradually and new energy resource which can solve this shortage is needed now. Methane hydrate, non-polluting new energy resource, satisfies this requirement and considered the precious resource prevent the global warming. Fortunately, there are abundant resources of methane hydrate distribute in the earth widely, so developing the techniques that can use these gases effectively is fully valuable. the work presented here is to develop the skill which can transport and store methane hydrate. As a first step, the equilibrium point experiment has been carried out by increasing temperatures in the cell at fixed pressures. The influence of gas consumption rates under variable degree of subcooling, stirring and water injection has been investigated formation to find out kinetic characteristics of the hydrate. The results of present investigation show that the enhancements of the hydrate formation in terms of the gas/water ratio are closely related to operational pressure, temperature, degrees of subcooling, stirring rate, and water injection.

• Transactions of the Korean Society of Automotive Engineers
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• v.8 no.1
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• pp.92-100
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• 2000

The model gas reaction tests were carried out to investigate the purification characteristics of methane on the exclusive catalyst for NGV. The experiment was conducted with the factors which affect the conversion efficiency of methane, such as Redox ratio, coexistence components of CO, MO, $H_2$O, precious metals and additives. The catalyst loaded with larger amount of pd and with additive La showed lower light-off temperature. In the presence of CO and NO, the conversion efficiency of methane was varied according to the kind of additive loaded. The conversion efficiency of methane was dropped for the catalyst loaded with La under lean air-fuel ratio, while it increased for the one loaded with Ti+Zr for the same condition. It was shown that the water vapor inhibited methane from oxidation by its poisoning on the surface of catalyst.

• Journal of the Korean Institute of Gas
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• v.1 no.1
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• pp.106-112
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• 1997

This study measured the ignition limits of methane-air, propane-air, ethylene-air, and hydrogen-air mixture gases by discharge spark of D.C. power resistive circuit. The used experimental device is the IEC type spark ignition test apparatus, it consists of explosion chamber and supply -exhaust system of mixture gas. Mixture gases (methane-air, propane-air, ethylene-air, and hydrogen-air) were put into explosion chamber of IEC type spark ignition test apparatus, then it was confirmed whether ignition was made by 3,200 times of discharge spark between tungsten electrode and cadmium electrode. The ignition limits were found by increasing or decreasing the value of current. For the exact experiment, the ignition sensitivity was calibrated before and after the experiment in each condition. The ignition limits were found by changing the value of concentration of each gas-air mixture in D.C. 24 [V] resistive circuit. As the result of experiment, it was found that the minimum ignition limit currents exist at the value of methane-air 8.3 [$Vol\%$], propane-air 5.25[$Vol\%$], ethylene-air 7.8 [$Vol\%$], and hydrogen-air 21[$Vol\%$] mixture gases. For each the minimum ignition concentration of gases, the relationships between voltage and minimum ignition current were found. The results are as follows. - The minimum ignition limits are decreasing in the order of methane, propane, ethylene, and hydrogen. - The value of ignition current is inversely proportional to the value of source voltage. - The minimum ignition limit currents increase sharply at more than 2 [A]. The reason is caused by overheating the electrode.