• 대한의용생체공학회:의공학회지
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• 제17권2호
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• pp.247-254
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• 1996

The relationship between the isothermal age-hardening behavior and the phase transformation in the commercial dental Au-Ag-Cu-Pd alloy was investigated Age-hardening was mostly attributed to the lattice distortions of the supersaturated w phase resulting from the transformation to the metastable phasel which were more distinct at lower aging temperature. The lattice distortions resulting from the transformation of the metastable phases to the equilibrium phases also made a contribution to the age-hardening.

• 한국세라믹학회지
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• 제19권1호
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• pp.13-18
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• 1982

The crystallization of metastable "orthorhombic" phase from the glass in the system of Na $AlSi_3O_8-CaAl_2Si_2O_8$ is studied. These crystals are crystallized in the range of composition from $Ab_80An_20$ to An100. The symmetry of these crystals show orthorhombic as a possible space group P22121. Two probable twin models are proposed. proposed.

• EDISON SW 활용 경진대회 논문집
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• 제6회(2017년)
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• pp.417-423
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• 2017

Monolayer $MoS_2$의 metastable phase인 T' phase가 stable한 H phase보다 안정해지는 조건을 모색하기 위해 substitutional doping을 했을 때와 strain을 걸어주었을 때의 에너지 차이를 DFT 방법으로 계산하였다. Doping을 했을 때와 strain이 있을 때 T' phase와 H phase의 에너지 차이가 감소함을 확인하였으나 H phase보다 T' phase가 안정해지는 조건을 찾지는 못하였다. 하지만 이 방법을 기존의 alkali adsorption 방법과 병행하여 기존 방법의 단점을 보완할 수 있을 것을 기대해 볼 수 있다. 또한 전자구조 분석 중 얻은 dopant의 주기와 족에 따른 경향성은 다른 TMD 물질의 phase engineering을 design할 때 universal한 design rule로서 응용할 수 있음을 기대해 볼 수 있다.

• Bulletin of the Korean Chemical Society
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• 제18권12호
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• pp.1285-1288
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• 1997

The graphite tube nozzle has been developed for the generation of metastable He jet by which the nitrogen molecules initially excited in a jet with Engelking type nozzle have been further excited in a corona excited supersonic expansion. The excitation process of nitrogen molecules in the jet collision has been discussed in detail by observing the emission intensity from the vibronic emission spectra of nitrogen molecules and nitrogen molecular ions upon helium jet collision.

• 한국결정학회지
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• 제1권1호
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• pp.49-56
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• 1990

Albite-anorthite 계의 조성을 갖는 유리를 결정화 시키면 사장석의 공융상 외에도 육방정과 사방정의 두불안정상이 정출되며 이들의 결정화도를 X-선 회절에 의하여 측정하였다. 사방정의 불안 정상은 albite 70∼80%를 갖는 조성에서 가장 많이 결정화가 일어나며 육방정은 anorthite가 주로된 조성영역에서 결정화가 많이 일어났다. 불안정상 중에서 사방정의 걱정구조를 정산하기 위하여 Nao7 Cao.3 Al13 Si27 O7의 조성을 갖는 단결정편을 분리하여 X-선 회절강도를 측정하였다. 이 결정의 격자상수는 a=8.237(1)A. b=8.644(1)A c=4.818(1)A이며 공간군은 P22,2,이다. 최종정산한 구조의 R값은 0.040이었고 Rw는 0.028이었다. 한위치를 7 3의 비율로 통계적으로 차지하고 있는 Na와 Ca의 위치는 충진율 0.5를 가지며 두 위치로 분열되어 있다. Si가 A1원자는 육환구조내에서는 통계적으로 분포되어 있고 육환층과 층사이에서는 규칙적인 배열을 보이고 있다.

• 한국분말재료학회지
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• 제26권2호
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• pp.146-155
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• 2019

Rare earth magnets are the strongest type of permanent magnets and are integral to the high tech industry, particularly in clean energies, such as electric vehicle motors and wind turbine generators. However, the cost of rare earth materials and the imbalance in supply and demand still remain big problems to solve for permanent magnet related industries. Thus, a magnet with abundant elements and moderate magnetic performance is required to replace rare-earth magnets. Recently, $a^{{\prime}{\prime}}-Fe_{16}N_2$ has attracted considerable attention as a promising candidate for next-generation non-rare-earth permanent magnets due to its gigantic magnetization (3.23 T). Also, metastable $a^{{\prime}{\prime}}-Fe_{16}N_2$ exhibits high tetragonality (c/a = 1.1) by interstitial introduction of N atoms, leading to a high magnetocrystalline anisotropy constant ($K_1=1.0MJ/m^3$). In addition, Fe has a large amount of reserves on the Earth compared to other magnetic materials, leading to low cost of raw materials and manufacturing for industrial production. In this paper, we review the synthetic methods of metastable $a^{{\prime}{\prime}}-Fe_{16}N_2$ with film, powder and bulk form and discuss the approaches to enhance magnetocrystalline anisotropy of $a^{{\prime}{\prime}}-Fe_{16}N_2$. Future research prospects are also offered with patent trends observed thus far.

• 한국주조공학회지
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• 제8권4호
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• pp.446-452
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• 1988

To obtain detailed information on the metastable and the equilibrium phases in rapidly solidified Al-(Fe,Ce) alloys, analysis of X-ray diffraction pattern has been carried out. It has been found that the metastable phase formed in Al-Fe alloys including up to 6wt%Fe is $Al_6Fe$ and the equilibrium phase is $Al_3Fe$. Any X-ray diffraction peak corresponding to the equilibrium phase $Al_{13}Fe_4$ has not been observed during aging. In Al-4wt%Fe alloy, which is ribbon shape with thickness less than $70\;{\mu}m$, aged at $400^{\circ}C$ for 1h after rapid solidification, unidentified phase has been found. In Al-4wt%Ce alloy, only X-ray diffraction peak corresponding to the equilibrium phase, $Al_4Ce$ has been observed. It has been found that the metastable phase Formed in Al-Fe-Ce alloys including up to 6wt% Fe and 4wt% Ce is $Al_6Fe$ and the equilibrium phases are $Al_3Fe$ and $Al_{10}CeFe_2$.

• 한국분말재료학회지
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• 제12권1호
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• pp.36-42
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• 2005

Four different mechanical alloying(MA) processes were employed to fabricate very fine intermetallic compound $Al_3Zr$ particles dispersed Al composite materials(MMC) with Al-4at.%Zr composition. Phase transformations including phase stability during MA and heat treatment processes were investigated. Part of Zr atoms were dissolved into Al matrix and part of them reacted with hydrogen produced by decomposition of PCA(methanol) to form hydride $ZrH_2$ during first MA process. These $ZrH_2$ hydrides disappeared when alloy powders were heat treated at $500^{\circC}$. Stable $Al_3Zr$ dispersoids with $DO_23$ structure were formed by heat treating the mechanically alloyed powders at $400^{\circC}$. On the other hand, metastable $Al_3Zr$dispersoids with $L1_2$ structure were formed during first MA of powers with Al-25at.%Zr composition. These metastable $Al_3Zr$ dispersoids transformed to stable $Al_3Zr$ with $DO_23$ structure when heat treated above $450^{\circC}$.

• 전기학회논문지P
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• 제57권2호
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• pp.79-83
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• 2008

In this paper, we introduced a LIF measurement method and summarized the theoretical side. When an altered wavelength of laser and electric power, lamp applied electric power, we measured the relative density of the metastable state in mercury after observing a laser induced fluorescence signal of 404.8nm and 546.2nm, and confirmed the horizontal distribution of plasma density in the discharge lamp. Due to this generation, the extinction of atoms in a metastable state occurred through collision, ionization, and excitation between plasma particles. The density and distribution of the metastable state depended on the energy and density of plasma particles, intensely. This highlights the importance of measuring density distribution in plasma electric discharge mechanism study. The results confirmed the resonance phenomenon regarding the energy level of atoms along a wavelength. change, and also confirmed that the largest fluorescent signal in 436nm, and that the density of atoms in 546.2nm ($6^3S_1{\to}6^3P_2$) were larger than 404.8nm ($6^3S_1{\to}6^3P_2$). According to the increase of lamp applied electric power, plasma density increased, too. When increased with laser electric power, the LIF signal reached a saturation state in more than 2.6mJ. When partial plasma density distribution along a horizontal axis was measured using the laser induced fluorescence method, the density decreased by recombination away from the center.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2000년도 제18회 학술발표회 논문개요집
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• pp.147-147
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• 2000

Chemisorption of oxygen molecules on the Si(111)-(7x7) surface has been studied extensively as a model for the initial-stage oxidation of the surface. The basic step to the surface oxidation is the dissociation of the adsorbed O2 molecules, but the dissociation procedure and the atomic structure of the reaction products still remains as a subject of debates. We present here density-functional theory calculations on the initial-stage oxidation states of the Si adatom site for all possible dissociation configurations that can be generated by multiple O2 reactions. We determine the equilibrium structures and analyze their electronic and vibrational properties in comparison with measured UPS, XPS, and EELS spectra. The O(ad) atom bonded on top of the Si adatom is always less stable than the O(ins) atom inserted into one of the adatom backbonds. Our electronic and vibrational analysis demonstrates further that the O(ad) and O(ins) atoms account well for the metastable and stable features in previous experiments, respectively. Moreover, the calculated decay pathways of the metastable structures and the comparison of the calculated O ls core-level shifts with XPS data provides a convincing argument in unambiguously identifying the experimental metastable and stable structures, thereby making it possible to build a correct atomic-scale picture of the initial-stage oxidation process on this surface.