• Journal of Korean Society for Atmospheric Environment
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• v.16 no.1
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• pp.23-35
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• 2000

PM10, which is below 10 ${\mu}{\textrm}{m}$ in a diameter, has a high deposition in the lung or the bronchus by breathing and is generally composed of a lot of organic matters, viruses, algae, mold, and metallic elements that are very toxic to people. This study identified the characteristics of concentration of PM10 and air-borne jmetallic elements produced in the industrial city, Ulsan, and analyzed the correlatuion between sources and generation patterns of PM10 and metallic elements. We classified the five areas(green, residential, heavy traffic, mechanic, and petrochemcal and non-ferrous metal) which might have different characteristics of sources of PM10 and metallic elements. The average concentrations of PM10 in the five areas were as follows(petrochemical and non-ferrous metal(99.9$\mu\textrm{g}$/㎥)>mechanic(77.5 $\mu\textrm{g}$/㎥)>heavy traffic(47.1 $\mu\textrm{g}$/㎥)>residential(39.3 $\mu\textrm{g}$/㎥)>green(32.8 $\mu\textrm{g}$/㎥)). Those of petrochemical and non-ferrous metal areas were higher than other areas. In this study, the average concentration trend of metallic elements contained in PM10 are shown as follows: Fe>Zn>Pb>Cu>Mn>Cr>As>Cd>Sn>Hg, respectively. The metallic elements identified in PM10 showed the highest concentration in the petrochemical and non-ferrous areas. Metal combinations showed that a high correlation among concentrations of heavy metals were as follows: As, Cd and Fe in the residential area; Zn, Mn, Cu and Pb in the mechanical area; and Zn, Cu, As, Pb in the petrochemical and non-ferrous industrial area.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.39 no.2
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• pp.106-117
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• 2006

We measured the concentrations of organic matter and metallic elements (Al, Fe, Cr, Mn, Ni, Cu, Zn, As, Cd, Pb and Hg) in the surface sediments of Masan Harbor (in the southern sea, Korea) to evaluate the geochemical characters of sediment and the pollutions by organic matter and metallic elements. The mean grain size of the surface sediments in the study area ranged from $5.6{\phi}$ to $7.8{\phi}$, indicating silt sediment. The water content of the surface sediments exceeded 60% except at some stations. The contents of ignition loss (IL), total organic carbon (TOC) and total nitrogen (TN) ranged from 7.2-14.3%, 1.2-3.2%, and 0.10-0.28%, respectively. Based on the C/N ratios, the organic matter in the surface sediments of Masan Harbor may originate from terrigenous sources including fluvial inputs (mainly sewage in urban areas). The chemical oxygen demand (COD) and acid volatile sulfide (AVS) ranged from $11.3-29.9\;mgO_2/g\;dry$ and 0.20-4.47 mgS/g dry, respectively, and low concentrations were observed near a shipping route. In addition, the concentrations of metallic elements showed large spatial variations in Masan Harbor and the distributions of metallic elements were also comparable to those of organic matter. This implies that the distributions of organic matter and metallic elements in the surface sediments of Masan Harbor are mainly controlled by biogenic matter and artificial action (mainly dredging). In addition, we calculated the enrichment facto. (EF) and geoaccumulation index (Igeo) in order to evaluate pollution by metallic elements. The enrichment of metallic elements relative to Al was three to eighteen times higher at the study sites, compared to levels in the Earth's crust except for Fe, Ni and Mn. In addition, the Igeo class indicated that the surface sediments in the study area were moderately to strongly polluted in terms of metallic elements.

• Journal of Environmental Impact Assessment
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• v.12 no.2
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• pp.99-108
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• 2003

We collected and analyzed PM10 samples to account for the characteristics of heavy metallic elements for yellow sand and non-yellow sand during springtime of 2002 at Busan, The mean PM10 mass concentration for springtime of 2002 was $219.82{\mu}g/m^3$ with the maximum $787.50{\mu}g/m^3$ and the minimum $19.44{\mu}g/m^3$. The mean concentration of metallic elements contained in PM10 are shown as follows : Si>Ca>Fe>Al>Na, respectively. The ratio of mean PM10 mass concentration for yellow sand($362.7{\mu}g/m^3$) to that for non-yellow sand($48.3{\mu}g/m^3$) was 7.5, the significant positive correlation (P<0.05) was found between yellow sand and non-yellow sand. The metallic elements concentration ratios of yellow sand to the non-yellow sand were over 10 times for Al, Ca, Mg, 4~8 times for Fe, Si, Mn. But the concentration of Na, Cu, Zn for non-yellow sand was higher than those of yellow sand. The crustal enrichment factor of Cd, Cu, Pb, Zn, Cr, K, Mn, Na, Ni for yellow sand was higher that of non-yellow sand over 10 times, and concentration rate of soil particles of yellow sand was increased 2.3 times that of nonyellow sand.

• Journal of Environmental Science International
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• v.24 no.6
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• pp.777-784
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• 2015

This study investigates weekday/weekend characteristics of $PM_{10}$ and $PM_{2.5}$ concentration and metallic elements in Busan in the springtime of 2013. $PM_{10}$ concentration on weekday/weekend were 77.54 and $67.28{\mu}g/m^3$, respectively. And $PM_{2.5}$ concentration on weekday/weekend were 57.81 and $43.83{\mu}g/m^3$, respectively. Also, $PM_{2.5}/PM_{10}$ concentration ratio on weekdays/weekend was 0.75 and 0.65, respectively. The contribution rates of Na to total metallic elements in $PM_{10}$ on weekday/weekend were 38.3% and 38.9%, respectively. It would be useful in control effectively with management of urban fine particle to understand characteristics of fine particle concentration on weekday/weekend.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.43 no.2
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• pp.146-158
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• 2010

In order to evaluate the characteristics of sediments and pollution by organic matter and metallic elements in intertidal sediments along the southwestern coast of Korea, we measured various geochemical parameters, including the mean grain size (Mz), water content (WC), ignition loss (IL), chemical oxygen demand (COD), acid volatile sulfide (AVS), and metallic elements (Al, Fe, Cu, Pb, Zn, Cd, Cr, Mn, Hg, As), in intertidal surface sediments. The Mz of the surface sediments ranged from 2.1 to 8.3$\phi$, indicating that the surface sediments consist of various sedimentary facies, such as sand, slightly gravelly mud, sandy mud, and silt. The IL and COD in surface sediment ranged from 0.8 to 5.5% (mean $2.9\pm1.2%$) and from 3.9 to $13.8\;mgO_2/g{\cdot}dry$ (mean $8.5\pm2.6\;mgO_2/g{\cdot}dry$), respectively, which were lower than the values for surface sediment in areas near fish and shellfish farms or industrial complexes. No AVS was detected at any sampling station, despite various sedimentary facies. Most of metallic elements in surface sediments showed relatively good positive correlations with Mz and IL, which imply that the concentrations of metallic elements are mainly controlled by grain size and the organic matter content. The concentrations of metallic elements, except As, at some stations were considerably lower than those in the Sediment Quality Guideline (Effect Range Low, ERL) proposed by the National Oceanic and Atmospheric Administration (NOAA) in the United States. Similarly, the geoaccumulation index (Igeo) class indicated that pollution by metallic elements in intertidal surface sediment, except As, was moderate or non-existent. Our results imply that the intertidal surface sediments along the southwestern coast of Korea are not polluted by organic matter and metallic elements and are healthy for benthic organisms.

• Journal of Environmental Health Sciences
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• v.33 no.6
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• pp.479-487
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• 2007

[ $PM_{2.5}$ ], particulate matter less than 2.5 um in a diameter, can penetrate deeply into the lungs. Exposure to $PM_{2.5}$ has been associated with increased hospital visits for respiratory aliments as well as increase mortality. $PM_{2.5}$ is a byproduct of combustion processes and as such has a complex composition including a variety of metallic elements, inorganic and organic compounds as well as biogenic materials (microorganisms, proteins, etc). In this study, the average concentrations of fine particulates $PM_{2.5}$ have been measured simultaneously in Asan and Seoul, Korea, by using particulate matter portable sampler from September 2001 to August 2002. Sample collection filters were analyzed by ICP-OES to determine the concentrations of metallic elements (As, Ni, Fe, Cr, Cd, Cu, Pb, Zn, Si). Annual mean $PM_{2.5}$ concentrations in Asan and Seoul were 37.70 and $45.83\;{\mu}g/m^3$, respectively. The highest concentrations of $PM_{2.5}$ were found in spring season in both cities and the concentrations of measured metallic elements except As in Asan were higher than those in Seoul, suggesting that yellow dust in spring could affect $PM_{2.5}$ concentrations in Asan rather than Seoul. The correlation coefficients of Pb and Zn were 0.343 for Asan and 0.813 for Seoul during non-yellow dust condition, suggesting that Pb and Zn were influenced with the same sources. The correlation coefficients between Si and Fe in the fine particulate mode were 0.999 (Asan) and 0.998 (Seoul) during yellow dust condition. It was suggested that these two elements were impacted by soil-related transport from China during the yellow dust storm condition.

• Journal of the korean society of oceanography
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• v.38 no.1
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• pp.17-23
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• 2003

We report the distribution of $^{210}$ Pb and various metallic elements (Al, Fe, Mg, Ca, Ti, Mn, Sr, Ba, Zn, V, Cr, Zr, Ni, Cu, and Y) in the sediment cores from six shellfish-farming bays in the South Sea of Korea. The $^{210Pb}$ inventories in Deukryang, Gwangyang, and Goseong Bay cores were comparable to those expected from the known fallout input. However, the $^{210}$ Pb inventories were two times higher in Jinju, Gangjin, and Hansan-Koeje Bay cores, suggesting an important role of other sources such as fluvial inputs. Based on the enrichment factor analyses, non-detrital fractions of all the measured elements were found to be insignificant. The Mn was highly enriched only in the surface sediments of the Jinju and Goseong Bay, which implies that the surface-sediment environment of these bays is efficiently oxidizing Mn remobilized from either pore waters or bottom seawaters. These data set provides the sources of heavy metal in sediment around shellfish farms and the current level of metallic elements for the future monitoring.

• Journal of Korea Foundry Society
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• v.32 no.4
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• pp.177-180
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• 2012

Ti-based bulk metallic glasses with high glass forming ability were developed through a systematic alloy design technique. The main alloy design strategy was the selection of alloying elements that may not be toxic in the human body. The $Ti_{45.0}Cu_{40.1}Zr_{12.7}Si_{2.2}$ alloy could be cast into an amorphous rod with the diameter of 3 mm by a suction casting technique using Cu mold. The compressive strength of the amorphous rod was measured as 1826 MPa. Since the Ti-based amorphous alloys consist of non-toxic elements, they can be widely used as bio-materials and eco-materials with unique and beneficial properties.

• Journal of Environmental Science International
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• v.11 no.9
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• pp.881-895
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• 2002

Sediments and river waters form the channel of Hwasun-cheon were studied in sedimentological size and geochemical analyses of metallic elements for the purposes of identification of depositional environments and geochemical characteristics. The sizes of sediments are assigned to pebble to coarse sand in mean size and polymodal in distribution. And the sediments are poorly to very poorly sorted and positively skewed. According to the grain size distributions of the sediments, the Hwasun-cheon belongs to gravel-bed river on the basis of the grain size distribution of the sediments. The behaviors of metallic elements in the sediments mainly depend on not grain size distribution but the geology connected with geomorphological reliefs near the stream. Contamination indices(CI) of Zn, Cu and Pb are 2.83 to 6.96 with average 4.31 in the sediments. Hwasun-cheon is assigned to general stream type in accordance with water quality of physical factors and chemical characteristics by Piper's diagram. Though meaningful values of BOD, T-N, T-P were locally depicted near Masan-ri, Hwasun-eup and Jiseok-cheon areas, artificial metal concentration do not represent in the most area of the stream. Sediments and river water are considered that the relatively more or less high metallic contents in the stream are originated from coal mine and urban area.

• Journal of Environmental Health Sciences
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• v.30 no.2
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• pp.123-132
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• 2004

The purpose of this study was to characterize background mass concentration of PM$_{10}$ and metallic composition from September 2001 to August 2002 in comparison with Asan and Seoul. Annual mean of PM$_{10}$ concentrations in Asan and Seoul were 47.98 and 75.33$\mu\textrm{g}$/㎥, respectively. The concentrations of PM$_{10}$ were highest in spring season in both cities. The concentrations of measured metals except for As and Pb in Asan were higher than those in Seoul. Yellow dust could affect the mass and metals concentrations of measured PM$_{10}$ in Asan and Seoul. Relationship between measured metals concentrations showed that Si and Fe were associated with natural sources such as soil. Pb, Cu and Zn were closely related to urban anthropogenic sources such as fuel combustion. Especially, relationship between metals showed different association during yellow dust. Proper management for PM$_{10}$ will need in Asan, considered the concentrations of metallic elements in PM$_{10}$ in Asan were relatively higher than those in Seoul.se in Seoul.