• Title/Summary/Keyword: Mercury-containing Waste

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Efficient Management System for Mercury-containing Waste according to the Current Status of Spent Fluorescent Lamps (폐형광등 현황에 따른 수은함유폐기물의 효율적 관리 방안)

  • RHEE, Seung-Whee;Park, Hun-Su;Yoo, Ho-Sik
    • Journal of Environmental Policy
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    • v.14 no.1
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    • pp.135-158
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    • 2015
  • An efficient management system of mercury-containing waste was designed by reviewing the management and treatment of spent fluorescent lamp in Korea and foreign countries. According to Waste Management Act in Korea, mercury-containing wastes from households are classified as municipal solid wastes even though mercury-containing wastes pose hazardous risks. In general, hence, mercury-containing wastes from households are not being managed properly because those wastes from households were not classified as specific wastes (or hazardous wastes). Some mercury-containing wastes are managed as a mandatory target item in waste charge system and Extended Producer Responsibility (EPR) system under Act on Promotion for Saving and Recycling of Resources. An efficient management plan of mercury-containing wastes can be derived with an improved collection system, designating disposal sites and advanced treatment facilities for spent fluorescent lamps. Finally, the role of each agent involved from collection to disposal of mercury-containing wastes was suggested to establish the efficient management system for mercury-containing waste.

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Trace Mercury Determination by Differential Pulse Anodic Stripping Voltammetry Using Polythiophene-Quinoline/Glassy Carbon Modified Electrode

  • Yoo, Kwang-Sik;Woo, Sang-Beom;Jyoung, Jy-Young
    • Bulletin of the Korean Chemical Society
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    • v.24 no.1
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    • pp.27-31
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    • 2003
  • A Polythiophene-quinoline/glassy carbon (PTQ/GC) modified electrode was developed for the determination of trace mercury in industrial waste water, natural water, soil, and other media. The electrode was prepared by the cyclic voltammetric polymerization of thiophene and quinoline on glassy carbon (GC) electrode by the potential application from -0.6 V to +2.0 V (50 mV/sec) in a solution of 0.1 M thiophene, quinoline and tetrabutyl ammonium perchlorate (TBAP) in acetonitrile. Optimum thickness of the polymer membrane on the GC electrode was obtained with 20 repeated potential cyclings. The redox behavior of Cu(Ⅱ) and Hg(Ⅱ) were almost identical on this electrode. The addition of 4-(2-pyridylazo)resorcinol (PAR) to the solution containing Cu(Ⅱ) and Hg(Ⅱ) allowed the separation of the components due to the formation of the Cu(Ⅱ)-PAR complex reduced at -0.8V, which was different from the Hg(Ⅱ) reduced at -0.5 V on a saturated calomel electrode (SCE). The calibration graph of Hg(Ⅱ) shows good linear relationship with the correlation factor of 0.9995 and the concentration gradient of 0.33 ㎂/㎠/ppb down to 0.4 ppb Hg. The method developed was successfully applied to the determination of mercury in samples such as river, waste water, and sea water.

Stabilization and solidification of tailings from a traditional gold mine using Portland cement

  • Rachman, Ranno Marlany;Bahri, Ayi Syaeful;Trihadiningrum, Yulinah
    • Environmental Engineering Research
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    • v.23 no.2
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    • pp.189-194
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    • 2018
  • The traditional gold mining in Kulon Progo district, Special Region of Yogyakarta Province produced tailings containing mercury (Hg) from the gold amalgamation process. Mercury accumulated in tailings has 164.19 mg/kg - 383.21 mg/kg in total concentration. Stabilization/solidification (S/S) is one of the remediation technologies to reduce waste pollution. Portland cement is one of the additive materials in S/S that effective encapsulates heavy metal waste. The aim of this research is to know the optimum composition of tailings mixture with Portland cement in S/S process. This research used variation of tailings composition. Variation of Portland cement composition with tailing are 100:0, 90:10, 80:20, 70:30, 60:40, 50:50, 40:60, 30:70, 20:80 and 10:90. The result of this study found that the optimum composition of Portland cement: tailings was 10:90, with compression test of $257ton/m^2$ and TCLP test was 0.0069 mg/L. The compression test results were in accordance to US EPA Standard quality of $35ton/m^2$. TCLP test results meet the standard of Indonesian Government Regulation No. 101 Year 2014 of 0.05 mg/L.

Study on the Pre-treatment for Quantitative Analysis of Mercury in Paper Packaging Materials (지류포장재에서의 수은 정량분석을 위한 전처리 방법 연구)

  • Ko, Seung-Tae;Lee, Tai-Ju;Park, Ji-Hyun;Kim, Hyoung-Jin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.42 no.5
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    • pp.67-73
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    • 2010
  • Paper packaging materials are essential in protection and transportation of commercial or industrial products. Raw materials for packaging paper production are mainly obtained from various grades of waste paper. For this reason, the recycled fibers from waste paper would probably have possibility of containing heavy metals. This study was focused on the development of optimum pre-treatment method for the quantitative analysis of mercury. The optimum pre-treatment for open digestion system were obtained at the treatment conditions of acid combination with $HNO_3/HCl/H_2O_2$ or $HNO_3/H_2SO_4$ at $80^{\circ}C$. The optimum pre-treatment conditions in closed digestion system were determinated by the acid combination with $HNO_3/HCl/H_2O_2/HF$ in microwave at 320 W for 20 min. The recovery rate in open digestion system was 85~94% and in closed digestion system was indicated as about 100%. Therefore, the closed system is superior than the open system in pre-treatment method for the quantitative analysis of mercury, and the detected mercury contents in the sample of KOCC, AOCC and kraft sack paper were measured below 1 ppm.

Study on Material Flow Analysis of Mercury in Paint (페인트 중 수은의 물질흐름분석 연구)

  • Cho, Yoon A;Jeong, Mi Jeong;Jeon, Tea Wan;Lee, Hee Sung;Kim, Yong Jun;Yeon, Jin Mo;Cho, Na Hyeon;Shin, Sun Kyoung
    • Journal of Korean Society of Environmental Engineers
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    • v.39 no.4
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    • pp.180-185
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    • 2017
  • For the management of mercury-containing products, the products were selected to do material flow analysis in preference of not having selected in previous studies. Domestically mercury have been added to pigment for prevention of bacterial growth. So, in this study paint containing pigment was selected as a target. 71 samples of paint products collected in 2014 and data of 38 samples of wastes (dust, sludge, paint) analyzed in 2010 were used in material flow analysis. The result shows that mercury was 0~0.25 mg/kg in products and 0.23~0.69 mg/kg in the wastes. In the material flow analysis, the amount of flow in the process of distribution was 10.06 kg/year, but the amount of flow in disposal like a landfill, incineration and recycling was much than distribution as 25.27 kg/year. It was caused by different sampling period between collecting products and data of wastes. Therefore, It could be possible to be affected from regulation by RoHS like decreasing usage of mercury in paint products or eradicated in the industry. Mercury contents in current paint products are very low to affect discharging to the environment.

Study on the Emission Characteristics of Heavy metals in sewage sludge Incinerator (하수슬러지 소각시설의 중금속 배출특성에 관한 연구)

  • Park, Jung-Min;Lee, Sang-Bo;Kim, Min-Jung;Kim, Jin-Pil;Kim, Jong-Chooun;Lee, Suk-Jo;Lee, Sang-Hak
    • Journal of environmental and Sanitary engineering
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    • v.24 no.3
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    • pp.28-36
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    • 2009
  • We have closely examined the concentration change characteristics, emission amounts, and the material balance of hazardous air pollutants at both early and later stages of the prevention facilities. These results will be uses as the basic data when preparing for the regulatory and management plans for hazardous air pollutants. The results of the study on heavy metals illustrated that the content of heavy metals in sludge across five facilities were as follows: copper> zinc> chrome> nickel> cadmium> mercury. In terms of heavy metal content in swage sludge, the sludge in incinerating facilities other than the sludge in the D incinerating facility containing industrial water waste, was examined in order to satisfy the ocean contamination standard and fertilizer specifications. Most of the items were shown to have satisfied the emission tolerance standards in the latter part of the prevention facilities(The average elimination rate was over 90%). Therefore, it is concluded that swage sludge containing high-concentrate heavy metals needs to be incinerated rather than recycled as fertilizer.

DNA barcoding of fish diversity from Batanghari River, Jambi, Indonesia

  • Huria Marnis;Khairul Syahputra;Jadmiko Darmawan;Dwi Febrianti;Evi Tahapari;Sekar Larashati;Bambang Iswanto;Erma Primanita Hayuningtyas Primanita;Mochamad Syaifudin;Arsad Tirta Subangkit
    • Fisheries and Aquatic Sciences
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    • v.27 no.2
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    • pp.87-99
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    • 2024
  • Global climate change, followed by an increase in anthropogenic activities in aquatic ecosystems, and species invasions, has resulted in a decline in aquatic organism biodiversity. The Batanghari River, Sumatra's longest river, is polluted by mercury-containing illegal gold mining waste (PETI), industrial pollution, and domestic waste. Several studies have provided evidence suggesting a decline in fish biodiversity within the Batanghari River. However, a comprehensive evaluation of the present status of biodiversity in this river is currently lacking. The species under investigation were identified through various molecular-based identification methods, as well as morphological identification, which involved the use of neighbor-joining (NJ) trees. All collected specimens were initially identified using morphological techniques and subsequently confirmed with molecular barcoding analysis. Morphological and DNA barcoding identification categorized all specimens (1,692) into 36 species, 30 genera and 16 families, representing five orders. A total of 36 DNA barcodes were generated from 30 genera using a 650-bp-long fragment of the mitochondrial cytochrome oxidase subunit I (COI) gene. Based on the Kimura two-parameter model (K2P), The minimum and maximum genetic divergences based on K2P distance were 0.003 and 0.331, respectively, and the average genetic divergence within genera, families, and orders was 0.05, 0.12, 0.16 respectively. In addition, the average interspecific distance was approximately 2.17 times higher than the mean intraspecific distance. Our results showed that the COI barcode enabled accurate fish species identification in the Batanghari River. Furthermore, the present work will establish a comprehensive DNA barcode library for freshwater fishes along Batanghari River and be significantly useful in future efforts to monitor, conserve, and manage fisheries in Indonesia.