• Title/Summary/Keyword: Membrane introduction

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A SURVEY OF THE DEVELOPMENT OF MEMBRANE SCIENCE AND TECHNOLOGY IN CHINA

  • Congjie, Gao
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.05a
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    • pp.12-12
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    • 2004
  • A brief introduction was given in this paper for the research and development on membrane science and technology in China. Ion exchange membranes and electrodialysis, MF, UF, NF and RO membranes, gas separation (GS) membranes, pervaporation (PV), membranes, inorganic membranes (IM) and membrane reactors (MR) were involved.(omitted)

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Membrane Inlet-based Portable Time-of-flight Mass Spectrometer for Analysis of Air Samples

  • Kim, Tae-Kyu;Jung, Kyung-Hoon;Yoo, Seung-Kyo;Jung, Kwang-Woo
    • Bulletin of the Korean Chemical Society
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    • v.26 no.2
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    • pp.303-308
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    • 2005
  • A miniaturized time-of-flight mass spectrometer with an electron impact ionization source and sheet membrane introduction has been developed. The advantages and features of this mass spectrometer include high sensitivity, simple structure, low cost, compact volume with field portability, and ease of operation. A mass resolution of 400 at m/z 78 has been obtained with a 25 cm flight path length. Under optimized conditions, the detection limits for the volatile organic compounds (VOCs) studied were 0.2-10 ppm by volume with linear dynamic ranges greater than three orders of magnitude. The response times for various VOCs using a silicone membrane of 127 $\mu$m thickness were in the range 4.5-20 s, which provides a sample analysis time of less than 1 minute. These results indicate that the membrane introduction/time-of-flight mass spectrometer will be useful for a wide range of field applications, particularly for environmental monitoring.

Preparation of Cation Exchange Membrane using Block Copolymer of Polysulfone and Poly(Phenylene Sulfide Sulfone) and its Electrochemical Characteristics (Polysulfone과 Poly(Phenylene Sulfide Sulfone)의 블록 공중합체를 이용한 양이온 교환막의 제조 및 전기화학적 특성)

  • 임희찬;강안수
    • Membrane Journal
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    • v.10 no.2
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    • pp.66-74
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    • 2000
  • In consideration that a high tensile strength and ion exchange capacity are maintained as the swelling of membrane is controlled by the coagulation of PSf with the introduction of ion exchange groups and PPSS without the introduction of ion exchange groups, the block copolymer of PSf and PPSS were synthesized. The cation exchange membrane was prepared by sulfonation with CSA and casted. The synthesized block copolymer and cation exchange membrane were characterized by FT-IR and their thermal stability was confirmed by TGA. The optimum sulfonation could be accomplished at a mole ratio of BPSf to CSA 1:3. The best electrochemical properties obtained by the optimal condition were area resistance of 4.37 $\Omega$$\textrm{cm}^2$, ion exchange capacity of 1.71 meq/g dry membrane, water content of 0.2941 g $H_2O$/g dry membrane, and fixed ion concentration of 5.81 meq/g $H_2O$. When GBL was used as an additive, area resistance was increased by 13.7 % and ion exchange capacity was increased by 14.6%. When the membrane was fabricated in a form of composite using non woven cloth as a support. the tensile strength of membrane could be improved, but the electrochemical characteristics were not influenced.

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Study on Stress Transition Mechanism and Uniaxial Tensile Characteristics by Tensile Fractured Test of Clamping Part of Membrane Structures (막구조 정착부의 인장파단시험을 통한 신장특성 및 응력전달체계에 관한 연구)

  • Kim, Hee-Kyun;Jeon, Sang-Hyeon;Ha, Chang-Woo;Kim, Jae-Yeol
    • Journal of Korean Association for Spatial Structures
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    • v.20 no.3
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    • pp.91-98
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    • 2020
  • For form stability of membrane structures, membrane material is required to be in tension. Therefore, in planning and maintenance management, the engineer should consider enough about introduction of stress during construction and re-introduction of stress after completion. Clamping part is an important portion with the function for introducing tension into membrane materials, and the function to transmit stress to boundary structures, such as steel frames. Then, the purpose of this research is to clarify stress condition and stress transfer mechanism including clamping part of membrane structures, and to grasp the changing tendency of membrane structures with the passage of time. In this research, following previous one, we perform well-balanced evaluation by conducting tensile fractured tests of clamping part's specimens, and by measuring individually the amount of displacement of not only overall specimen's length but membrane material and clamping part. Thereby, we consider the influence the difference in the hardness of edge rope and the difference in the direction of thread affect modification and fracture load.

MEMBRANE-BASED GAS AND VAPOR SEPARATIONS

  • Wijmans, Hans
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.05a
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    • pp.3-6
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    • 2004
  • Industrial gas separation by membranes began in 1980 with the introduction of hollow-fiber polysulfone membrane systems by Permea, at that time a division of Monsanto. This first application was the recovery of hydrogen from ammonia reactor purge gas and was soon followed by the generation of nitrogen from air. Today, membrane gas separation ranks second behind cryogenic distillation in terms of nitrogen production, and this application has drawn the industrial gas companies into the membrane field.(omitted)

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Mass Transfer Modelling of Asymmetric Membrane Formation by Phase Inversion

  • 김제영;이환광;백기전;김성철
    • Proceedings of the Membrane Society of Korea Conference
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    • 1997.10a
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    • pp.81-82
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    • 1997
  • 1. Introduction : The growth of membrane science was initiated by the invention of asymmetric membrane which can be formed by the technique known as phase inversion. The basic procedure of phase inversion involves casting a thin film of polymer solution onto a suitable substrate followed by immersion in a coagulation bath (quench step). Therefore, events occurring during the quench period, at which time solvent-nonsolvent exchange and eventual polymer precipitation take place, can play a controlling role in the determination of ultimate membrane structure.

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Surface reactive micro/nano particles on inorganic oxygen separation membrane

  • Lee, Kee-Sung;Shin, Tae-Ho;Lee, Shiwoo;Woo, Sang-Kuk;Yang, Jae-Kyo;Choa, Yong-Ho
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.05a
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    • pp.94-97
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    • 2004
  • Micro/nano-sized L $a_{0.6}$S $r_{0.4}$Co $O_{3-}$$\delta$/ particles are considered to improve oxygen permeability in highly selective inorganic oxygen separation membrane. A L $a_{0.7}$S $r_{0.3}$G $a_{0.6}$F $e_{0.4}$ $O_{3-}$$\delta$/ membrane with perovskite structure is fabricated by a conventional solid-state reaction. As the oxygen permeation flux of the L $a_{0.7}$S $r_{0.3}$G $a_{0.6}$F $e_{0.4}$ $O_{3-}$$\delta$/ membrane was lower than commercial gas separation membranes, we coated the L $a_{0.6}$S $r_{0.4}$Co $O_{3-}$$\delta$/ particles to enhance the oxygen permeation flux. It has been demonstrated that the effective area of reactive free surface is an important factor in determining the effectiveness of the introduction of coating layer for oxygen permeation. The introduction of micro/nano L $a_{0.6}$S $r_{0.4}$Co $O_{3-}$$\delta$/ particles was very effective for increasing oxygen flux, as the flux was as much as 2 to 6 times higher than that of an uncoated L $a_{0.7}$S $r_{0.3}$G $a_{0.6}$F $e_{0.4}$ $O_{3-}$$\delta$/ membrane.\delta$/ membrane.>/ membrane.brane.

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Synthesis and Membrane Preparation of Polyimides for Non-aqueous System (비수계용 폴리이미드 합성 및 분리막 제조)

  • 전종영;탁태문
    • Proceedings of the Membrane Society of Korea Conference
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    • 1997.10a
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    • pp.39-45
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    • 1997
  • Introduction : Polyimides are one of the most important classes of the high performance polymers due to their excellent electrical, thermal, and high-temperature mechanical properties. But their uses are limited because of their poor solubility. Most polyimide derivatives are processed in the form of polyamic acids, which are subsequently converted into the imide structures.Recently, it has been found that the soluble polyimides with large molecular weight sufficient to application. For enhancing processability, the majority of approaches have involved the following factors. As much as, the separation of the imide ring along the back-bone, that is to say, reducing the density of imide ring in the repeat structure. The introduction of bulky substituents along the back-bone, in order to enhance the free volume of main-chain. The incorporation of flexible or thermally stable linkages in the main-chain, reducing the packing force. The disruption of symmetry or recurrence regularity through copolymerization in order to reduce crystallnity.The objectives of this investigation are the synthesis and characterization of soluble polyimides as membrane materials by the single-step polymerization and the preparation of the asymmetric polyimide membrane by using phase inversion technique. In the present study, three series of polyimide derivatives are synthesized; H series is homopolyimides, A series is prepared from single dianhydride and two diamines, B series is yielded from two dianhydrides and a diamine. The dope solution was directly prepared from the PI solution via one step polymerization from monomers.

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Vitrification Phenomena in Polysulfone/NMP/water system (폴리술폰/NMP/물 계의 고화 현상에 관한 연구)

  • Kim, Je-Young;Kanamori, Toshiyuki;Lee, Hwan-Kwang;Baik, Ki-Jun;Kim, Sung-Chul
    • Proceedings of the Membrane Society of Korea Conference
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    • 1998.04a
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    • pp.53-55
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    • 1998
  • 1. INTRODUCTION : Since the knowledge of vitrification phenomena can lead to a better understanding of the mechanism of membrane formation, it is desirable to include vitrification line into the phase diagrams. While the final morphology obtained during phase inversion depends upon the kinetics as well as the thermodynamics of the phase separation, the equilibrium phase diagram and vitrification line for amorphous polymers are still a good tool for controlling the morphology and interpreting the membrane structure.

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The Correlation between Gas Transport Properties and Physical Properties of Modified Polysulfones (변형 폴리술폰의 기체 투과 성질과 물리적 성질의 상관관계)

  • ;;;;;Guiver, Michael D.;R
    • Proceedings of the Membrane Society of Korea Conference
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    • 1997.10a
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    • pp.67-68
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    • 1997
  • 1. Introduction : Gas transport through dense polymeric membranes is predominantly determined by the chain packing density as well as the chain flexibility. Thus, improved permeation properties can be obtained by controlling these two factors. In this work, the introduction of bulky substituents was attempted to improve permeation properties. Polysulfone, widely used material for gas separation membrane, was the starting material of this modification. Gas transport properties of resulting modified polysulfones were examined, and the improved properties were explained by probing the change of physical properties.

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