• 제목/요약/키워드: Membrane separation

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Study on Enhancement of Membrane Technology Competitiveness through NTIS (National Science & Technology Information Service) Data (NTIS (National Science & Technology Information Service) Data를 이용한 분리막 소재산업 경쟁력 향상 및 국가 연구비 지원 효율화에 관한 연구)

  • Woo, Chang Hwa
    • Membrane Journal
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    • 제30권2호
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    • pp.124-130
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    • 2020
  • Climate change is getting worse in the 21st century. So, water shortages are expanding worldwide. Carbon dioxide generated from the use of fossil fuels is 80% of the total green house gas. Because it occupies, it has become a factor of global warming. Therefore, the importance of water treatment membrane, gas separation membrane, and secondary battery separation membrane is increasing, but it occupies technology in developed countries such as the United States, Japan, and Germany. Therefore, the advancement of membrane technology is urgently required. So, although the country supports a lot of research budgets, We will analyze the results using NTIS data. As a result of the analysis used, it is supported mainly for short-term tasks, and the research budget is small compared to other technical fields, so the basic material field technology is weak. Therefore, when we invest a lot of long-term tasks, with a lot of budget, and universities, membrane technology has been improved and competitiveness has been strengthened.

Development and Application of Pervaporation Membranes (투과증발막의 발전과 응용)

  • 유제강;임지원;이영무;남상용
    • Membrane Journal
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    • 제12권4호
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    • pp.193-206
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    • 2002
  • Pervaporation separation is one of promising membrane technology for the energy saving processes and it has been developed to separate complex mixture systems including azeotropic mixture, close-boiling mixture, aqueous organic mixtures etc. Many researchers focused on dehydration pervaporation separation and they commercialized ethanol dehydration and isopropanol recycling processes. Nowadays, petroleum separation and volatile organic compound removal using pervaporation membranes is one of the emerging application of pervaporation separation. We reviewed the development and application of pervaporation membranes.

Pore Condensation-Based Separation of VOCs by a Microporous Ceramic Membrane (미세다공성 세라믹 막에서의 가공응축기구에 의한 휘발성 유기화합물의 분리)

  • Cha, Jun-Seok
    • Journal of Korean Society for Atmospheric Environment
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    • 제12권E호
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    • pp.19-28
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    • 1996
  • A pore concensation-based separation technique was studied experimentally using toluene and xylene in a nitrogen stream. The removal rate of toluene and xylene on a microporous ceramic membrane was enhanced by increasing the partial pressure difference across the membrane, but the selectivity was reduced with increasing flux of nitrogen. This was found both in vacuum and pressure modes of operation. The experimental results from this study suggest that the pores mear the inlet portion of the module were filled with the organic solvent while the pores near the exit section of the module were slightly opened as the solvent concentration was depleted along the module. In the case of xylene, the rate of N$_{2}$ permeation was reduced considerably relative to toluene, resulting in a much higher separation gactor. Condensibility of xylene appeared to be higher than that of toluene, the potential for pore condensation-based separation of xylene was also found to be higher than that for toluene.

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Treatment of dyeing wastewater by membrane process

  • Kim, In-Chul;Ka, Young-Hyun;Joo Young park;Lee, Kew-Ho
    • Proceedings of the Membrane Society of Korea Conference
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    • 한국막학회 2003년도 The 4th Korea-Italy Workshop
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    • pp.95-97
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    • 2003
  • The main purpose of this work is to investigate the performance of membranes for treatment of dyeing wastewater. The microfiltration (MF) membranes (titania-blended polysulfone & alumina) were prepared. The nanofiltration (NF) and reverse osmosis (RO) membranes were kindly supplied by the Sae-Han. In order to reuse the wastewater for dyeing, the effluents were treated by the high flux RO and the fouling resistant RO (FRM) membranes. Also, the NF membrane was used for water reuse in rinsing.

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New Pervaporation Membrane for Petroleum Separation

  • Nam, Sang-Yong;John R. Dorgan
    • Proceedings of the Membrane Society of Korea Conference
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    • 한국막학회 2003년도 The 4th Korea-Italy Workshop
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    • pp.77-80
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    • 2003
  • Hydrocarbon-hydrocarbon separations are one of the most important processes in petroleum refining. Distillation process has been used for separating hydrocarbons, but this conventional process is very energy consuming. Pervaporation separation through polymeric membranes is an emerging process alternative to distillation because of energy savings, compact system installation, reduced capital investment, and other performance attributes. In hydrocarbon separations, polymeric membranes are easily swollen by hydrocarbons and can lose mechanical strength. Chemically robust membranes are needed for the separation of hydrocarbons. In this study, the blend membrane was applied to separate benzene and cyclohexane. This is a model system for aliphatic and aromatic separation. Cyclohexane is also physically very similar to benzene and as a result of the very closing boiling points (0.6$^{\circ}C$), benzene and cyclohexane form an azetrope. Thus the system provides a good model for azeotrope breaking by pervaporation. The semi-quantitative thermodynamic model predicts that the calculated selectivity increases with increasing Hydrin contents in the blend membranes. Pervaporation experiments utilizing various operating temperatures and feed concentrations with different blend membranes are compared with the result from semi-quantitative thermodynamic calculations.

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Gas Separation Membranes - Current Status

  • Puri, Pushpinder S.
    • Membrane Journal
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    • 제6권3호
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    • pp.117-126
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    • 1996
  • Membrane-based gas separation systems are now widely accepted and employed as unit operation in industrial gas, chemical, and allied industries. Following their successful commercialization in the late seventies to recover hydrogen from ammonia purge gas streams, membrane-based systems have gained acceptance in a wide variety of applications. Numerous systems are in operation today to: recover hydrogen from other purge gas and hydrocarbon streams; adjust the $H_{2}/CO$ ratio in syngas; remove $CO_{2}$ from natural gas; recover helium; dry gas streams; and separate air. Lower cost, ease of operation, operational flexibility and portability are a few of the reasons membrane-based systems are chosen over absorption and cryogenic-based separations in certain applications.

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Comparisons of Reverse Osmosis and Pervaporation Membrane Processes I. Theoretical Interpretations

  • Rhim, Ji-Won;Lee, Kew-Ho;Huang, Y.M.
    • Proceedings of the Membrane Society of Korea Conference
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    • 한국막학회 1991년도 추계 총회 및 학술발표회
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    • pp.47-48
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    • 1991
  • The pressure in RO leads to a concentration difference across the membrane, while the concentration difference in PVAP across the membrane is achieved by applying a vacuum to the downstream compartment. Therefore, it could be possible to compare this two processes using the solution-diffusion mechanism.

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MEK SEPARATION FROM ITS AQUEOUS SOLUTION BY MEMBRANE CONTACTOR

  • Hyoseong Ahn;Yoonjin Oh;Lee, Yongtaek
    • Proceedings of the Membrane Society of Korea Conference
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    • 한국막학회 2003년도 The 4th Korea-Italy Workshop
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    • pp.17-20
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    • 2003
  • Separation of MEK(methylethylketone) was carried out experimentally by a flat membrane contactor using a variety of extracting organic compounds. A correlation equation of Sherwood number was determined in terms of Reynolds number and Schmidt number for the flat membrane contactor system. This correlation equation was applied to get theoretically the overall mass transfer coefficient of MEK: it was compared to the experimental one. It was found that they are in good agreement.

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The effect of thermodynamic stability of casting solution on the membrane inversion process morphology and permeation properties in phase inversion process

  • Kim, Jeong-Hoon;Lee, Kew-Ho
    • Proceedings of the Membrane Society of Korea Conference
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    • 한국막학회 1995년도 춘계 총회 및 학술발표회
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    • pp.26-27
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    • 1995
  • Most of synthetic polymeric membranes used in ultrafiltration, reverse osmosis and microfiltration processes are prepared by phase inversion(or phase separation) technique. In this technique, a homogeneous polymer solution is cast into thin film or hollow fiber shape and then immersed into a nonsolvent coagulant bath. The exchange of solvent and nonsolvent across the interface between casting solution and coagu!ant can make the casting solution phase-separate and form a membrane with a symmetric or asymmetric structure. Because of importance of this technique in membrane field, many investigations have been dedicated to elucidate the mechanism of membrane formation by phase inversion technique.[1-10] These investigation have suggested that the structure formation and permeation properties of phase inversion membrane depend on the variables such as the nature and content of casting solution and coagulant, temperature of casting solution and coagulant, and the diffusional exchange rate of solvent and nonsolvent etc. which can be related to the thermodynamic and kinetic properties of the casting system. The variables such as the nature and content of casting solution can also be the important factor affecting the structure formation and permeation property of the phase inversion membrane.

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