• Korean Journal of Soil Science and Fertilizer
• /
• v.47 no.6
• /
• pp.518-524
• /
• 2014

Heavy metal pollution in agricultural field near at the abandoned metal mines has been a critical issue in Korea. In particular, bioaccumulation in plants can have detrimental effect on human health. Main objective of this research was to examine arsenic (As) concentration in soil with varied extraction methods and to determine bioaccumulation and biological transfer factor in different crops. Results showed that bioaccumulation ratio of As for total contents in soil was ordered leafy and stem vegetables (1.19%) > fruit bearing vegetables (0.79%) > pulses (0.40%) > root vegetables (0.36%) with different crop species. Among 6 different extraction methods, all of extraction methods showed high correlation ($R^2=0.87-0.97$) except DTPA ($R^2=0.25$) when comparing As concentration in soil extracted with different extractants and As concentration in each crops. Calculated biological transfer factor was ranged 0.002-0.018 depending on crop species. Overall, concentration of As in crops can be varied and best management practice for minimizing bioaccumulation of As should be considered depending on crop species.

• Proceedings of the Korean Society of Machine Tool Engineers Conference
• /
• 2003.10a
• /
• pp.265-270
• /
• 2003

When designing an engine part the designer has to choose the proper material and to define the dimensions of the part. in the most rudimentary case he has available as guidelines the collective experience from similar applications. The performance of the part is tested on occasion of the trial runs for the full system, and possibly occurring deficiencies are corrected until a satisfactory usable life and safety of operation is achieved. This procedure is time consuming and costly, and the learning effect is minimal. These requirements have to be condensed into characteristic values ameanable to computation. Since testing and computation are complementary we have to look at the currently existing mathematical models for engine bearing performance.

• Bulletin of the Korean Chemical Society
• /
• v.33 no.7
• /
• pp.2359-2364
• /
• 2012

Two new chemosensors, rhodamine 6G derivative bearing hydroxyethyl group (1) and rhodamine base derivative bearing 15-crown-5 group (2) were synthesized and their sensing behaviors toward various metal ions were investigated by UV/Vis and fluorescence spectroscopies. Addition of $Hg^{2+}$ ion to a $CH_3CN$ solution of 1 and 2 gave visual color changes as well as fluorescent OFF-ON observations. Selectivity and sensitivity of 1 towards $Hg^{2+}$ are excellent enough to detect micromolar level of $Hg^{2+}$ ion, even in equeous media and biological sample (HeLa cell).

• Economic and Environmental Geology
• /
• v.23 no.2
• /
• pp.183-199
• /
• 1990

Ore deposits of Dongwon mine are composed of numerous gold and silver veins emplaced in sedimentary rocks of Cambrian Choseon Supergroup and granitoids of Cretaceous age. Ore veins of the mine can be divided into gold and silver veins on the base of vein structure, mineral assemblage and vein trends. Mutual relationships between gold and silver veins are uncertain. Gold veins are simple veins which are composed of base-metal sulfides, and electrum with quartz and ankerite. On the other hand, silver veins are complex veins which reveal three distinct stages of mineral deposition based on vein structure; stage I, deposition of small amounts of oxides and pyrite with quartz; stage II, deposition of base-metal sulfides, small amounts of Ag-bearing minerals, calcite and quartz; stage III, deposition of base metal sulfides, electrum, Ag-sulfosalts, native silver, carbonates and quartz. Homogenization temperature and salinity of fluid inclusion from quartz of gold vein are as follows; $229^{\circ}$ to $283^{\circ}C$, 4.7 to 6.4 wt.% equivalent NaCI. The ore mineralogy suggests that temperature(T) and sulfur fugacity($fs_2$) of the formation of the gold vein and stage III of silver vein are estimated as T ; $294^{\circ}$ to $318^{\circ}C$, $fs_2\;10^{-9.4}$ to $10^{-10.1}$ atm. and T; $240^{\circ}$ to $279^{\circ}C$, $fs_2;10^{-11.1}$ to $10^{-17.3}$ atm. respectively. Pressure condition during gold vein formation estimated from data of ore mineralogy and fluid inclusion range 500 to 750 bar.

• Bulletin of the Korean Chemical Society
• /
• v.24 no.3
• /
• pp.269-273
• /
• 2003

The synthesis and properties of 2,13-bis(3'-pyridylmethyl) $(L^3)$, 2,13-bis(4'-pyridylmethyl) $(L^4)$, and 2,13-bis(phenylmethyl) $(L^5)$ derivatives of 5,16-dimethyl-2,6,13,17-tetraazatrcyclo$[16.4.0.^{1.18}0^{7.12}]$docosane are reported. The 3- or 4-pyridylmethyl groups of $[ML^3](ClO_4)_2\;or\;[ML^4](ClO_4)_2$ (M = Ni(Ⅱ) or Cu(Ⅱ)) are not involved in coordination, and the coordination geometry (square-planar) and ligand field strength of the complexes are quite similar to those of $[ML^5](ClO_4)_2$, bearing two phenylmethyl pendant arms. However, the complex formation reactions of $L^3\;and\;L^4$ are strongly influenced by the pyridyl groups, which can interact with a proton or metal ion outside the macrocyclic ring. The macrocycle $L^5$ exhibits a high copper(Ⅱ) ion selectivity against nickel(Ⅱ) ion; the ligand readily reacts with copper(Ⅱ) ion to form $[CuL^5]^{2+}$ but does not react with hydrated nickel(Ⅱ) ion in methanol solutions. On the other hand, $L^3\;and\;L^4$ form their copper(Ⅱ) and nickel(Ⅱ) complexes under a similar condition, without showing any considerable metal ion selectivity. The ligands $L^3\;and\;L^4$ react with copper(Ⅱ) ion more rapidly than does $L^5$ at pH 6.4. At pH 5.0, however, the reaction rate of the former macrocycles is slower than that of the latter. The effects of the 3- or 4-pyridylmethyl pendant arms on the complex formation reaction of $L^3\;and\;L^4$ are discussed.

• Design & Manufacturing
• /
• v.11 no.1
• /
• pp.7-13
• /
• 2017

The aim of this study is to develop the dies oven for energy-saving during the pre-heated process of extrusion dies. Applying high-efficiency near-infrared heater, single cell type dies oven was developed as a substitute for traditional chest type oven. Therefore the dies is individually heated uniformly to operation temperature so rapidly. By using the developed dies oven, electric-energy consumption of preheating extrusion dies reduced up to 30% and the waiting time in the oven also minimized up to 90min. In addition, the results have shown that it is possible to accurately control the dies temperature for improving the quality of extruded profile and to minimize die bearing oxidation and nitride layer degradation responsible for surface defects on the profile and shorter die life.

• Steel and Composite Structures
• /
• v.19 no.3
• /
• pp.661-678
• /
• 2015

Buckling Restrained Braces (BRB) have been widely used in the construction industry as they utilize the most desirable properties of both constituent materials, i.e., steel and concrete. They present excellent structural qualities such as high load bearing capacity, ductility, energy-absorption capability and good structural fire behaviour. The effects of size and type of filler material in the existed gap at the steel core-concrete interface as well as the element's cross sectional shape, on BRB's fire resistance capacity was investigated in this paper. A nonlinear sequentially-coupled thermal-stress three-dimensional model was presented and validated by experimental results. Variation of the samples was described by three groups containing, the steel cores with the same cross section areas and equal yield strength but different materials (metal and concrete) and sizes for the gap. Responses in terms of temperature distribution, critical temperature, heating elapsed time and contraction level of BRB element were examined. The study showed that the superior fire performance of BRB was obtained by altering the filler material in the gap from metal to concrete as well as by increasing the size of the gap. Also, cylindrical BRB performed better under fire conditions compared to the rectangular cross section.

• Journal of Magnetics
• /
• v.16 no.2
• /
• pp.124-128
• /
• 2011

This study estimated experimentally the loss distribution caused by magnetic friction in magnetic parts of a superconductor flywheel energy storage system (SFES) to obtain information for the design of high efficiency SFES. Through the spin down experiment using the manufactured vertical shaft type SFES with a journal type superconductor magnetic bearing (SMB), the coefficients of friction by the SMB, the stator core of permanent magnet synchronous motor/generator (PMSM/G), and the leakage flux of the metal parts were calculated. The coefficients of friction by the stator core of PMSM/G in case of using Si-steel and an amorphous core were calculated. The energy loss by magnetic friction in the stator core of PMSM/G was much larger than that in the other parts. The level of friction loss could be reduced dramatically using an amorphous core. Energy loss by the leakage magnetic field was small. On the other hand, the energy loss could be increased under other conditions according to the type of metal nearby the leakage magnetic fields. In manufactured SFES, the rotational loss by the amorphous core was approximately 2 times the loss of the superconductor and leakage. Moreover, the rotational loss by the Si-steel core is approximately 3~3.5 times the loss of superconductor and leakage.

• Journal of Environmental Science International
• /
• v.14 no.7
• /
• pp.691-697
• /
• 2005

Waste sludge may be used to recovery wastewater contaminated with heavy metals. The waste sludge is an inexpensive readily available source of biomass for biosorption with metal-bearing wastewater. The biosorption of heavy metals such as Pb(II), Cu(II), Cr(II), and Cd(II) onto waste sludge was investigated in batch ex­periments and waste sludge loaded heavy metals was separated by dissolved air flotation. The biosorption equi­bria of heavy metals could be described by Langmuir and Freundich isotherms. The adsorption capacity for waste sludge was in the sequence of Pb(II)>Cr(II)>Cu(II)>Cd(II). The system attained equilibrium about 20 min. The Langmuir and Freundlich adsorption model effectively described the biosorption equilibrium of Cu(II) and Cr(II) ions on waste sludge. Maximum adsorption capacity of Cu(II) and Cr(II) were 196.08 and 158.73 mg/g, respectively. Solid-liquid separation efficiencies were kept above $95\%$ on waste sludge loaded heavy metals, and were decreased with pH increasing.

• Journal of the Korean Society of Manufacturing Process Engineers
• /
• v.21 no.5
• /
• pp.1-8
• /
• 2022

Fused deposition modeling (FDM), based on stacking a continuous filament of polymer or composite materials, is well matured and is thus widely used in additive manufacturing technology. To advance FDM-based 3D printing technology, the mechanical properties of additively manufactured composite materials must be improved. In this study, we proposed a novel FDM 3D printing process using metal wire-polymer composites, enabling enhanced mechanical properties. In addition, we developed a new type FDM filament of copper wire wrapped in nylon material for stable 3D printing without thermal damage during the printing process. After FDM printing of the copper wire-nylon composite filament, we conducted a tensile test to investigate the mechanical behavior of the printed composite materials. The experimental results confirmed that the tensile strength of the 3D-printed metal wire-polymer composites was higher than that of the conventional single polymer material. Thus, we expect that the FDM printing process developed in this study may be promising for high-load-bearing applications.