• 제목/요약/키워드: Mercury Lamp

검색결과 149건 처리시간 0.021초

As$_{40}Ge_{10}Se_{100-x}S_x$ 계 박막의 광유기 스칼라 현상 (Photo-induced scalar phenomena of As$_{40}Ge_{10}Se_{100-x}S_x$ Thin-Film)

  • 박수호;이현용;정홍배
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1996년도 추계학술대회 논문집
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    • pp.5-9
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    • 1996
  • As optical massmemories, (Se, S)-based chalcogenide amorphous films are used for a holographic supermicrofiche by using the refractive-index change. In 1000$\AA$thick-As$_{40}$ Ge$_{10}$Se$_{100-x}$S$_{x}$(x=0.25, 35at.%), the amount of refractive index change $\Delta$n reaches 0.01~0.53 at 6328, 7800$\AA$ by exposing for 15minutes plue-pass filtered mercury lamp(~4300$\AA$) and annealing 20$0^{\circ}C$. And in initially annealed As$_{40}$ Ge$_{10}$Se$_{15}$ S$_{35}$, photodarkening(PD) and thermalbleaching(TB) was founded.ded.B) was founded.d.

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인코히어런트 삼각 홀로그래피의 해상도 분석에 관한 연구 (A study on resolution analysis of incoherent trigangular holography)

  • 김수길;김은수;이병호
    • 한국광학회지
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    • 제10권2호
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    • pp.128-137
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    • 1999
  • 변형 삼각간섭계에 있어서 기록과 복원 시스템을 고려한 PSF를 구하였다. 그리고 변형 삼각간섭계와 Cochran 삼각간섭계의 해상도를 유도하였으며, 렌즈의 배율, 복원시에 사용되는 레이저의 파장, 그리고 홀로그램의 크기에 따른 두 시스템의 해상도를 구하고 분석하였다. 또한, 인코히어런트 홀로그래피의 가능성을 입증하기 위하여 수은등을 이용한 인코히어런트 홀로그램의 생성과 이를 이용한 광학적 복원 결과가 제시되었다.

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Relationship between Structure and Properties of UV-Curable Polyurethane Acrylate Ionomers

  • 김태우;김한도
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 1996년도 추계 학술발표회
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    • pp.468-472
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    • 1996
  • A series of UV-curable polyurethane acrylate ionomer were synthesized from isophorone diisocyanate(IPDI), poly(tetramethylene ether glycol)(PTMG), 2,2-bis(hydroxymethyl)propionic acid (CMPA), triethylamine(TEA), 2-hydroxy ethyl acrylate (HEA), and dibutyl tin dilaurate (DBT) as a catalyst. 2,2-dimethoxy-2-phenyl acetophenone(DMPAP) was used as a photoinitiator. The films of UV-cured polyurethane acylate ionomer were prepared by casting the formulated materials onto a glass plate at room temperature and cured using a medium pressure mercury lamp (80 W/cm, max = 365nm). Effects of DMPA content, molecular weight of PTMG and degree of neutralization on the properties were invesigated. It is found that the storage modulus increased with increasing DMPA content. The glass transition temperature of sample A shifted to higher temperature as the content of DMPA was increased. Tensile modulus also increased with increasing DMPA content. Modulus and Tg decreased with increasing molecular weight of PTMG form 650 to 2000. With increasing the degree of nutralizaion, ionomers exhibited improved modulu.

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주파수 변화에 따른 무수은 평판 형광 램프의 특성 (Characteristic of Mercury free Flat fluorescent Lamp as Driving frequency)

  • 이명호;임기조;임민수;이문주
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2005년도 제36회 하계학술대회 논문집 C
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    • pp.2075-2078
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    • 2005
  • 본 논문은 무수은 평판 형광램프의 구동원리를 해석하기 위하여 주파수 변화에 따른 벽전하와 벽전압 특성이 방전특성에 미치는 영향을 연구하였다. 펄스폭 $9[{\mu}s]$, 300[ns]의 전압 상승 시간을 갖는 펄스파로 방전시켰다. 벽전하, 정전용량, 벽전압의 전기적 특성은 인가된 전압, 전류 파형으로부터 계산하였다. 이때 구동 주파수는 20[kHz]에서 40[kHz]까지 변화시키면서 방전 전후의 정전용량 및 Q-V특성 곡선을 해석하였다. 주파수가 증가하면서 전극간의 정전용량 $C_p$ 방전공간상의 정전용량 $C_o$는 변화를 보이지 않았으나 방전공간과 전극사이의 정전용량 $2C_g$는 증가하는 경향을 보였다. 또한 주파수가 증가하면서 방전개시 전압은 감소하였으며 효율은 감소하는 경향을 보였다.

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Preconcentration and Detection of Herbicides in Water by Using the On-line SPE-HPLC System and Photochemical Reaction

  • 이승호;이성광;박영훈;김현주;이대운
    • Bulletin of the Korean Chemical Society
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    • 제20권10호
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    • pp.1165-1171
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    • 1999
  • The analysis of trace herbicides using the on-line SPE-HPLC system and a photochemical reaction was studied. 18 compounds of herbicides including eight triazines, six phenoxy acids and esters, and four other herbicides were examined. The on-line SPE-HPLC system developed for selection of eluting solvent improved chromatographic efficiency. The recoveries of herbicides were higher than 77%. With 100 mL tap water samples, the detection limits for all analytes were in the 0.1-2.3×10-10 M range. Detection was done by a UV or fluorescence spectrometer after photochemical reaction at the end of the column with 2W or 450W mercury lamp. Without a photochemical reaction, all compounds responded to 230 nm UV detector, but phenoxy acids and esters were weakly detected. However, with a photochemical reaction, these compounds were selectively detected at 320 nm wavelength of UV absorption and 400 nm emission of the fluorescence detectors. This method can be used for the analysis of environmental water containing herbicides at trace levels.

Photodecomposition of N-t-Butyl-N-chloro-$\omega$-phenylalkanesulfonamides in the Presence of Oxygen

  • Lee, Jong Hun;Kim Kyongtae
    • Bulletin of the Korean Chemical Society
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    • 제13권6호
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    • pp.676-680
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    • 1992
  • Irradiation of N-t-butyl-N-chloro-3-phenylpropanesulfonamide (1a) in benzene at $20^{\circ}C$ using 450 W high pressure mercury arc lamp in the presence of oxygen affored N-t-butyl-3-phenylpropanesulfonamide (2), N-t-butyl-3-chloro-3-phenylpropanesulfonamide (3), and N-t-butyl-3-oxo-3-phenylpropanesulfonamide (4). Similarly, N-t-butyl-4- (5), N-t-butyl-4-chloro-4- (6), and N-t-butyl-4-phenylbutanesulfonamides (7) were obtained from N-t-butyl-N-chloro-4-phenylbutanesulfonamide (1b). However, irradiation of N-t-butyl-N-chloro-5-phenylpentanesulfonamide (1c) under the same conditions gave complex mixtures. These results indicate that sulfonamidyl radical generated from each of 1a and 1b can abstract intramolecularly a hydrogen atom from the benzylic position only by forming six and seven-membered transition states, respectively.

Photochemical Studies of Schiff Base Cu(II) Complex: (1) UV-Irradiation of N,$N^{\prime}$-bis(salicylidene)ethylenediamine copper(II)

  • 안병태
    • Bulletin of the Korean Chemical Society
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    • 제16권3호
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    • pp.202-204
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    • 1995
  • The ultraviolet photochemistry of N,N'-bis(salicylidene)ethylenediamine copper(II), Cu(sal)2en, was investigated with low pressure mercury lamp. Redution of Cu(Ⅱ) and formation of Cl- were shown on 254 nm irradiation both for aerated and deaerated chlorinated hydrocarbon solvent such as CH2Cl2, chloroform, and 1,2-dichloroethane. Relatively long lived $({\tau}=100{\mu}sec)$ intermediate was detected by flash photolysis. Overall photo-process can be described as the formation of Cl- and new copper complex, product(1) by chlorohydrocarbon mediation, photoinduced reduction by abstraction of halogen from solvent, followed by redox induced substitution of axial ligand with chlorine. Product(1) is possibly Cu(III) chlorosalicylaldeimido complex and cyclic -CH2CH2- moiety is absent in the structure. 247nm band of Cu(sal)2en should contain ligand to metal charge transfer character.

직접 광여기 Photo-CVD에 의한 이산화실리콘 박막의 증착 특성 (Photo-Induced Chemical Vapor Deposition of $SiO_2$ Thin Film by Direct Excitation Process)

  • 김윤태;김치훈;정기로;강봉구;김보우;마동성
    • 대한전자공학회논문지
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    • 제26권7호
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    • pp.73-82
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    • 1989
  • 실리콘계 절연박막 형성을 위한 저온공정을 개발하기 위하여 photo-CVD장치를 제작하여 $SiO_2$ 박막을 $50{\sim}250^{\circ}C$ 범위에서 증착시켰다. 이때 $SiH_4/N_2O$ 혼합가스는 수은증감반응법을 사용하지 않고 저압수은램프의 직접 광여기에 의해 분해시켰다. AES와 ESCA 분석결과 Si와 O의 화학량론적 구성이 거의 모든 공정조건에서 1:2로 나타났고, Si와 O원자의 결합상태가 $SiO_2$의 형태로 이루어져 있음을 보여주었다. 그리고 박막의 굴절율은 $1.39{\sim}1.44$의 범위로 나타나, 저온증착에 의해 밀도가 비교적 낮은 박막이 형성됨을 보였다.

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275 nm UVC LED와 TIR 렌즈 장착 광원을 이용하는 물 살균장치 제작 (Fabrication of a Water Sterilization System Utilizing a 275 nm-wavelength UVC LED and TIR Lens-equipped Light Source)

  • 카완 어닐;유승희;유승훈;박준아;신인식;이승재;김유빈;권용빈;한동균;유순재;김희태;박성배
    • 반도체디스플레이기술학회지
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    • 제23권1호
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    • pp.84-87
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    • 2024
  • A water sterilization system is developed utilizing a 275 nm-wavelength LED light source equipped with a TIR lens. The system's light source is constructed by combining a 275 nm-wavelength UVC LED, known for its germicidal properties, with a TIR lens having a direction angle of 6.8 degrees. The optical simulation software 'LightTools' is employed to design and optimize the intensity of deep ultraviolet sterilizing light irradiation, its distribution, and sterilization capacity. In the inactivation experiment with E. coli, the water sterilizer system achieved a sterilization rate of 78.92 % while maintaining a water flow capacity of 50 L/min. Compared to the conventional mercury lamp light source water sterilizer system, the UVC LED water sterilizer system addresses environmental concerns related to mercury usage and offers advantages in terms of lifespan and durability.

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광학부품의 진공자외선특성 측정용 분광반사율계 제작 (Fabrication of reflectometer for vacuum ultraviolet spectral characteristic measurements of optical component)

  • 신동주;김현종;이인원
    • 한국광학회지
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    • 제15권4호
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    • pp.325-330
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    • 2004
  • 진공자외선 파장영역에서 광학부품의 분광특성을 측정할 수 있는 중수소광원과 진공단색화장치, 시료챔버 및 광 검출기 구조의 진공자외선 분광반사율계를 제작하였다. 제작된 진공자외선 분광반사율계는 115nm∼330 nm의 분광영역에서 약 3.0${\times}$$10^{-4}$ Pa의 기압에서 작동하였다. 253.652 nm와 184.95 nm의 수은 선스펙트럼으로 진공단색화장치의 파장을 교정하여 그 분해능이 0.012 nm이고, 파장정확도가 $\pm$0.03 nm 임을 확인하였다. 중수소 광원을 이용하여 115 nm∼230 nm 파장대역의 진공자외선 영역에서 여러 가지 광학부품들에 이용되고 있는 재료(MgF$_2$, CaF$_2$, BaF$_2$, SiO$_2$, Sapphire)들의 분광투과율과 반사율을 측정하였다.