• Title/Summary/Keyword: Metal-air cell, NaCl electrolyte

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Study on the Anode Electrode Reaction in the Metal-Air Cell (금속-공기전지의 Anode전극 반응에 관한 연구)

  • Kim, Yong-Hyuk
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.23 no.12
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    • pp.1002-1006
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    • 2010
  • In this study, magnesium (Mg), zinc (Zn) and aluminium (Al) as anode electrode and the solution of NaCl dissolved with 2~20 wt% as electrolytes were used for the metal-air cell. The open circuit voltage, short circuit current and I-V characteristics upon different kinds of anode electrode and electrolyte concentration were investigated. The open circuit voltage, initially about 1.45 V, rises to 1.6 V during the first 10 minutes indicating the necessity of an induction time to activate the catalyst on the air cathode. The short circuit current increases with an increased concentration of NaCl, causes an increase in the conductivity of the electrolyte solution, but the open circuit voltage did not under undergo influence of electrolyte. From NaCl 20 wt% electrolyte, the maximum output power of the magnesium electrode materials was measured with 177mW. It is found that the power characteristics of metal-air cell could be improved by using magnesium electrode materials in the NaCl electrolyte.

The Effect of Ion Exchange Membrane on the Electrical Conduction in Metal Fuel Cell (금속연료전지에서 이온교환막이 전기전도에 미치는 영향)

  • Kim, Yong-Hyuk
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.59 no.12
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    • pp.2235-2239
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    • 2010
  • In this study, The cation exchange membrane and the anion exchange membrane affect in electrical conduction of metal fuel cell was investigated. Magnesium material as anode electrode and the NaCl solution dissolved with 5~15wt% as electrolyte were used for the metal fuel cell. It was found that magnesium slag where flows toward the air electrode was suppressed by using ion exchange membrane. The open circuit voltage variation during discharge has very flat pattern by using ion exchange membrane, but the case which is not the exchange membrane, the open circuit voltage increased according to time. When using the anion exchange membrane, the electric current was higher case of the cation exchange membrane, as a result of higher equivalent conductivity in anion Cl-. The cation exchange membrane was observed with the fact that the output power is excellent in compared with anion exchange membrane.

The Effect of Load Conditions for the Power of Mg-Air Fuel Cell (부하조건이 마그네슘-공기연료전지의 출력특성에 미치는 영향)

  • Kim, Yong-Hyuk
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.61 no.3
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    • pp.134-139
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    • 2012
  • The power characteristics of the Mg-Air fuel cell were investigated with regard to variation of load conditions. The types of load current using for the Mg-Air fuel cell with 10% NaCl electrolyte were step type, ramp type and pulse type. It was found that transient phenomena occurred in the step current load, which is due to activate of the oxidation-reduction reaction process. And the transient time increase with the load current increase. In the load current of ramp type, the slop of voltage drop increased with current load slop ${\alpha}$ increase. The load voltage and power decreased according to the pulse period of load current decrease were attributed to the metal sludges.