• Title/Summary/Keyword: Metal-doped

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A Study on the Mg-doped LAS Ceramics Using Metal Alkoxide (금속 알콕사이드를 이용한 Mg-doped LAS계 내열세라믹스의 제조 및 소결에 관한 연구)

  • 김영배;김형태;이응상
    • Journal of the Korean Ceramic Society
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    • v.32 no.1
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    • pp.45-50
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    • 1995
  • In order to densify LAS(Lithuim Aluminosilicate)system compounds, we used metal alkoxides as precursors. Also Mg was added by sol-gel method using metal alkoxides to the LAS system for improving the sinterability, thermal and mechanical properties. The result was that the synthesizing temperature was lowered about 10$0^{\circ}C$, the sintering temperature was lowered by over 10$0^{\circ}C$ and MOR of samples from metal alkoxides was two times larger than that of sample form oxide.

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The doping effect and electronic structure of alkali metal doped tris (8-hydroxyquinoline) aluminum

  • Kim, Ki-Soo;Lee, Jong-Lam
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.1059-1060
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    • 2009
  • We have investigated the pristine alkali metal doping effect which is the Fermi level of alkali metal doped Alq3 shifts toward the LUMO. In-situ measurements of synchrotron radiation photoelectron spectroscopy revealed that the interface dipole or bend bending in previous reports are not the pristine alkali metal doping effect

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Photodecomposition Effect of Metal doped $Ti0_2$ System (I)

  • Jin, Eui;Lee, Kang-Hyeob;Kim, Young-Soon;Min, Tae-Jin;Yu, Kook-Hyun
    • Journal of Photoscience
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    • v.9 no.2
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    • pp.403-405
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    • 2002
  • To study photocatalytic mechanism of metal doped $Ti0_2$, we investigated photodecomposition effect, photocurrent effect and antibacterial effect. When aluminium content was 2 wt %, photodecomposition effect was better than the others. Silver doped thin films had high photocurrent efficiency and antibacterial effect. This reactions were caused by dissolved oxygen in solution and oxygen adsorbed on surface of thin films.

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Top Emission Organic EL Devices Having Metal-Doped Cathode Interface Layer

  • Kido, Junji
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.1081-1081
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    • 2002
  • Top emission organic EL devices were fabricated by using metal-doped cathode interface layer to achieve low drive voltages. Also, facing-targets-type sputtering was used to sputter indium-tin oxide layer on top of organic active layer. The devices fabricated in this study showed reasonably high external quantum efficiency of about 1 % which is comparable to that of bottom-emission-type devices.

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Photocatalytic Decomposition of Methyl Orange over Alkali Metal Doped LaCoO3 Oxides (알칼리족 금속이 첨가된 LaCoO3 산화물에서 메틸 오렌지의 광촉매분해 반응)

  • Hong, Seong-Soo
    • Korean Chemical Engineering Research
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    • v.55 no.5
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    • pp.718-722
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    • 2017
  • We have investigated the photocatalytic activity for the decomposition of methyl orange on the pure $LaCoO_3$ and metal ion doped $LaCoO_3$ perovskite-typeoxides prepared using microwave process. In the case of pure $LaCoO_3$ and cesium ion doped $LaCoO_3$ catalysts, the formation of the perovskite crystalline phase was confirmed regardless of the preparation method. From the results of UV-Vis DRS, the pure $LaCoO_3$ and cesium ion doped $LaCoO_3$ catalysts have the similar absorption spectrum up to visible region. The chemisorbed oxygen plays an important role on the photocatalytic decomposition of methyl orange and the higher the contents of chemisorbed oxygen, the better performance of photocatalyst.

Synthesis and Surface Characterization of Transition Metal Doped Mesoporous Silica Catalysts for Decomposition of N2O (N2O 분해를 위한 전이금속이 도핑된 메조포러스 실리카 촉매의 합성과 표면 특성에 관한 연구)

  • Lee, Kamp-Du;Noh, Min-Soo;Park, Sang-Won
    • Journal of Environmental Science International
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    • v.21 no.7
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    • pp.787-795
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    • 2012
  • The purpose of this study is to synthesize transition metal doped mesoporous silica catalyst and to characterize its surface in an attempt to decomposition of $N_2O$. Transition metal used to surface modification were Ru, Pd, Cu and Fe concentration was adjusted to 0.05 M. The prepared mesoporous silica catalysts were characterized by X-ray diffraction, BET surface area, BJH pore size, Scanning Electron Microscopy and X-ray fluorescence. The results of XRD for mesoporous silica catalysts showed typical the hexagonal pore system. BET results showed the mesoporous silica catalysts to have a surface area of 537~973 $m^2/g$ and pore size of 2~4 nm. The well-dispersed particle of mesoporous silica catalysts were observed by SEM, the presence and quantity of transition metal loading to mesoporous surface were detected by XRF. The $N_2O$ decomposition efficiency on mesoporous silica catalysts were as follow: Ru>Pd>Cu>Fe. The results suggest that transition metal doped mesoporous silica is effective catalyst for decomposition of $N_2O$.

Magnetic Properties of Carbon Chains Doped with 4d Transition Metals

  • Jang, Y.R.;Lee, J.I.
    • Journal of Magnetics
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    • v.13 no.1
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    • pp.7-10
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    • 2008
  • The structural and magnetic properties of functionalized carbon chains doped with 4d transition metals, such as Ru, Rh, and Pd, were investigated using the full-potential linearized augmented plane wave (FLAPW) method. The carbon nanowire doped with Ru exhibited a ferromagnetic ground state with a sizable magnetic moment, while those doped with Rh and Pd had nonmagnetic ground states. For the Ru-doped chain, the density of states at the Fermi level showed large spin polarization, which suggests that the doped nanowire could be used for spintronic applications.

Properties of Dy-doped $La_2O_3$ buffer layer for Fe-FETs with Metal/Ferroelectric/Insulator/Si structure

  • Im, Jong-Hyun;Kim, Kwi-Jung;Jeong, Shin-Woo;Jung, Jong-Ill;Han, Hui-Seong;Jeon, Ho-Seung;Park, Byung-Eun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.140-140
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    • 2009
  • The Metal-ferroelectric-semiconductor (MFS) structure has superior advantages such as high density integration and non-destructive read-out operation. However, to obtain the desired electrical characteristics of an MFS structure is difficult because of interfacial reactions between ferroelectric thin film and Si substrate. As an alternative solution, the MFS structure with buffer insulating layer, i.e. metal-ferroelectric-insulator-semiconductor (MFIS), has been proposed to improve the interfacial properties. Insulators investigated as a buffer insulator in a MFIS structure, include $Ta_2O_5$, $HfO_2$, and $ZrO_2$ which are mainly high-k dielectrics. In this study, we prepared the Dy-doped $La_2O_3$ solution buffer layer as an insulator. To form a Dy-doped $La_2O_3$ buffer layer, the solution was spin-coated on p-type Si(100) wafer. The coated Dy-doped $La_2O_3$ films were annealed at various temperatures by rapid thermal annealing (RTA). To evaluate electrical properties, Au electrodes were thermally evaporated onto the surface of the samples. Finally, we observed the surface morphology and crystallization quality of the Dy-doped $La_2O_3$ on Si using atomic force microscopy (AFM) and x-ray diffractometer (XRD), respectively. To evaluate electrical properties, the capacitance-voltage (C-V) and current density-voltage (J-V) characteristics of Au/Dy-doped La2O3/Si structure were measured.

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Crystal Growth of Transition Metal Ion Doped Rutile

  • Y.M. Yu;Kim, J.Y.;S.J. Jeong
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1998.09a
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    • pp.71-71
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    • 1998
  • Transition metal ions, such as Sc, V, Cr and Fe, doped rutile crystals were grown by Floating Zone method. Growth conditions for high quality of crystals depending on the concentration of doped ions were investigated. Grown crystals were cut and polished to thin wafers, and then various types of defects such as homogeneities, low angle grain boundaries, scattering centers, and oxygen vacancies were analyzed. The effects of transition metal ions on defect formation are discussed. Results and discussions on absorption and fluorescence spectra and electrical properties of grown crystals were also reported.

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