• 제목/요약/키워드: Membrane interface

검색결과 157건 처리시간 0.022초

Membrane Concentrate Thickening by Hollow-fiber Microfilter in Drinkin Water Treatment Processes

  • 이병호
    • 멤브레인
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    • 제1권1호
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    • pp.100-100
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    • 1991
  • A novel system to thicken the concentrated colloidal solution from membrane water treat-ment processes was developed. A hollow-fiber microfilter(hydrophilic polyethylene nominal pore size 0.1 μm total surface area 0.42 m2) was installed in an acrylic housing that has an aeration port 5 cm below the membrane and a clarifier in the bottom. The concentrate was uniformly supplied from the top of the housing. Bacuum filtration caused downward flow of concentrate and as a result thickening interface. The addition of poly-aluminum chloride (PAC) resulted in rapid increase of trans-membrane pressure (TMP) and in no improvement of the filtered water turbidity and thickening process. Two types of con-centrate and concentrate turbidity had little effect on the increase of TMP and concentrate thickening. It was observed that for the same height of membrane housing membrane surface area to housing volume (A/V) ratio had significant effect on the increase of TMP. When the housing volume was increased ten times the increasing rate of TMP was three times faster as compared to the original housing. A hydraulic model successfully simulated the formation and sedimentation of thickening interface.

Use of Inner Ionomer Solution in Preparing Membrane-Electrode Assembly (MEA) for Fuel Cells and Its Characterization

  • Seo, Seok-Jun;Woo, Jung-Je;Yun, Sung-Hyun;Park, Jin-Soo;Moon, Seung-Hyeon
    • Korean Membrane Journal
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    • 제10권1호
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    • pp.46-52
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    • 2008
  • Optimization of ionomer solution was conducted in order to improve the performance of MEAs in PEMPC. The interface between membrane and electrodes in MEAs is crucial region determining fuel cell performance as well as ORR reaction at cathode. Through the modification of Nafion ionomer content at the interface between membrane and electrodes, an optimal content was obtained with Nafion 115 membranes. Two times higher current density was obtained with the outer Nafion sprayed MEA compared with the non-sprayed one. In addition, the symmetrical impedance spectroscopy mode (SM) exhibited that the resistances of membrane area, proton hydration, and charge transfer decreased as the outer Nafion is sprayed. From the polarization curves and SM, the highest current density and the lowest resistance was obtained at the outer ionomer content of $0.15\;mg\;cm^{-2}$.

Transport Analysis of olefins & nitrogen through PDMS membranes

  • Kim, Jeong-Hoon;Shin, Hyo-Jin;Choi, Seung-Hak;Park, In-Jun;Lee, Soo-Bok
    • 한국막학회:학술대회논문집
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    • 한국막학회 2004년도 Proceedings of the second conference of aseanian membrane society
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    • pp.195-198
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    • 2004
  • Annually, 60 millions tons of polyolefins including polyethylene and polypropylene, etc. are produced in the world. During the manufacturing process, 1-2wt% of olefin gases of total feedstock remains unreacted and incinerated into air. Because of high cost of olefins and hazardous emission of carbon dioxide and toxic gases in incineration process, it is of important to recover them efficiently.(omitted)

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Slippage on which interface in nanopore filtration?

  • Xiaoxu Huang;Wei Li;Yongbin Zhang
    • Membrane and Water Treatment
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    • 제15권1호
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    • pp.31-39
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    • 2024
  • The flow in a nanopore of filtration membrane is often multiscale and consists of both the adsorbed layer flow and the intermediate continuum fluid flow. There is a controversy on which interface the slippage should occur in the nanopore filtration: On the adsorbed layer-pore wall interface or on the adsorbed layer-continuum fluid interface? What is the difference between these two slippage effects? We address these subjects in the present study by using the multiscale flow equations incorporating the slippage on different interfaces. Based on the limiting shear strength model for the slippage, it was found from the calculation results that for the hydrophobic pore wall the slippage surely occurs on the adsorbed layer-pore wall interface, however for the hydrophilic pore wall, the slippage can occur on either of the two interfaces, dependent on the competition between the interfacial shear strength on the adsorbed layer-pore wall interface and that on the adsorbed layer-continuum fluid interface. Since the slippage on the adsorbed layer-pore wall interface can be designed while that on the adsorbed layer-continuum fluid interface can not, the former slippage can result in the flux through the nanopore much higher than the latter slippage by designing a highly hydrophobic pore wall surface. The obtained results are of significant interest to the design and application of the interfacial slippage in nanoporous filtration membranes for both improving the flux and conserving the energy cost.

연성 막구조의 파라메트릭 설계 시스템 개발 (Development of a Parametric Design System for Membrane Structures)

  • 최현철;이시은;김치경
    • 한국공간구조학회논문집
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    • 제16권4호
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    • pp.29-36
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    • 2016
  • The objective of this research is to development of a parametric design system for membrane structures. The parametric design platform for the spatial structures has been designed and implemented. Rhino3D is used as a 3D graphic kernel and Grasshopper is introduced as a parametric modeling engine. Modeling components such as structural members, loading conditions, and support conditions are developed for structural modeling of the spatial structures. The interface module with commercial structural analysis programs is implemented. An iterative generation algorithm for design alternatives is a part of the design platform. This paper also proposes a design approach for the parametric design of Spoke Wheel membrane structures. A parametric modeling component is designed and implemented. SOFiSTik is examined to interact with the design platform as the structural analysis module. The application of the developed interface is to design optimally Spoke Wheel Shaped Ductile Membrane Structure using parametric design. It is possible to obtain objective shape by controlling the parameter using a parametric modeling designed for shape finding of spoke wheel shaped ductile membrane structure. Recently, looking at the present Construction Trends, It has increased the demand of the large spatial structure. But, It requires a lot of time for Modeling design and the Structural analysis. Finally an optimization process for membrane structures is proposed.

Pervaporation of TFEA/MA/Water Mixtures through PVA Composite Membranes

  • Ahn, Sang-Man;Kim, Jeong-Hoon;Lee, Yong-Taek;Lee, Soo-Bok
    • 한국막학회:학술대회논문집
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    • 한국막학회 2005년도 추계 총회 및 학술발표회
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    • pp.133-147
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    • 2005
  • In order to investigate applicability for 2,2,2-trifluoroethyl methacrylate (TFEMA) produced by esterification of 2,2,2-trifluoroethanol(TFEA) and methacrylic acid(MA) using pervaporation membrane, poly(vinyl alcohol) (PVA) composite membranes were prepared with glutaraldehyde(GA) onto porous polyethersulfone(PES) support. The degree of crosslinking and thickness of PVA coating layer were analyzed by swelling test and SEM(scanning electron microscopy), respectively. Pervaporation test was done with two feed mixures; TFEA/water, MA/water. The pervaporation data were obtained as a function of content of crosslinking agent, feed composition, and operating temperature, respectively. In case of TFEA-water(90/10 wt%) feed mixture at $80^{\circ}C$, the optimized membrane showed the high permeation flux of 1.5 $kg/m^2hr$ and separation factor of 320. In case of MA-water(90/10 wt%) feed mixture, the membranealso showed high permeation flux of 2.3 $kg/m^2hr$ and separation factor of 740 in same conditions.

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차수용 박층 멤브레인의 직접전단실험에 관한 수치해석 연구 (Numerical Study on Direct Shear Test of Composite Shotcrete with Sprayable Waterproofing Membrane)

  • 이기철;최순욱;김동욱;이철호
    • 한국지반신소재학회논문집
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    • 제17권4호
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    • pp.189-197
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    • 2018
  • 차수용 박층 멤브레인은 폴리머로 구성된 재료로 기존 방수포(sheet membrane)와 비교했을 때, 시공에 있어서 뿜어 붙이는 방식을 사용하기 때문에 타설이 용이하고 상대적으로 높은 부착성능을 보이는 재료이다. 하지만, 차수용 박층 멤브레인은 최근에 개발된 재료로 그 성능이나 구조물과의 거동 양상은 충분히 보고되지 못한 실정이다. 따라서 본 연구에서는 차수용 박층 멤브레인이 삽입된 복합 숏크리트 재료에 대해 전단시험을 수행한 기존 연구 결과를 이용하여 차수용 박층 멤브레인의 전단거동을 수치해석적으로 접근하여 접촉면 특성을 파악하고자 하였다. 연구를 통해 숏크리트 사이에 시공된 멤브레인에 의해 숏크리트의 전단거동과는 다른 거동을 보여 일반적으로 사용되는 전단강도 방식으로 거동을 표현하는데에는 한계가 있었다. 이에 따라 수치해석 방법을 사용하여 직접 전단시험을 모사하였고 차수용 박층 멤브레인의 전단거동을 가장 효과적으로 표현할 수 있는 방안을 제시하였다.

Membrane interaction of the coiled-coil motif of HIV gp41 and its implication in the membrane fusion process

  • Jin, Bong-Suk;Yu, Yeon-Gyu
    • 한국생물물리학회:학술대회논문집
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    • 한국생물물리학회 2003년도 정기총회 및 학술발표회
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    • pp.58-58
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    • 2003
  • The envelope glycoprotein of HIV, gp41, mediates the membrane fusion with human cells. The extracellular domain of gp41 has two helical regions. The N-terminus helical region (N-helix) forms trimeric coiled coil, interacts with the C-terminus helical region (C-helix) of gp41 to form a stable helical bundle structure. In this study, we have shown that the N-helix of gp41 has membrane interacting and disrupting abilities. It was localized into the interface of the lipidic phase and head group of the membrane. In contrast, the N-helix region with membrane fusion defective mutations could not bind to membrane. In addition, the N-helix bound on the membrane was released from the membrane by the C-helix, and the complex of the N- and C-helix did not interact with membrane. These results suggested that the membrane binding ability of the N-helix is necessary for the fusion activity of gp41, and such property is possibly controlled by the C-helm.

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Membrane Distillation의 전망 (The Prospect of Membrane Distillation)

  • 조한욱;신우철
    • 멤브레인
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    • 제7권2호
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    • pp.57-64
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    • 1997
  • 새로운 분리공정으로서 Membrane Distillation(MD)에 대하여 고찰하였다. 정밀여과에서 이용되고 있는 소수성막이 MD공정에 적합한 막소재가 된다. MD는 고온보다는 완화된 온도에서 100%에 가까운 선택도를 가지면서 기존의 수처리 공정을 간소화시킬 수 있는 가능성이 있다. MD는 막표면의 기공에서 층기-액체간의 상분리가 일어나는 분리원리를 이용한다. 공급액 및 투과액의 온도, 조성, 막의 젖음현상, 열 및 물질전달이 MD의 선택도와 플럭스를 결정할 수 있다.

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[ $Ag^+$ ]-Chitosan Complex Membranes for Propylene/Propane Separation

  • Kim, Jeong-Hoon;Lee, Soo-Bok;Feng, Xianshe
    • Korean Membrane Journal
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    • 제8권1호
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    • pp.36-42
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    • 2006
  • We have prepared new water-swollen chitosan-$Ag^+$ complex membranes and studied their permeation and separation behavior for propylene and propane gases. The $Ag^+$ containing chitosan complex membranes were prepared from chitosan and $AgNO_3$ aqueous solution. The $AgNO_3$ and water content in the membrane were controlled by adjusting $AgNO_3$ concentration of casting solution. The permeation properties of propylene and propane were investigated as a function of $AgNO_3$ concentration, and various operation conditions. High permeability of above 17 barrer and high selectivity of above 170 could be obtained with the membranes prepared from 3 M $AgNO_3$ aqueous solution. Periodic regeneration test confirmed these membranes could be very useful for the separation of propylene/propane and other olefin/paraffin separation.