• 소성∙가공
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• 제24권6호
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• pp.395-399
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• 2015

A microstructure-based finite element simulation was conducted to predict the plastic strain ratio (R-value) of a dual-phase (DP) steel. The representative volume elements (RVEs) concept was adopted for the image-based FE modeling and a 3D model was constructed using sequential 2D images. Each phase was considered with the von-Mises yield criterion and the Swift model. The Swift parameters were defined by the empirical equations based on the chemical composition. The developed model was applied to analyze the effect of residual stress on the R-value and stress distribution. In order to consider the residual stress development after cold rolling, 10 % compression was applied in the thickness direction and unloaded before the tensile stress was applied in the rolling direction. The results showed a reasonable prediction for the R-value evolution: a sharp increase at small strains was well described and a transition followed in the downward direction. The R-value evolution was analyzed using the stress distribution change on the π-plane

• 상하수도학회지
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• 제21권6호
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• pp.671-678
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• 2007

2-methylisoborneol (MIB) is a musty odor compound produced as a secondary metabolite by some cyanobacteria and actinomycetes. It is lead to distrust in tap water due to taste and odor. It is well known that activated carbon (AC) adsorption is the best available technology to remove 2-MIB and geosmin. In this study, physical characteristics of virgin AC and reactivated AC was compared. The effect of variation of NOM molecular weight on adsorption of 2-MIB in virgin AC and reactivated AC were also evaluated. BET surface area was decreased by 13 to 23% and total pore volume was decreased by 18 to 21% due to first and second reactivation compare to the virgin carbon. However, mesopore volume ($V_{meso}$) was increased about 14% after reactivation. It showed that micropore volume was decreased and move to mesopore or macropore after reactivation. Decreased adsorption capacity of 2-MIB was greatly related to below 3000Da. Adsorption capacity of 2-MIB was rather greater in virgin AC than in reactivated, which is strongly related to micropore volume.

• Journal of Advanced Marine Engineering and Technology
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• 제39권8호
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• pp.838-842
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• 2015

The Li-air battery is a promising candidate for the most energy-dense electrochemical power source because it has 5 to 10 times greater energy storage capacity than that of Li-ion batteries. However, the Li-air cell performance falls short of the theoretical estimate, primarily because the discharge terminates well before the pore volume of the air electrode is completely filled with lithium oxides. Therefore, the structure of carbon used in the air electrode is a critical factor that affects the performance of Li-air batteries. In a previous study, we reported a new class of carbon nanomaterial, named carbon nanoballs (CNBs), consisting of highly mesoporous spheres. Structural characterization revealed that the synthesized CNBs have excellent a meso-macro hierarchical pore structure, with an average diameter greater than 10 nm and a total pore volume more than $1.00cm^3g^{-1}$. In this study, CNBs are applied in an actual Li-air battery to evaluate the electrochemical performance. The formation mechanism and electrochemical performance of the CNBs are discussed in detail.

• Korean Chemical Engineering Research
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• 제47권3호
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• pp.368-372
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• 2009

흡착제의 흡착특성인 흡착표면적과 세공크기를 수정진동자를 이용하여 측정하는 방법을 제안하고 그 성능을 조사하였다. 액체질소를 활용하는 기존의 방법에 비해 상온에서 이산화탄소를 이용하기 때문에 장치가 소형이고, 조작이 간편하며 짧은 흡착시간 내 측정이 가능한 이점을 가지고 있다. 마이크로 입자의 카본 크라오젤과 대나무 활성탄에 대해 흡착특성을 측정한 측정치를 흡착능 측정기로 측정한 측정치와 비교한 결과 메조세공의 흡착제에 대해서는 유효한 측정치가 얻어진 반면 마이크로 세공의 입자에서는 다소 큰 오차를 나타내었다.

• Bulletin of the Korean Chemical Society
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• 제32권3호
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• pp.768-778
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• 2011

Calixpyrroles and related macrocycles are non-planer synthetic anion receptors that have attracted considerable attentions in recent years. Although the synthesis of calix[4]pyrrole (known as meso-octamethylporphyrinogen) was reported more than 100 years ago, the anion binding properties were first discovered in 1996. The simple calix[4]pyrroles can be synthesized in single step in high yield by condensation of pyrrole with acetone. The compounds showed preferential binding for halide anions including fluoride, phosphate, carboxylate, and chloride in organic media. Efforts to improve the anion affinity of calix[4]pyrrole and to enhance its selectivity have led to the synthesis of a variety of new calixpyrrole derivatives. Among the various modifications, introduction of straps on one side of the calix[4]pyrroles are the most effective. Incorporation of aromatic rings other than pyrroles also exhibited interesting binding behaviour. Introduction of signalling units as part of the strapping element enable to detect the anions on chromogenic or fluorogenic fashion. Finding of the anion transport properties across the membrane and cytotoxic effects of the calix[4]pyrroles open new window for calixpyrrole-related research. The polymer-incorporated systems have also been employed as anion complexants in solvent-solvent extraction. These old, yet easy-to-make macrocycles have well advanced more recently with the discovery of the ion-pair complexation properties. In this review, the synthetic developments and anion binding properties of calixpyrroles for the last decades will be discussed and will cover the advances in calixpyrrole chemistry.

• Bulletin of the Korean Chemical Society
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• 제31권6호
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• pp.1638-1642
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• 2010

Mesoporous carbon CMK-3s with different textural properties have been used for the adsorption of phenol to understand the necessary physicochemical properties of carbon for the efficient removal of phenol from contaminated water. The kinetic constants (both pseudo-second order and pseudo-first-order kinetics) increase with increasing pore size of carbons. The maximum adsorption capacities correlate well with micropore volume compared with surface area or total pore volume even though large pore (meso or macropore) may contribute partly to the adsorption. The pore occupancies also explain the importance of micropore for the phenol adsorption. For efficient removal of phenol, carbon adsorbents should have large micropore volume and wide pore size for high uptake and rapid adsorption, respectively.

• 디지털융복합연구
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• 제9권4호
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• pp.91-101
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• 2011

본 연구는 인공지능 네트워크 시스템의 개발을 위해 존재하는 방법론들이 어떠한 것이 있는지를 연구하고자 한다. 인공지능 네트워크 개발에 대해 현재 발표된 것과 방법론을 명확히 하기위한 관점들을 측정하였으며 그것은 이러한 네트워크 개발에 이용되었다. 광범위한 이러한 방법론들을 어떻게 범주화하고, 만약 이런 방법론들이 인공지능 네트워크 개발에 대한 일반적, 근본적이고 포괄적인 방법론으로 증명할 수 있는지, 그리고 이런 방법론들이 기존 시스템 개발 방법론들과 어떻게 다른지 본 연구를 통해 시험했다.

• Journal of Information Science Theory and Practice
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• 제11권2호
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• pp.37-66
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• 2023

Scientometrics and research evaluation describe and analyze research publications when conducting publication, citation, and topic analyses. However, what exactly is a (scientific, academic, scholarly or research) publication? This article demonstrates that there are many problems when it comes to looking in detail at quantitative publication analyses, citation analyses, altmetric analyses, and topic analyses. When is a document a publication and when is it not? We discuss authorship and contribution, formally and informally published documents, as well as documents in between (preprints, research data) and the characteristics of references, citations, and topics. What is a research publication? Is there a commonly accepted criterion for distinguishing between research and non-research? How complete and unbiased are data sources for research publications and sources for altmetrics? What is one research publication? What is the unit of a publication that causes us to count it as "1?" In this regard, we report problems related to multi-author publications and their counting, weighted document types, the unit and weighting of citations and references, the unit of topics, and counting problems-not only at the article and individual researcher level (micro-level), but also at the meso-level (e.g., institutions) and macro-level (e.g., countries). Our results suggest that scientometric counting units are not reliable and clear. Many scientometric and research evaluation studies must therefore be used with the utmost caution.

• Geomechanics and Engineering
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• 제36권2호
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• pp.121-130
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• 2024

Many foundation projects are built on red-bed soft rocks, and the damage evolution of this kind of rocks affects the safety of these projects. At present, there is insufficient research on the damage evolution of red-bed soft rocks, especially the progressive process from mesoscopic texture change to macroscopic elastoplastic deformation. Therefore, based on the dual-porosity characteristics of pores and fissures in soft rock, we adopted a cellular automata model to simulate the propagation of these voids in soft rocks under an external load. Further, we established a macro-mesoscopic damage model of red-bed soft rocks, and its reliability was verified by tests. The results indicate that the relationship between the number and voids size conformed to a quartic polynomial, whereas the relationship between the damage variable and damage porosity conformed to a logistic curve. The damage porosity was affected by dual-porosity parameters such as the fractal dimension of pores and fissures. We verified the reliability of the model by comparing the test results with an established damage model. Our research results described the progressive process from mesoscopic texture change to macroscopic elastoplastic deformation and provided a theoretical basis for the damage evolution of these rocks.

• 한국환경복원기술학회지
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• 제10권1호
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• pp.57-71
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• 2007

While a concept on biotop or the urgency of its classification systems have been under discussion recently, this study aims to examine outdoor biotop classification systems for environment-friendly community. To this end, the feasibility of creating a biotop in the community and application elements were generated and biotops were classified and categorized. Then, elements that can be applied in consideration of traditional Korean techniques were generated and biotop classification systems and specific components in residential areas were reviewed. As for the result of this study, based on a preliminary draft prepared through literature review, considerations for biotop classification systems were taken into account. Then, based on classification criteria for biotop formats, biotop functions and biotop types, a second-tier classification system was developed. Criteria for biotop formats included surfaces, lines and points while criteria for biotop functions were large cores, small bases, corridors, stepping stones and ecological islands. Criteria for habitat types were divided to include natural forest, developed green areas, lacustrine wetland, palustrine wetland, shrubs, grasslands, linear habitats, vacant plots and practical green areas, which were sub-categorized. As for the biotop classification system, macro-classification divided biotops into three types-space, line and point-based on biotop formats. Meso-classification had five groups and micro-classification had 21 groups based on habitat types. Future studies should focus on the ecological features of each biotop categories generated in this study and their creation and management techniques to find many practical methods to create, protect and manage outdoor biotop for environment-friendly community.