• Title/Summary/Keyword: Metallic particle

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EffECTIVE PARTICULATES REDUCTION IN DIESEL ENGINES THROUGH THE USE OF FUEL CATALYSED PARTICULATE FILTERS

  • Vincent, M.-W.;Richards, P.-J.;Rogers, T.-J.
    • International Journal of Automotive Technology
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    • v.3 no.1
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    • pp.1-8
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    • 2002
  • There is Increasing world-wide interest in diesel particulate filters (DPF) because of their proven effectiveness in reducing exhaust smoke and particulate emissions. Fine particulates have been linked to human health . DPF use requires a means to secure the bum-out of the accumulated soot, a process called regeneration. If this is not achieved, the engine cannot continue to operate. A number of techniques are available, but most are complex, expensive or have a high electrical demand. The use of fuel additives to catalyse soot bum-out potentially solves the problem of securing regeneration reliably and at low cost. Work on organo-metallic fuel additives has shown that certain metals combine to glove exceptional regeneration performance. Best performance was achieved with a combination of iron and strontium based compounds. Tests were carried out un a bed engine and on road vehicles, which demonstrated effective and reliable regeneration from a tow dose fuel additive, using a single passive DPF. No control valves, flow diverters. heaters or other devices were employed to assist regeneration. Independent particle size measurements showed that there were no harmful side effects from the use of the iron-strontium fuel additive.

Synthesis of Nickel and Copper Nanopowders by Plasma Arc Evaporation

  • Cho, Young-Sang;Moon, Jong Woo;Chung, Kook Chae;Lee, Jung-Goo
    • Journal of Powder Materials
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    • v.20 no.6
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    • pp.411-424
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    • 2013
  • In this study, the synthesis of nickel nanoparticles and copper nanospheres for the potential applications of MLCC electrode materials has been studied by plasma arc evaporation method. The change in the broad distribution of the size of nickel and copper nanopowders is successfully controlled by manifesting proper mixture of gas ambiance for plasma generation in the size range of 20 to 200 nm in diameter. The factors affecting the mean diameter of the nanopowder was studied by changing the composition of reactive gases, indicating that nitrogen enhances the formation of larger particles compared to hydrogen gas. The morphologies and particle sizes of the metal nanoparticles were observed by SEM, and ultrathin oxide layers on the powder surface generated during passivation step have been confirmed using TEM. The metallic FCC structure of the nanoparticles was confirmed using powder X-ray diffraction method.

Synthesis of Nanoscale Zerovalent Iron Particle and Its Application to Cr(VI) Removal from Aqueous Solutions

  • Awad, Yasser M.;Abdelhafez, Ahmed A.;Ahmad, Mahtab;Lee, Sang-Soo;Kim, Rog-Young;Sung, Jwa-Kyung;Ok, Yong-Sik
    • Korean Journal of Environmental Agriculture
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    • v.29 no.4
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    • pp.402-407
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    • 2010
  • Zerovalent iron (ZVI) is one of the most commonly used metallic reducing agents for the treatment of toxic contaminants in wastewater. Traditional ZVIs are less effective than nanoscale ZVI (nZVI) due to prolonged reaction time. However, the reactivity can be significantly increased by reducing the size of ZVI particles to nanoscale. In this study, nZVI particles were synthesized under laboratory condition and their efficiency in removing hexavalent chromium (Cr(VI)) from aqueous solutions were compared with commercially available ZVI particles. The results showed that the synthesized nZVI particles (SnZVI) reduced >99% of Cr(VI) at the application rate of 0.2% (w/v), while commercial nZVI (CnZVI) particles resulted in 59.6% removal of Cr(VI) at the same application rate. Scanning electron micrographs (SEM) and energy dispersive spectra (EDS) of the nZVI particles revealed the formation of Fe-Cr hydroxide complex after reaction. Overall, the SnZVI particles can be used in treating chromium contaminated wastewater.

The Reaction Efficiency and Surface Characteristics for Metallic Ions in Air Flotation Process (부상공정에서 금속이온의 기포 표면 전위 특성 및 반응효율)

  • Han, Moo-Young;Dockko, Seok;Kim, Young-Hwan
    • Journal of Korean Society of Water and Wastewater
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    • v.18 no.2
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    • pp.222-227
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    • 2004
  • Flotation processes involve the use of very small bubbles (micro-bubbles) to separate particles from water. The process has become a good alternative to sedimentation, especially where the particles are small or of low density. Although the flotation process commences with a collision between particles and bubbles, most research has been focused only on the characteristics of the particles. In this paper, recent theoretical and experimental research on the characteristics of bubbles is summarized. The effect on the collision efficiency of the size and charge of bubbles is calculated through trajectory analysis. The size and charge of bubbles are measured under different conditions and the ramifications of the results are discussed. The results may lead to a better understanding and optimization of the existing process. In particular, we discuss an idea that a new advanced flotation process might be possible by the modification of the characteristics of the bubble alone or of both bubble and particle.

Application of Electromagnetic Fields to Improve the Removal Rate of Radioactive Corrosion Products

  • Kong, Tae-Young;Lee, Kun-Jai;Song, Min-Chul
    • Nuclear Engineering and Technology
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    • v.36 no.6
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    • pp.549-558
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    • 2004
  • TTo comply with increasingly strict regulations for protection against radiation exposure, many nuclear power plants have been working ceaselessly to reduce and control both the radiation sources within power plants and the radiation exposure experienced by operational and maintenance personnel. Many research studies have shown that deposits of irradiated corrosion products on the surfaces of coolant systems are the main cause of occupational radiation exposure in nuclear power plant. These corrosion product deposits on the fuel-clad surface are also known to be main factors in the onset of axial offset anomaly (AOA). Hence, there is a great deal of ongoing research on water chermistry and corrosion processes. In this study, a magnetic filter with permanent magnets was devised to remove the corrosion products in the coolant stream by taking advantage of the magnetic properties of the corrosion products demonstrated a removal efficiency of over 90% for particles above 5${\mu}m$. This finding led to the construction of an electromagnetic device that causes the metallic particulates to flocculate into larger aggregates of about 5${\mu}m$ in diameter by using a novel application of electromagnetic flocculation on radioactive corrosion products.

Spherical Bi2Te3 Powder Synthesized by Oxide-Reduction Process via Ultrasonic Spray Pyrolysis (초음파 분무 열분해법에 의한 산화물 환원 공정의 구형 Bi2Te3 분말 합성)

  • Song, Chul-Han;Jang, Dae-Hwan;Jin, Yun-Ho;Kong, Man-Sik
    • Journal of the Korean institute of surface engineering
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    • v.50 no.2
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    • pp.114-118
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    • 2017
  • Bismuth telluride ($Bi_2Te_3$) and its alloys are well-known thermoelectric materials for ambient temperature applications. In this study, the dissolved Bi-Te precursor solution was used to synthesis metallic $Bi_2Te_3$ powder via ultrasonic spray pyrolysis and reduction process. The droplets of the Bi-Te precursor solution were decomposed to Bi-Te oxide powders by ultrasonic spray pyrolysis. The spherical $Bi_2Te_3$ powders were synthesized by reduction reaction in atmosphere of hydrogen gas at the temperature above $375^{\circ}C$ for 6h. The reduced $Bi_2Te_3$ powders have a mean particle size of $1.5{\mu}m$. The crystal structure of the powder was evaluated by X-Ray diffraction(XRD), and the microstructure with size and shape powders was observed by fieldemission scanning electron microscope(FE-SEM) and transmission electron microscope(TEM).

Microstructure Evolution and Its Effect on Strength during Thermo-mechanical Cycling in the Weld Coarse-grained Heat-affected Zone of Ti-Nb Added HSLA Steel (Ti-Nb첨가 저합금강 용접열영향부에서의 열-응력 이력이 미세조직 및 기계적 성질에 미치는 영향에 관한 연구)

  • Moon, Joonoh;Lee, Changhee
    • Journal of Welding and Joining
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    • v.31 no.6
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    • pp.44-49
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    • 2013
  • The influence of thermo-mechanical cycling on the microstructure and strength in the weld coarse-grained heat affected zone (CGHAZ) of Ti-Nb added low carbon HSLA steel was explored through Vickers hardness tests, nanoindentation experiments, scanning electron microscopy (SEM) and transmission electron microscopy (TEM) analysis. Undeformed and deformed CGHAZs were simulated using Gleeble simulator with different heat inputs of 30kJ/cm and 300kJ/cm. At high heat input of 300kJ/cm, the CGHAZ consisted of ferrite and pearlite and then their grain sizes were not affected by deformation. At low heat input of 30kJ/cm, the CGHAZ consisted of lath martensite and then the sizes of prior austenite grain, packet and lath width decreased with deformation. In addition, the fraction of particle increased with deformation and this is because the precipitation kinetics was accelerated by deformation. Meanwhile, the Vickers and nanoindentation hardness of deformed CGHAZ with 30kJ/cm heat input were higher than those of undeformed CGHAZ, which are due to the effect of grain refinement and precipitation strengthening.

Combustion Characteristics of Fuel-rich Gas Generator (불완전연소 가스발생기 연소특성 연구)

  • Choi, Ho-Jin;Hyun, Hyung-Soo;Byun, Jong-Ryul;Park, Eui-Yong;Yoon, Hyun-Gull;Lim, Jin-Shik
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2011.04a
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    • pp.375-378
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    • 2011
  • The combustion characteristics of fuel-rich gas generator which could be adopted to Ducted Rocket propulsion system is investigated. The gas generator is designed considering the design requirements of propulsion system then solid fuel, which is developed by reducing the contents of oxidizer and increasing the contents of metallic solid particle, is loaded in the manufactured gas generator. The results of combustion test shows the necessity of the special analysis tool for estimating the gas generator performance where multi-phase flow of fuel-rich gas exists.

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In-situ formation of co particles encapsulated by graphene layers

  • Minjeong Lee;Gyutae Kim;Gyu Hyun Jeong;Aram Yoon;Zonghoon Lee;Gyeong Hee Ryu
    • Applied Microscopy
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    • v.52
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    • pp.7.1-7.6
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    • 2022
  • The process of encapsulating cobalt nanoparticles using a graphene layer is mainly direct pyrolysis. The encapsulation structure of hybrids prepared in this way improves the catalyst stability, which greatly reduces the leaching of non-metals and prevents metal nanoparticles from growing beyond a certain size. In this study, cobalt particles surrounded by graphene layers were formed by increasing the temperature in a transmission electron microscope, and they were analyzed using scanning transmission electron microscopy (STEM). Synthesized cobalt hydroxide nanosheets were used to obtain cobalt particles using an in-situ heating holder inside a TEM column. The cobalt nanoparticles are surrounded by layers of graphene, and the number of layers increases as the temperature increases. The interlayer spacing of the graphene layers was also investigated using atomic imaging. The success achieved in the encapsulation of metallic nanoparticles in graphene layers paves the way for the design of highly active and reusable heterogeneous catalysts for more challenging molecules.

FAST irradiations and initial post irradiation examinations - Part I

  • G. Beausoleil;L. Capriotti;B. Curnutt;R. Fielding;S. Hayes;D. Wachs
    • Nuclear Engineering and Technology
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    • v.54 no.11
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    • pp.4084-4094
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    • 2022
  • The Advanced Fuels Campaign Fission Accelerated Steady-state Test (FAST) at Idaho National Laboratory (INL) completed its first irradiation cycle within the Advanced Test Reactor (ATR). The test focused on the irradiation of alloy fuel forms for use in sodium fast reactors. The first cycle of FAST testing was completed and four rodlets were removed for the initial post irradiation examination (PIE). The rodlet design and irradiation conditions were evaluated using Monte Carlo N-Particle (MCNP) for as-run power history and COMSOL for temperature analysis. These rodlets include a set of low burnups (~2.5 % fissions per initial metal atoms [%FIMA]), control rodlets, and a helium-bonded annular rodlet (4.7 %FIMA). Nondestructive PIE has been completed and includes visual inspection, neutron radiography and gamma scanning of the FAST capsules and rodlets. Radiography confirmed the integrity of the experiments, revealed that the annulus in the annular fuel was filled at a modest burnup (4.7 %FIMA), and indicated potential slumping of the cooler rodlets at lower burnup. Precision gamma scanning indicated mostly usual fission product behavior, except for cesium in the He-bonded annular fuel. Future destructive PIE will be necessary to fully interpret the effects of accelerated irradiation on U-Zr metallic fuel behavior.