• Title/Summary/Keyword: Metal composite

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Pre-shaping of ionic polymer metal composite actuators by heat treatment and characterization (이온성 고분자 금속 복합물(IPMC) 액추에이터의 열처리에 의한 성형 및 특성분석)

  • Park, Shin-Ho;Kim, Dong-Ik;Park, Man-Jun;Lee, Seung-Ki
    • Journal of Sensor Science and Technology
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    • v.18 no.5
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    • pp.353-358
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    • 2009
  • Ionic polymer metal composite(IPMC) has been used as a promising material for various actuator applications. The IPMC actuator is difficult to be fabricated with complicated 3-dimensional shape. We propose a simple heat treatment process that can fabricate IPMC actuator with various shapes. Experimental results show the pre-shaped IPMC actuator by heat treatment does not show any degradation of its actuation abilities such as bending displacement, generation force and reliability in bending motion.

Dielectric characteristics of PMMA-PZT coated Ni Composites (PMMA-PZT coated Ni 복합체의 유전특성)

  • Jeong, Won-Chae;Lee, Hee Young;Kim, Jeong-Joo;Im, Eun-Seop
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.349-349
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    • 2005
  • 수동소자를 PCB(Printed Circuit Board) 안으로 집적하기 위한 방법의 일환으로 polymer-metal, polymer-ceramic composite에 연구가 국내외 연구 국내외 연구기관에서 광범위하게 진행되고 있다. 본 연구에서는 polymer-metal-ceramic composite 에서 PZT-coated Ni의 volume fraction에 따른 유전율 변화에 대하여 조사하였다. 원료로는 PZT(52/48) solution. 니켈금속분말, PMMA(polymethyl methacrylate)를 사용하였다. 전기적 특성은 임피던스분석기를 이용하여 측정하였으며 mixing rule과 percolation theory를 이용하여 결과를 해석하였다.

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The Effect of Crosslinking on the Actuation of Electroactive IPMC Prepared with Fluoroalkyl Methacrylate/Acrylic Acid/HEMA Copolymer (Fluoroalkyl Methacrylate/Acrylic Acid/2-HEMA 공중합체로 제조한 IPMC의 구동 특성에 미치는 가교의 영향)

  • Jeong, Han-Mo;La, Young-Soo
    • Polymer(Korea)
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    • v.29 no.5
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    • pp.463-467
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    • 2005
  • In order to enhance the actuation force of ionic polymer-metal composite (IPMC) made with the acrylic copolymer of fluoroalkyl methacryate, acrylic acie, and 2-hydroxyethyl methacrylate(HEMA), the hydroxy group of HEMA was corsslinked with 1,3-diethoxy-1,1,3,3-tetramethyldisiloxane. The water uptake was reduced and the mechanical strengths and the actuation force of the membrane was improved by crosslinking. However, current and deformation responses of IPMC were decreased by crosslinking.

A Study on the Pd-Ni Alloy Hydrogen Membrane using the Porous Nickel Metal Support (다공성 Ni 금속 지지체를 사용한 Pd-Ni 합금 수소 분리막 연구)

  • Kim Dong-Won;Um Ki-Youn;Kim Sang-Ho;Park Jong-Su
    • Journal of the Korean institute of surface engineering
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    • v.37 no.5
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    • pp.289-295
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    • 2004
  • A dense palladium-nikel (Pd-Ni) alloy composite membrane has been fabricated on microporous nickel support mixed with submicron/micron nickel powder instead of mesoporous stainless steel support. Plasma treatment process is introduced as pre-treatment process instead of HCI activation. Pd-Ni alloy composite membrane prepared by electro plating was fairly a uniform and dense surface morphology. The membrane was characterized by permeation experiments with hydrogen and nitrogen gases at temperature 773 K and pressure 2.2 psi. The results showed that hydrogen ($H_2$) permeance was 27 ml/$\textrm{cm}^2$ㆍatmㆍmin and hydrogen/ nitrogen ($_H2$$N_2$) selectivity was 8 at 773 K.

Microstructure and Mechanical Properties of TiC-Co/Al Composites Prepared by Reaction-Bonded Sintering (반응결합 소결에 의한 TiC-Co/Al 복합체의 미세구조 및 기계적 특성)

  • 한인섭;남기웅;정윤중
    • Journal of the Korean Ceramic Society
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    • v.32 no.2
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    • pp.257-269
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    • 1995
  • The TiC-Co/Al reaction-sintered products were prepared by the infiltration of various Co/Al metal mixture into the preform, and their microstructure, phases, and mechanical properties were investigated. With increasing the atomic ratio of Co/Al, tiC grain shape was changed from spherical to platelet particles, and the grain size increased. The crystalline phases found in the liquid matrix formed by the infiltration of Co/Al metal mixture were determined to be Al5Co2 and AlCo by EDS and XRD, and the two crystalline phases were located dominantly between TiC grains, when the Co/Al atomic ratio was lower than an unity. There was a tendency that the density, bending strength and fracture toughness increase with Co/Al atomic ratio until the infiltrated metal was 100% Co. The maximum value was achieved by the composition containing 100% Co infiltrated metal. The Vickers hardness decreased as Co/Al atomic ratio increased.

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Examination of Dust Trapping Mechanism in a Metal Fiber Filter-bed (금속 섬유 필터층을 이용한 미세 분진 집진 성능 관찰)

  • 이경미;조영민
    • Journal of Korean Society for Atmospheric Environment
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    • v.20 no.3
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    • pp.361-369
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    • 2004
  • A metal fiber bed has seldom been applied to the practical filtration process despite its excellent mechanical and chemical stability. The filter-bed used in this work was highly porous with open structure, of which apparent porosity was 80 ∼ 90%. Although pressure loss across the filter-bed was very low, separation efficiency was found to be quite high. This paper focuses on the basic filtration mechanisms of a metal filter-bed and a thin ceramic filter from fly ash for reference. The experimental parameters were face velocity, dust loading and porosity of filter-bed. Pressure drop increased with increasing face velocity and dust feeding load for both filters. It also showed that dust particles deposited in the deep flow path, finally resulting in clogging the pore channels. It thereby indicates that the dominating mechanism of the metal filter-bed would be depth filtration. Meanwhile, the thin fly ash composite filters trapped the aerated dust mainly on the surface of the filter medium, so that the instantaneously formed dust layer might cause a steep increase of pressure drop across the filtration system.

Infiltration Processing of Ceramic-Metal Composites: The Role of Wettability, Reaction, and Capillary Flow

  • Asthana Rajiv;Singh Mrityunjay;Sobczak Natalia
    • Journal of the Korean Ceramic Society
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    • v.42 no.11 s.282
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    • pp.703-717
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    • 2005
  • The infiltration of ceramics by liquid metals to fabricate ceramic-metal composites is discussed. In particular, the complexity of infiltrating ceramics by liquid metals at high temperatures due to interfacial reactions, metal oxidation, pore modulation and closure, and transient capillary forces has been highlighted. The role of these factors is discussed in the context of reactive infiltration with examples from ceramic/metal composites of practical interest. In addition to flow through porous ceramics, reactive penetration of dense ceramics via chemical dissolution and reaction is also discussed.

The Preparation of Non-aqueous Supercapacitors with Lithium Transition-Metal Oxide/Activated Carbon Composite Positive Electrodes

  • Kim, Kyoung-Ho;Kim, Min-Soo;Yeu, Tae-Whan
    • Bulletin of the Korean Chemical Society
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    • v.31 no.11
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    • pp.3183-3189
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    • 2010
  • In order to increase the specific capacitance and energy density of supercapacitors, non-aqueous supercapacitors were prepared using lithium transition-metal oxides and activated carbons as active materials. The electrochemical properties were analyzed in terms of the content of lithium transition-metal oxides. The results of cyclic voltammetry and AC-impedance analyses showed that the pseudocapacitance may stem from the synergistic contributions of capacitive and faradic effects; the former is due to the electric double layer which is prepared in the interface of activated carbon and organic electrolyte, and the latter is due to the intercalation of lithium ($Li^+$) ions. The specific capacitance and energy density of a supercapacitor improved as the lithium transition-metal oxides content increased, showing 60% increase compared to those of supercapacitor using a pure activated carbon positive electrode.

Effect of Cobalt Loading on the Performance and Stability of Oxygen Reduction and Evolution Reactions in Rechargeable Zinc-air Batteries

  • Sheraz Ahmed;Joongpyo Shim;Gyungse Park
    • Journal of the Korean Chemical Society
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    • v.68 no.2
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    • pp.87-92
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    • 2024
  • The commercialization of rechargeable metal-air batteries is extremely desirable but designing stable oxygen reduction reaction (ORR) catalysts with non-noble metal still has faced challenges to replace platinum-based catalysts. The nonnoble metal catalysts for ORR were prepared to improve the catalytic performance and stability by the thermal decomposition of ZIF-8 with optimum cobalt loading. The porous carbon was obtained by the calcination of ZIF-8 and different loading amounts of Co nanoparticles were anchored onto porous carbon forming a Co/PC catalyst. Co/PC composite shows a significant increase in the ORR value of current and stability (500 h) due to the good electronic conductive PCN support and optimum cobalt metal loading. The significantly improved catalytic performance is ascribed to the chemical structure, synergistic effects, porous carbon networks, and rich active sites. This method develops a new pathway for a highly active and advantageous catalyst for electrochemical devices.

Mechanics model of novel compound metal damper based on Bi-objective shape optimization

  • He, Haoxiang;Ding, Jiawei;Huang, Lei
    • Earthquakes and Structures
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    • v.23 no.4
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    • pp.363-371
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    • 2022
  • Traditional metal dampers have disadvantages such as a higher yield point and inadequate adjustability. The experimental results show that the low yield point steel has superior energy dissipation hysteretic capacity and can be applied to seismic structures. To overcome these deficiencies, a novel compound metal damper comprising both low yield point steel plates and common steel plates is presented. The optimization objectives, including "maximum rigidity" and "full stress state", are proposed to obtain the optimal edge shape of a compound metal damper. The numerical results show that the optimized composite metal damper has the advantages such as full hysteresis curve, uniform stress distribution, more sufficient energy consumption, and it can adjust the yield strength of the damper according to the engineering requirements. In view of the mechanical characteristics of the compound metal damper, the equivalent model of eccentric cross bracing is established, and the approximate analytical solution of the yield strength and the yield displacement is proposed. A nonlinear simulation analysis is carried out for the overall aseismic capacity of three-layer-frame structures with a compound metal damper. It is verified that a compound metal damper has better energy dissipation capacity and superior seismic performance, especially for a damper with double-objective optimized shape.