• Title/Summary/Keyword: Metallic material

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고효율 저가형 결정질 실리콘 태양전지에 적용될 Ni/Cu 전극 및 Ni silicide 형성에 대한 연구

  • Kim, Min-Jeong;Lee, Su-Hong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.11a
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    • pp.260-260
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    • 2009
  • In high-efficiency crystalline silicon solar cell, If high-efficiency solar cells are to be commercialized, It is need to develop superior contact formation method and material that can be inexpensive and simple without degradation of the solar cells ability. For reason of plated metallic contact is not only high metallic purity but also inexpensive manufacture. It is available to apply mass production. Especially, Nickel, Copper are applied widely in various electronic manufactures as easily formation is available by plating. Ni is shown to be a suitable barrier to Cu diffusin as well as desirable contact metal to silicon. Nickel monosilicide has been suggested as a suitable silicide due to its lower resistivitym lower sintering temperature and lower layer stress than $TiSi_2$. In this paper, Nickel as a seed layer and diffusion barrier is plated by electroless plating to make nickel monosilicide.

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Coupling shape-memory alloy and embedded informatics toward a metallic self-healing material

  • Faravelli, Lucia;Marzi, Alessandro
    • Smart Structures and Systems
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    • v.6 no.9
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    • pp.1041-1056
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    • 2010
  • This paper investigates the possibility of a strategy for an automatic full recover of a structural component undergoing loading-unloading (fatigue) cycles: full recover means here that no replacement is required at the end of the mission. The goal is to obtain a material capable of self healing earlier before the damage becomes irreversible. Attention is focused on metallic materials, and in particular on shape memory alloys, for which the recovering policy just relies on thermal treatments. The results of several fatigue tests are first reported to acquire a deep understanding of the physical process. Then, for cycles of constant amplitude, the self-healing objective is achieved by mounting, on the structural component of interest, a suitable microcontroller. Its input, from suitable sensors, covers the current stress and strain in the alloy. The microcontroller elaborates from the input the value of a decisional parameter and activates the thermal process when a threshold is overcome.

The surface propery change of multi-layer thin film on ceramic substrate by ion beam sputtering (이온빔 스퍼터링법에 의한 다층막의 표면특성변화)

  • Lee, Chan-Young;Lee, Jae-Sang
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.259-259
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    • 2008
  • The LTCC (Low Temperature Co-fired Ceramic) technology meets the requirements for high quality microelectronic devices and microsystems application due to a very good electrical and mechanical properties, high reliability and stability as well as possibility of making integrated three dimensional microstructures. The wet process, which has been applied to the etching of the metallic thin film on the ceramic substrate, has multi process steps such as lithography and development and uses very toxic chemicals arising the environmental problems. The other side, Plasma technology like ion beam sputtering is clean process including surface cleaning and treatment, sputtering and etching of semiconductor devices, and environmental cleanup. In this study, metallic multilayer pattern was fabricated by the ion beam etching of Ti/Pd/Cu without the lithography. In the experiment, Alumina and LTCC were used as the substrate and Ti/Pd/Cu metallic multilayer was deposited by the DC-magnetron sputtering system. After the formation of Cu/Ni/Au multilayer pattern made by the photolithography and electroplating process, the Ti/Pd/Cu multilayer was dry-etched by using the low energy-high current ion-beam etching process. Because the electroplated Au layer was the masking barrier of the etching of Ti/Pd/Cu multilayer, the additional lithography was not necessary for the etching process. Xenon ion beam which having the high sputtering yield was irradiated and was used with various ion energy and current. The metallic pattern after the etching was optically examined and analyzed. The rate and phenomenon of the etching on each metallic layer were investigated with the diverse process condition such as ion-beam acceleration energy, current density, and etching time.

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PWHT Cracking Susceptibility in the Weld Heat-Affected Zone of Reduced Activation Ferritic/Martensitic Steels (핵융합로 구조용 저방사화강의 용접열영향부 후열처리 균열 감수성)

  • Lee, Jinjong;Moon, Joonoh;Lee, Chang-Hoon;Park, Jun-Young;LEE, Tae-Ho;Hong, Hyun-Uk;Cho, Kyung-Mox
    • Journal of Welding and Joining
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    • v.34 no.6
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    • pp.47-54
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    • 2016
  • Post-Weld Heat Treatment (PWHT) cracking susceptibility in the weld heat-affected zone (HAZ) of reduced activation ferritic-martensitic (RAFM) steels was evaluated through stress-rupture tests. 9Cr-1W based alloys including different C, Ta and Ti content were prepared. The coarse grained heat-affected zone (CGHAZ) samples were simulated with welding condition of 30 kJ/cm heat input. CGHAZ samples consisted of martensite matrix. Stress rupture experiments were carried out using a Gleeble simulator at temperatures of $650-750^{\circ}C$ and at stress levels of 125-550 MPa, corresponding to PWHT condition. The results revealed that PWHT cracking resistance was improved by Ti addition, i.e., Ti contributed to the formation of fine and stable MX precipitates and suppression of coarse M23C6 carbides, resulting in improvement of stress rupture ductility. Meanwhile, rupture strength increased with increasing solute C content.

Resonance Characteristics of a Metallic Enclosure Having Sub-Cavity with Lossy Dielectric Materials (부공동에 손실 유전체를 충진한 함체 케이스의 공진 특성)

  • Lim, Sung-Min;Jung, Sung-Woo;Kim, Ki-Chai
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.20 no.9
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    • pp.936-942
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    • 2009
  • This paper presents the delivered power and reflection coefficient in metallic shielding enclosure with a sub-cavity, which are evaluated with the method of moments, sad describes a method for controlling the resonance characteristics of the metallic cavity by putting lossy dielectric material in the sub-cavity. In this paper we introduce carbon polystyrene-foam as lossy dielectric material and observe it's effects of reduction when the dimensions of the sub-cavity and permittivity of lossy dielectric material are changed. The results show that the reduction of the electromagnetic radiation can be achieved by controlling the amount of carbon in lossy dielectric material and the dimensions of the sub-cavity. The theoretical analysis is verified by the measured delivered power.

Structure and Oxidation Behavior of the $LaCrO_3$-dispersed Cr alloys ($LaCrO_3$가 분산된 Cr 합금의 구조 및 산화거동)

  • Jeon, Kwang-Sun;Song, Rak-Hyun;Shin, Dong-Ryul;Jo, J.
    • Proceedings of the KIEE Conference
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    • 1998.07d
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    • pp.1303-1305
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    • 1998
  • In order to reduce or avoid oxidation problem at operation the interconnects in SOFCs have so far mostly been made of ceramic material. It has high chemical stability both under cathode and anode condition, relatively thermal expansion coefficient that matchs that of electrolyte material YSZ. But this material shown rather weak in the low oxygen atmosphere and thermal shock, and it has lower mechanical strength than alloys. To avoid these problems one may consider to use metals or alloys as materials for interconnects. Metallic interconnects are advantageous because of their high thermal and electronic conductivities. But it has some problems, Those are high thermal expansion and oxidation at high temperature in air. To solve these problems in the interconnection material in this study, $LaCrO_3$-dispersed Cr alloys for metallic interconnector of SOFC have been investigated as a fuction of $LaCrO_3$ content in the range of 5 to 25 vol.%. The Cr alloy were prepared by mixing Cr and $LaCrO_3$ powders in high-energy ball mill for 48h and by sintering under Ar atmosphere with 5vol.% $H_2$ for 10h at $1500^{\circ}C$. The alloys had a relative density of 95% and above. The Cr alloys in composed of two kind of small $LaCrO_3$ and large Cr particles. As the $LaCrO_3$ content increased, the Cr particle size decreased but the $LaCrO_3$ particle size remained contant. Also the oxidation tests show that the $LaCrO_3$-dispersed Cr is very resistant to oxidation in air. These results means that $LaCrO_3$-dispersed Cr is a useful material for metallic interconnect of planar SOFC.

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Current Status of Domestic Recycling of Used Metallic Can (국내 금속캔 리싸이클링 현황)

  • Park, Hyungkyu;Shin, Shunmyung
    • Resources Recycling
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    • v.23 no.5
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    • pp.62-67
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    • 2014
  • Used metallic can should be recycled from the point of view of environmental preservation and resource recycling. Metallic can is one of EPR items, and classified into steel can and aluminum can according to the can body material. In Korea about eighty percent of metallic cans are made of steel. In this article, production of cans and current status on domestic recycling of used metallic cans in recent years(2008-2012) were surveyed. Recycled ratio by weight of used steel and aluminum cans was about 80.8% and 81.8%, respectively in 2012. Totally it reached 81.8%.

Recovery of Heavy-Metallic Components from a Waste Electro-polishing Solution of 316L Steel by the Solar Cell Electricity (태양전지 전력을 이용한 316L강의 전해연마 폐액 중 중금속 성분의 회수)

  • Kim, Ki-Ho;Jang, Jung-Mok
    • Journal of the Korean institute of surface engineering
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    • v.42 no.1
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    • pp.53-57
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    • 2009
  • Recovery of heavy-metallic component from a waste solution of factory was undertaken by the solar cell electricity. The solution was obtained from an electrolytic etching process of 316L stainless steel. The electrolysis of the solution for recovery of heavy metallic components was made with platinum plated titanium mesh anode and copper plate cathode. Analysis for the solution and electro-winned materials were made by EDS, XRD and SEM. Iron, chromium, and sulfur components were recovered on the cathode from the solution. Result of EDS analysis for the electro-winned materials revealed that some metal oxide were contained in the recovered material. The recovered materials were expected to have metallic form only by the electrolysis, but metal compounds were contained because of weak solar cell power. Nickel and manganese component in the solution doesn't recovered by this electrolysis process, but they made a sludge with phosphoric acid in the solution.

Corrosion Characteristics of 316L Stainless Steel with Chloride Concentrations in Cathode Operating Conditions of Metallic Bipolar Plate for PEMFC (고분자 전해질 연료전지 금속분리판용 316L 스테인리스강의 양극작동조건에서 염화물 농도에 따른 부식 특성)

  • Shin, Dong-Ho;Kim, Seong-Jong
    • Corrosion Science and Technology
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    • v.20 no.6
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    • pp.435-450
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    • 2021
  • The interest in eco-friendly energy is increasing, and polymer electrolyte membrane fuel cell (PEMFC) is attracting attention as alternative power sources. Research on metallic bipolar plates, a fuel cell component, is being actively conducted. However, since the operating conditions of PEMFC, in which sulfuric acid (H2SO4) and hydrofluoric acid (HF) are mixed, are strong acidity, the durability of the metallic bipolar plate is very important. In this research, the electrochemical characteristics and corrosion damage behavior of 316L stainless steel, a material for metallic bipolar plates, were analyzed through potentiostatic corrosion tests with test times and chloride concentrations. As the test times and chloride concentrations increased, the current density and corrosion damage increased. As a result of observation with scanning electron microscope(SEM) and 3D microscope, both the depth and width of pitting corrosion increased with increases in test times and chloride concentrations. In particular, the pitting corrosion damage depth at test conditions of 6 hours and 1000 ppm chloride increased the most. The growth of the pitting corrosion damage was not directly proportional to time and increased significantly after a certain period.

The Effects of Aging Conditions on the Crystallization of $Fe_{78}B_{13}Si_9$ Metallic Glass (시효조건에 다른 $Fe_{78}B_{13}Si_9$ 비정질 합금의 결정화 연구)

  • Lee, Won-Jae;Kim, Ki-Uk;Mlin, Bok-Ki;Song, Jae-Sung;Hong, Jin-Wan;Kang, Won-Koo;Kim, Yoon-Dong
    • Proceedings of the KIEE Conference
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    • 1989.07a
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    • pp.291-294
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    • 1989
  • The effect of isothermal aging on the crystallization of $Fe_{78}B_{13}Si_9$ metallic glass has been investigated by electrical resistivity, X-ray measurements, bending test, thermal analysis and transmission electron microscpy. Amouphous $Fe_{78}B_{13}Si_9$ alloy was annealed isothermally for 5 to 1200 min. between $300^{\circ}C$ and $540^{\circ}C$. It has been found that close relation between relative resistivity and X-ray diffraction pattern showed. The crystalline peaks of ${\alpha}$-(Fe, Si) and $Fe_2B$ are detected by X-ray experiment. The crystalline phases observed by TEH show ${\alpha}$-(Fe, Si) and $Fe_2B$ with dendritic and cylindrical morphology, respectively. It has been also found that the embrittleness of aged samples rapidly increased with the crystallization and was shown before the crystallization.

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