• Journal of Korea Foundry Society
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• v.16 no.2
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• pp.149-157
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• 1996

Several aluminum based alloys were fabricated by a twin roll strip casting mill. As-cast microstructures and microsegregations of these aluminum alloys were investigated by means of optical microscope, scanning electron microscope and electron probe micro analysis. Clear distinction on microsegregation among the alloy systems was observed, that is, A1235 and A8011 alloys showed diffused segregation in the middle of the strip, while A3003 and A5086 alloys revealed a centerline segregation consisted of lamellar structure. Above center line segregation was resulted from enrichment of the alloying elements such as Mn, Fe, Cu, Si and eutictic reaction in central region of the alloy strip.

• Korean Journal of Materials Research
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• v.24 no.4
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• pp.175-179
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• 2014

Ti and Ti alloys have been extensively used in the medical and dental fields because of their good corrosion resistance, high strength to density ratio and especially, their low elastic modulus compared to other metallic materials. Recent trends in biomaterials research have focused on development of metallic alloys with elastic modulus similar to natural bone, however, many candidate materials also contain toxic elements that would be biologically harmful. In this study, new Ti based alloys which do not contain the toxic metallic components were developed using a theoretical method (DV-$X{\alpha}$). In addition, alloys were developed with improved mechanical properties and corrosion resistance. Ternary Ti-Ag-Zr alloys consisting of biocompatible alloying elements were produced to investigate the alloying effect on microstructure, corrosion resistance, mechanical properties and biocompatibility. The effects of various contents of Zr on the mechanical properties and biocompatibility were compared. The alloys exhibited higher strength and corrosion resistance than pure Ti, had antibacterial properties, and were not observed to be cytotoxic. Of the designed alloys' mechanical properties and biocompatibility, the Ti-3Ag-0.5Zr alloy had the best results.

• Korean Journal of Metals and Materials
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• v.49 no.9
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• pp.739-745
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• 2011

Beta-type alloys are the most versatile class of titanium alloys. They offer the highest strength to weight ratios and very attractive combinations of strength, toughness, and fatigue resistance inlarge cross sections [1]. The present study was made to obtain useful information for the design of ${\beta}$-type titanium alloys with high-strength properties by using the $DV-X{\alpha}$ method. Employing two calculated parameters, the bond order (Bo) and the d-orbital energy level (Md) of alloying elements in ${\beta}$-type titanium alloy was introduced and used for prediction of mechanical properties. Thus, high-strength titanium alloys were designed by calculating the Md and Bo values of the previous and present titanium alloys.

• Korean Journal of Metals and Materials
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• v.48 no.10
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• pp.936-941
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• 2010

Al-Zn based alloys are the most common types of wrought Al alloys. Although Al-Zn alloys have high strength, they cannot be applied to a conventional casting process. In this study, Al-Zn-based alloys applicable to a die casting process were developed successfully. The developed Al-45 wt% Zn-based alloys showed a fine equiaxed grain structure and high strength. A fine equiaxed grain having an average size of $25{\mu}m$ was obtained by the die casting process. The UTS and elongation of the new alloy are 475 MPa and ~3.5%, respectively. In addition, we elucidate the effect of a Zn addition on variations in different mechanical properties and the microstructure characteristics of (Al96.3-xZnxCu3Si0.4Fe0.3) x=20, 30, 40, and 45 wt% alloys fabricated by a die casting process.

• Nuclear Engineering and Technology
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• v.47 no.3
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• pp.323-331
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• 2015

Zirconium alloys are widely used in nuclear reactors as structural materials. During the operation, they are exposed to fast neutrons. Ion irradiation is used to simulate the damage introduced by neutron irradiation. In this article, we briefly review the neutron irradiation damage of zirconium alloys, then summarize the effect of ion irradiation on microstructural evolution, mechanical and corrosion properties, and their relationships. The microstructure components consist of dislocation loops, second phase precipitates, and gas bubbles. The microstructure parameters are also included such as domain size and microstrain determined by X-ray diffraction and the S-parameter determined by positron annihilation. Understanding the relationships of microstructure and properties is necessary for developing new advanced materials with higher irradiation tolerance.

• Journal of the Korean Physical Society
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• v.73 no.9
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• pp.1370-1376
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• 2018

The electronic structures, magnetic properties and half-metallicity in $Zr_2RuZ$ (Z = Ga, In, Tl, Ge, Sn, and Pb) alloys with $AlCu_2Mn-$ and $CuHg_2Ti$-type structures were investigated using first-principles density functional theory (DFT) calculations. The calculations showed that $Zr_2RuIn$, $Zr_2RuTl$, $Zr_2RuSn$, and $Zr_2RuPb$ compounds with $CuHg_2Ti$-type structures were half-metallic ferromagnets with half-metallic band gaps of 0.18, 0.24, 0.22, and 0.27 eV, respectively. The half-metallicity originated from d-d and covalent hybridizations between the transition metals Zr and Ru. The total magnetic moments of the $Zr_2RuZ$ (Z = In, Tl, Sn, and Pb) compounds with $CuHg_2Ti$-type structures were integer values of $1{\mu}B$ and $2{\mu}B$, which is in agreement with Slater-Pauling rule ($M_{tot}=Z_{tot}-18$). Among these compounds, $Zr_2RuIn$ and $Zr_2RuTl$ were half-metals over relatively wide regions of the lattice constants, indicating that these two new Heusler alloys are ideal candidates for use in spintronic devices.

• Corrosion Science and Technology
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• v.2 no.1
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• pp.30-35
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• 2003

In this study, sand cast AZ91E and zirconium grain refined MEZ are representative of two typical groups of magnesium alloys: those containing aluminium and those containing no aluminium but with zirconium as a grain refiner. The corrosion performance of these two alloys was evaluated and compared in 5%wt NaCI solution through measurements of weight loss and polarisation curves and examination of microstructure. Corrosion damage of AZ91E was deeper and more localised than that of MEZ, while MEZ had a lower rate of cathodic hydrogen evolution and a higher rate of anodic dissolution than AZ91E. These differences in behaviour can be related to the differences in microstructure and chemical composition between the two alloys.

• Korean Journal of Metals and Materials
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• v.47 no.11
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• pp.773-785
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• 2009

Studies of a number of Cu-Zr amorphous alloys have demonstrated that those exhibiting greater plastic strain during homogeneous deformation at room temperature show lower global plasticity associated with inhomogeneous deformation in a typical compression test. Using a combination of experiments and molecular dynamics simulations, we clarify this seeming paradox between the homogeneous and inhomogeneous deformation by exploring the microstructural aspects in view of the structural disordering, disorder-induced softening, and shear localization and relate these findings to the global plasticity of bulk amorphous alloys. Additional analyses were conducted to derive a simple structural parameter that allows the prediction of the global plasticity of bulk amorphous alloys.

• Korean Journal of Metals and Materials
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• v.46 no.9
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• pp.572-576
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• 2008

Elastostatic compression tests were carried out on amorphous alloys to evaluate their energy absorption capability during homogeneous deformation at room temperature. Experiments demonstrated that a compressive stress below the global yield imposed on amorphous alloys for extended periods causes homogeneous plastic strain associated with the irreversible structural disordering. During the disordering process, free volume was created, dissipating the externally applied strain energy and the rate of creation was found to converge to a saturated value. We evaluated the capability of energy absorption of amorphous alloys during homogeneous deformation using recent theories on the evolution of the structural state.

• Analytical Science and Technology
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• v.7 no.4
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• pp.517-526
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• 1994

Large insoluble phases and dispersoids in Al-Li-Cu-Mg-Mn-Zr alloys containing Mn were analyzed with EPMA(Electron Probe Microanalyzer) and SAEM(Scanning Auger Electron Microscope). Morphology, distribution and volume fraction of the large insoluble phase were also analyzed quantitatively by optical microscopy. Mechanical properties were tested at room temperature and at $200^{\circ}C$. With increasing Mn contents, the volume fraction of the large insoluble phases increased steeply, thus decreasing ductility. Mn was found to be very effective for obtaing uniformly distributed fine-grain structures. The alloy containing 0.44 wt% Mn showed the highest tensile strength among Mn-bearing alloys tested.