• Journal of the Korean Society for Heat Treatment
• /
• v.34 no.1
• /
• pp.10-16
• /
• 2021

Exhaust manifold is a very important component that is directly connected to air environment pollution and that requires strict mechanical properties such as high temperature fatigue and oxidation. Among stainless steels, the ferritic stainless steel with body-centered cubic structure shows excellent resistance of stress-corrosion cracking, ferromagnetic at room temperature, very excellent cold workability and may not be enhanced by heat treatment. The microstructural characteristics of four cast ferritic stainless steels which are high heat-resistant materials, were analyzed. By comparing and evaluating the mechanical properties at room temperature and high temperature in a range of 400℃~800℃, a database was established to control and predict the required properties and the mechanical properties of the final product. The precipitates of cast ferritic stainless steels were analyzed and the high-temperature deformation characteristics were evaluated by comparative analysis of hardness and tensile characteristics of four steels at room temperature and from 400℃ to 800℃.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.35 no.5
• /
• pp.419-430
• /
• 2022

Defects in solids play a vital role on thermoelectric properties through the direct impacts of electronic band structure and electron/phonon transports, which can improve the electronic and thermal properties of a given thermoelectric semiconductor. Defects in semiconductors can be divided into four different types depending on their geometric dimensions, and thus understanding the effects on thermoelectric properties of each type is of a vital importance. This paper reviews the recent advances in the various thermoelectric semiconductors through defect engineering focusing on the charge carrier and phonon behaviors. First, we clarify and summarize each type of defects in thermoelectric semiconductors. Then, we review the recent achievements in thermoelectric properties by applying defect engineering when introducing defects into semiconductor lattices. This paper ends with a brief discussion on the challenges and future directions of defect engineering in the thermoelectric field.

• Journal of the Korean Society for Precision Engineering
• /
• v.14 no.9
• /
• pp.90-100
• /
• 1997

A full three-dimensional thermo-coupled rigid-viscoplastic finite element method and the currently developed microstructural evolution system which includes semi-empirical equations suggested by different research groups were used together to form an integrated system of process and micro- structure simulation of hot rolling. The distribution and time histroy of the momechanical variables such as temperature, strain, strain rate, and time during pass and between passes were obtained from the finite element analysis of multipass hot rolling processes. The distribution of metallurgical variables were calculated on the basis of instantaneous thermomechanical data. For the verification of this method the evolution of microstructure in plate rolling and shape rolling was simulated and their results were compared with the data available in the literature. Consequently, this approach makes it possible to describe the realistic evolution of microstructure by avoiding the use of erroneous average value and can be used in CAE of multipass hot rolling.

• Fire Science and Engineering
• /
• v.25 no.6
• /
• pp.83-88
• /
• 2011

This study presented the structure and characteristics of vinyl cords used for wiring electric equipment and appliances and analyzed the photographs of damaged flat-type vinyl cords (VFF, $1.25mm^2$) and the metallic cross-sectional structure of melted conductors. Normal VFFs were made by twisting several strands together and the surface of the conductor was red brown. In addition, from the analysis of the metallic structure of the conductor, it was found that its grains had been elongated. The surface of a VFF damaged by normal flame showed no sheen with carbonized insulation material fused on the conductor surface. In addition, from the analysis of the cross-sectional structure of the melted area, it was found that voids of a certain shape were formed on it but that the cord's own elongation structure could not be checked. The cross-sectional analysis of the melted conductor damaged by the external flame applied to a VFF to which electric current was being applied showed no elongation structure for each cord, and revealed that irregular voids and a columnar structure had grown. The surface of the VFF damaged by overcurrent was uniformly carbonized and the cross-sectional structure analysis of the melted conductor revealed that the dendritic structure had grown. The analysis of the characteristics of the VFF melted by short-circuit showed that even though some part of the surface was contaminated, it showed little sheen and that the area rebounded by melting was round in shape. In addition, the cross-sectional structure analysis using a metallurgical microscope showed the boundary surface and columnar structure and revealed an amorphous structure like normal copper at areas other than the melted conductor.

• Journal of Welding and Joining
• /
• v.18 no.1
• /
• pp.59-69
• /
• 2000

The purpose of the present study was to investigate weld metallurgical phenomena such as primary solidification mode, microstructural evolution and hot cracking susceptibility in nitrogen-bearing austenitic stainless steel GTA welds. Eight experimental heats varying nitrogen content from 0.007 to 0.23 wt.% were used in this study. Autogenous GTA welding was performed on weld coupons and the primary solidification mode and their microstructural characteristics were investigated from the fusion welds. Varestraint test was employed to evaluate the solidification cracking susceptibility of the heats and TCL(Total Crack Length) was used as cracking susceptibility index. The solidification mode shifted from primary ferrite to primary austenite with an increase in nitrogen content. Retained delta ferrite exhibited a variety of morphology as nitrogen content varied. The weld fusion zone exhibited duplex structure(austenite+ferrite) at nitrogen contents less than 0.10 wt.% but fully austenitic structure at nitrogen contents more than 0.20 wt.%. The weld fusion zone in alloys with about 0.15 wt.% nitrogen experienced primary austenite + primary ferrite solidification (mode AF) and contained delta ferrite less than 1% at room temperature. Regarding to solidification cracking susceptibility, the welds with fully austenitic structure exhibited high cracking susceptibility while those with duplex structure low susceptibility. The cracking susceptibility increased slowly with an increase in nitrogen content up to 0.20 wt.% but sharply as nitrogen content exceeded 0.20 wt.%, which was attributed to solidification mode shift fro primary ferrite to primary austenite single phase solidification.

• Journal of the Korean Society for Heat Treatment
• /
• v.8 no.4
• /
• pp.302-317
• /
• 1995

After initial structure of AISI 9260 steel is changed into pearlite and martensite, one is isothermally annealed at $700^{\circ}C$ below of $A_1$ transformation point and the other is isothermally annealed at the same condition after 3 cycles of heating and cooling between $680^{\circ}C$ and $780^{\circ}C$ of $A_1$ transformation point. Analyzing the changes of microstructure, mechanical properties and fractography of tension test, we obtained result as follows. The fastest spheroidization rate by changes of initial structure and heat treatment cycles is appeared at the heat treatment cycle which is isothermally annealed after 3 cycles of heating and cooling at below and above $A_1$ transformation point for martensite. At the above condition, the perfect spheroidization structure is appeared after 60hrs and after then, globular carbide is being coarsened. The mean diameter of globular carbide is $2.4{\times}10^{-3}mm$ after 90hrs. The changes of tension strength during spheroidization heat treatment follows Orwan function, ${\sigma}_o={\sigma}_i+Gb/l$, where l is interspacing of carbide particles and at the above condition, ${\sigma}_o=70.48+2.5{\times}10^{-3}/l(kg/mm^2)$. Fractography of fracture of spheroidization structure in tension test is appeared as dimple which is ductile rupture type by nucleation and growth of void, size of dimple is larger and deeper with increasing of heat treatment time.

• Nuclear Engineering and Technology
• /
• v.38 no.3
• /
• pp.293-300
• /
• 2006

A liquid metal reactor (LMR) operated at high temperatures is subjected to both cyclic mechanical loading and thermal loading; thus, creep-fatigue is a major concern to be addressed with regard to maintaining structural integrity. The Korea Advanced Liquid Metal Reactor (KALIMER), which has a normal operating temperature of $545^{\circ}C$ and a total service life time of 60 years, is composed of various cylindrical structures, such as the reactor vessel and the reactor baffle. This study focuses on the creepfatigue crack initiation for a cylindrical Y-junction structure made of 316 stainless steel (SS), which is subjected to cyclic axial tensile loading and thermal loading at a high-temperature hold time of $545^{\circ}C$. The evaluation of the considered creep-fatigue crack initiation was carried out utilizing the ${\sigma}_d$ approach of the RCC-MR A16 guide, which is the high-temperature defect assessment procedure. This procedure is based on the total accumulated strain during the service time. To confirm the evaluated result, a high-temperature creep-fatigue structural test was performed. The test model had a circumferential through wall defect at the center of the model. The defect front of the test model was investigated after the $100^{th}$ cycle of the testing by utilizing a metallurgical inspection technique with an optical microscope, after which the test result was compared with the evaluation result. This study shows how creep-fatigue crack initiation for a high-temperature structure can be predicted with conservatism per the RCC-MR A16 guide.

• Journal of the Korean Society for Heat Treatment
• /
• v.17 no.6
• /
• pp.346-355
• /
• 2004

The flame quenching process has been employed to modify the surfaces of commercial marine propeller material, aluminum bronze alloy (Cu-8.8Al-5Ni-5Fe), and the microstructure, hardness and wear properties of the flame-quenched layers have been studied. The thermal history was accurately monitored during the process with respect to both the designed maximum surface temperature and holding time. The XRD and EDX analyses have shown that at temperatures above $T_{\beta}$, the microstructure consisting of ${\alpha}+{\kappa}$ phases changed into the ${\alpha}+{\beta}^{\prime}$ martensite due to an eutectoid reaction of ${\alpha}+{\kappa}{\rightarrow}{\beta}$ and a martensitic transformation of ${\beta}{\rightarrow}{\beta}^{\prime}$. The ${\beta}^{\prime}$ martensite phase formed showed a face-centered cubic (FCC) crystal structure with the typical twinned structure. The hardness of the flame-quenched layer having the ${\alpha}+{\beta}^{\prime}$ structure was similar to that of the ${\alpha}+{\kappa}$ structure and depended sensitively on the size and distribution of hard ${\kappa}$ and ${\beta}^{\prime}$ phases with depth from the surface. As a result of the sliding wear test, the wear resistance of the flame-quenched layer was markedly enhanced with the formation of the ${\beta}^{\prime}$ martensite.

• Transactions of the Korean Society of Mechanical Engineers
• /
• v.12 no.5
• /
• pp.1083-1091
• /
• 1988

Vacuum brazing is the most modern brazing process and is at present, far from being completely understood. By brazing under high vacuum, in an atmosphere free of oxidizing gases, a superior product with greater strength, ductility and uniformity can be obtained. In this study, the influence of brazing parameters such as base metal characteristics, joint clearance and brazing time were described in relation to the metallurgical phenomena and shear strength of vacuum-brazed joints between carbon steels and 304 stainless steel (SUS 304) brazed by copper filler metal. In copper brazing of SUS 304 to a medium carbon steel(M.C.S) the columnar Fe-Cr-Ni-Cu-C alloy structure was formed and grew from the M.C.S side and at the same time, the surface of M.C.S. was decarbonized. The driving force for the formation and growth of columnar structure was the difference of carbon content between base metals. As the joint clearance is narrower and brazing time is longer, the formation and growth of columnar phase and decarburization of carbon steels were more noticeable. Because of decarburization of carbon steels, the shear strength of brazed joints were reduced as the formation of columnar structure was increased.

• Korean Journal of Materials Research
• /
• v.2 no.6
• /
• pp.452-460
• /
• 1992

Effects of the microalloyed elements, temperatures and cooling rates on the strength and toughness of the medium carbon microalloyed hot forging steels obtained by air cooling(A.C.) method and the low carbon microalloyed forging steels by direct quenching(D.Q.) method were investigated. Combined additions of V+Nb produced the optimum combination of strength and toughness with ferrite-pearlite structure of the medium carbon steel by the A.C. method. 831MPa in UTS and 52.1J in toughness were obtained for 0.40c+0.12V+0.07Nb. It was martensite structure for the low carbon steel by the D.Q. method. The highest UTS and toughness obtained by Mo additions were 855MPa and 108j by 0.12C+0.10V+0.03Nb+1.13Mo respectively. Especially, the toughness of the low carbon steel was twice better than that of the medium carbon steel. 110$0^{\circ}C$was more appropriate than 120$0^{\circ}C$ for the reheating and forging temperature and 1.$2^{\circ}C$ /s was the best cooling rate from the viewpoint of the strength and toughness. Multiple regression analysis was used to quantify the influence of the microalloyed elements, temperatures and cooling rates on the strength, toughness, austenite grain size, and the pearlite interlamellar spacing.