• Title/Summary/Keyword: Metal recovery

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Effects of process variables on morphology of palladium metal deposit in hydrochloric acid medium

  • kim Min-Seuk;Lee Jae-Chun;Kim Won-Back;Jeong Jin-Ki;Nam Chul-Woo
    • 한국지구물리탐사학회:학술대회논문집
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    • 2003.11a
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    • pp.642-647
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    • 2003
  • Palladium is widely used for several applications and recovery of palladium from secondary sources becomes increasingly important since palladium is one of maldistributed platinum group metals. Electrochemical recovery of dense palladium metal sheet from Pd leaching solution is a simple and easily controlled method. The surface morphology of the recovered Pd metal was significantly affected by current density and temperature. Dense deposit morphology was in higher stress state regardless of preparation condition under $55^{\circ}C$. Rising temperature up to $70^{\circ}C$ had a stress releasing effect besides densification of Pd deposit.

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Biosorption Technology Using Algal Biomass in Canadian Environment Industries (캐나다 환경산업의 조류 바이오매스 이용 생흡착 기술)

  • Volesky, Bohumil;Kong, Surk-Key
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 2005.11a
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    • pp.3-14
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    • 2005
  • We Investigated minutely how the biosorption technology using algal biomass is opened in Canadian technology society. Making comparative study for relative technologies in views of overall unit operation cost, we could grasp next facts. - Algal biomass plays the competitive performance for various metals. - Algal biomass biosorbent is regenerated. - Reactor system is not and involved one. This means that algal biomass occupies the strong position as biosorbent. Especially, in North America, for the purpose of metal bearing wastewater treatment, 20 hundred million US dollars was appropriated a sum for the purchase of ion exchange resin. But it is only thirty million US dollars if algal biomass biosorbent is used on behalf of ion exchange resin. Furthermore, the expenses for same treatment can be cut down additively through metal recovery.

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A Study on the Measurement for the Recovery Stress of Intelligent Composite by Experiment (실험법에 의한 지능성 복합체의 회복응력 측정에 관한 연구)

  • Hawong, Jai-Sug;Lee, Hyo-Jae
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.27 no.4
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    • pp.515-523
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    • 2003
  • Shape memory is physical phenomenon which a platically metal is restored to its original shape by a solid state phase change by heating. TiNi alloy the most effective material in the shape memory alloy(SMA). To study(measure) recovery stress of intelligent composite. Ti50-Ni50 shape memory matrix with prestrain SMA fiber. When SMA fiber of the intelligent composite is heated over austenite starting temperature(As) by electric heating. a recovery stress are generated. The recovery stress of the intelligent composite was measured by strain gage or photoelastic experiment. Measuring method of recovery stress by photoelastic experiment was developed in this research. It was certified that photoelastic experiment was more effective and more precise than strain gage method in the measurement of recovery stress.

The Study of Hydrometallurgical Process for Recovery of Zinc from Electric Arc Furnace Dust (습식산화법을 이용한 제강분진 내 아연회수에 관한 연구)

  • Moon, Dea-Hyun;Jeung, Jae-Hoon;Chang, Soon-Woong
    • Journal of Environmental Science International
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    • v.25 no.2
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    • pp.331-336
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    • 2016
  • In this study the optimum conditions for recovery of valuable metal in Electric Arc Furnace Dusts were investigated. 2M of $H_2SO_4$, 1~5 of solid/liquid ratio, 0~180 min of leaching time has been established for leaching condition, and for electrowinning, each of Pt, C, Zn, Pb anode and Zn, Cu cathode was compared respectively at pH 2, 4 and 6. The result of elemental analysis of Zn crystal, a lagre quantity of Fe and H has been observed with Zn and other heavy metal, therefore, impurities removing process would be requir for enhancing purity of Zn. As the result, about 60% of Zn has been recovered under condition of 2 M of $H_2SO_4$, 1:2 of S/L ratio at 120 min, and Pt or Pb for anode, Zn for cathode has been shown the highest efficiency of electrowinning at pH 6.

Recovery of Heavy-Metallic Components from a Waste Electro-polishing Solution of 316L Steel by the Solar Cell Electricity (태양전지 전력을 이용한 316L강의 전해연마 폐액 중 중금속 성분의 회수)

  • Kim, Ki-Ho;Jang, Jung-Mok
    • Journal of the Korean institute of surface engineering
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    • v.42 no.1
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    • pp.53-57
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    • 2009
  • Recovery of heavy-metallic component from a waste solution of factory was undertaken by the solar cell electricity. The solution was obtained from an electrolytic etching process of 316L stainless steel. The electrolysis of the solution for recovery of heavy metallic components was made with platinum plated titanium mesh anode and copper plate cathode. Analysis for the solution and electro-winned materials were made by EDS, XRD and SEM. Iron, chromium, and sulfur components were recovered on the cathode from the solution. Result of EDS analysis for the electro-winned materials revealed that some metal oxide were contained in the recovered material. The recovered materials were expected to have metallic form only by the electrolysis, but metal compounds were contained because of weak solar cell power. Nickel and manganese component in the solution doesn't recovered by this electrolysis process, but they made a sludge with phosphoric acid in the solution.

Effects on Tensile Strength of Base and Weld Metal of Ti-6Al-4V Alloy in Short Time Exposure to High Temperature (Ti-6Al-4V 합금의 단시간 고온 노출 시 모재 및 용접부의 인장강도 특성)

  • Chae, Byoung-Chan
    • Journal of the Korea Institute of Military Science and Technology
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    • v.17 no.4
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    • pp.413-421
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    • 2014
  • Since the structural temperature of a flight vehicle flying at high speed rises rapidly due to aerodynamic heating, it is necessary for optimum structural design to obtain proper material properties at high temperature by taking into account of its operational environment. For a special alloy, analysis data on strength change due to exposure time to high temperature are very limited, and most of them are for an exposure time longer than 30 minutes for long term operations. In this study, base and weld metal samples of Ti-6Al-4V alloy had been prepared and high temperature tensile tests with induction heating were performed, and then high temperature strength characteristics and strength recovery characteristics through cooling have been analyzed. Pre-tests to determine maximum heating rate were performed, and response characteristics for temperature control were confirmed. As a result, high temperature tensile strength appeared to be lower than that of room temperature, but it was higher than that of high temperature of 30 minite exposure listed in MMPDS. In strength recovery through cooling Ti-6Al-4V alloy has shown higher recovery rate compared with other alloys.

Trend on the Metal Recovery Technologies from Electric and Electronic Equipment Manufacturing Process Wastes (전기전자제품(電氣電子製品)의 제조공정(製造工程)에서 발생(發生)하는 폐기물(廢棄物)로부터 금속회수(金屬回收)에 관한 기술(技術) 동향(動向))

  • Jeong, Jinki;Shin, Doyun;Lee, Jae-Chun;Park, Sang-Woo
    • Resources Recycling
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    • v.21 no.4
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    • pp.26-34
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    • 2012
  • Recently, the recovery of resources from waste material of manufacturing electric and electronic equipment has been investigated. It is very important to extract metallic components from electric and electronic manufacturing processes with the view point of recycling of the used resources as well as an environmental protection. In this paper, open/registered patents of US, JP, EP, and KR and SCI journal related to metal recovery technologies from wastes produced in the electric and electronic manufacturing processes between 1975~2011 were reviewed. Patents and papers were collected using key-words searching and filtered by filtering criteria. The trends of the patents and papers were analyzed by the years, countries, companies, and technologies.

Study on recovery of heavy metals from red mud by using the ultrasonic waves (초음파를 이용한 레드머드로부터 유가금속 회수에 관한 연구)

  • Lim, Ki-Hyuk;Shon, Byung-Hyun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.1
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    • pp.906-913
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    • 2015
  • The red mud generated from the Bayer alumina production process seriously threatens the environment and human safety. Therefore, the reduction and recycling of red mud is an urgent topic in the aluminum industry. In this study, the effects of four parameters, ultrasound power, reaction temperature, time, and acid concentration, on the leaching of Fe, Al from red mud was investigated. The major parameters influencing the metal recovery efficiency from red mud were ultrasound power and reaction temperature. The use of ultrasonic irradiation resulted in 1.72 and 1.28 times higher recovery efficiency for Fe and Al, respectively. The proper conditions for the recovery of the metal components present in the red mud is the ultrasound intensity (150 W), sulfuric acid concentration (4-6N), reaction temperature ($70^{\circ}C$), and reaction time (2 hours), etc.

Recovery of Pd(II), Pt(IV), and Rh(III) Using Polyelectrolytes

  • Lee, You-Sean;Lee, Hoosung;Chung, Koo-Soon
    • Analytical Science and Technology
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    • v.8 no.4
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    • pp.561-568
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    • 1995
  • Two methods, precipitation and ultrafiltration, were applied in order to recover platinum group metals(PGM) by complexing them with water-soluble polyelectrolytes, e.g., polyethyleneimine [PEl], poly(2-vinylpyridine) [2-PVP], poly (4-vinylpyridine) [4-PVP], and poly (styrene sulfonic acid) [PSSA]. In the precipitation method, the PGM-polyelectrolyte complex that was formed by mixing first with polybase, e.g.,4-PVP at pH 1 was precipitated by further mixing with polyacid, e.g., PSSA. However, the recovery of PGM obtained by this method was not quantitative(less than 70%). The "sandwiching" binding between the metal anions and two polyelectrolytes was examined by X-ray photoelectron spectroscopy(XPS). The XPS studies indicated that the PGM atom was bound with the acdic and basic polyelectrolyte via its oxygen and nitrogen atom, respectively. The recovery of PGM using polyelectrolyte was further studied by ultrafiltration methods as follows : The PGM ions, eomplexed at pH 1 with polyelectrolyte, allowed the applicntion of membrane filtration by virtue of the great differences in molecular weights between PGM and other low molecular weight species. By applying this method, Pd and Pt (ca. $10^{-4}M$) were selectively separated almost quantitatively from coexisting metal ions, e.g., $Cu^{2+}$ and $Ni^{2+}$. The EPR spectra and viscosity measurements indicated that these polyelectrlytes were not bound to $Cu^{2+}$ and $Ni^{2+}$ ions at this pH, which provided the basis for selective separation of PGM(Pd, Pt and Rh) from these coexisting ions.

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R&D Trends of Rare Metals Recovery from Seawater (해수(海水)로부터 희유금속(稀有金屬) 회수(回收) 연구동향(硏究動向))

  • Kim, Jong-Heon;Noh, Kyung-Ran;Kim, Sang-Woo;Choi, Sung-Bae;Kil, Sang-Cheol
    • Resources Recycling
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    • v.22 no.6
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    • pp.73-80
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    • 2013
  • Marine mineral resources are classified into submarine and seawater mineral resources. In seawater, huge amounts of useful minerals, such as uranium, lithium, magnesium, aluminum, zinc, iron, silver, copper, vanadium, nickel, titanium and cobalt are present. If the rare metals recovery technology from seawater is developed, the commercialization of the precess will be possible. For the 21st century, countries rich in resoures tend to weaponize the resources, according to the depletion of reserves and quality degradation of metal resources in the land. Therefore, Korea that relies on imports for most of the metal resources, should focus on the research and development of the rare metals recovery technology from seawater by using the geographical characteristics of the country that is on three sea-sides.