• 제목/요약/키워드: Membrane filtration method

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연속공정에 의한 UF용 폴리이미드 분리막의 제조

  • 김완주;전종영;탁태문
    • Proceedings of the Membrane Society of Korea Conference
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    • 1995.04a
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    • pp.45-45
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    • 1995
  • Filtration, one of the most important process in the various industrials, is defined as the separation of two or more compounds from a fluid by passing the mixture refers to the separation of solid, immisible particles from liquid or gaseous mixture. Membrane filtration which is a type of filtration extends it's application further to include the separation, concentration, and filtration. The main objective of this investigation is the preparation of organic solvents-resistant polyimide membranes by using phase inversion technique and their application as a UF membrane. Specially, the dope solution was prepared from the newly developed method. The newly developed method is that the dope solution was directly prepared from the polyimide solution which was prepared by the modified one-step polymerization. The effects of the parameters for membrane preparation such as the casting solution composition and the casting conditions were investigated and the performance and chemical stabfiity of membrane are going to be tested.

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Comparison of Evaluation Methods for Disinfection Efficacy of Contact Lens Care Products (콘택트렌즈 관리용품의 살균력 효능 검사법 비교)

  • Sung, Hyung Kyung;Byun, Hyun Young;Kim, So Ra;Park, Mijung
    • Journal of Korean Ophthalmic Optics Society
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    • v.19 no.1
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    • pp.59-67
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    • 2014
  • Purpose: The present study was aimed to compare the results of disinfection efficacy tested by membrane filtration method with dilution-neutralization method to develop the standard methods for evaluating disinfection efficacy of contact lens care products and to provide the result of disinfection efficacy of commercially available contact lens care products in domestic market. Methods: The results of disinfection efficacy against Staphylococcus aureus, Pseudomonas aeruginosa, Serratia marcescens, Candida albicans evaluated by membrane filtration method as a FDA standard and dilution-neutralization method as newly being a KFDA standard were compared and the disinfection efficacy of 16 multi-purpose solutions was further evaluated. Results: The disinfectants and contact lens care products having strong disinfection efficacy showed same results in both membrane filtration method and dilution-neutralization method. In case of contact lens care products having weak disinfection efficacy, the number of micro-organisms was not able to count since the colony was aggregated when evaluated by membrane filtration method. However, the number of micro-organisms was able to exactly count when evaluated by dilution-neutralization method. In addition, some commercially available contact lens care products did not meet disinfection standard and especially, their disinfection effect was often weak against Serratia marcescen and Candida albicans. Conclusions: It is concluded that dilution-neutralization method will be useful to evaluate disinfection efficacy since it is possible to count micro-organisms more precisely even with small amount of sample and check the results faster compared with membrane filtration method.

Transmembrane Pressure of Backwashing, Filtration/Relaxation and the Sinusoidal Flux Continuous Operation Modes for Submerged Plate Membrane (역세척, 여과/이완 및 사인파형 연속투과 운전방식에 따른 침지형 평막의 막간차압)

  • Kim, Jae Hyo;Kim, Eun Soo;Chung, Kun Yong
    • Membrane Journal
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    • v.29 no.4
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    • pp.216-222
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    • 2019
  • In this study, permeation experiments were conducted using naturally circulating spherical beads, backwashable plate membrane and the air supplied from the bottom of the MBR. The activated sludge solution was maintained at 8,000 mg/L of MLSS and compared transmembrane pressure (TMP) with respect to FR (filtration and relaxation), FR/BW (filtration and relaxation/backwashing), SFCO (sinusoidal filtration continuous operation) and SFCO/BW (sinusoidal filtration continuous operation/backwashing). As the backwashing flux decreased from 47 to $14L/m^2{\cdot}hr$, the TMP increased generally, but the TMP of FR system increased significantly comparing with SFCO. In addition, the backwashing method reduced more TMP comparing to the cleaning method using spherical beads, and it was confirmed that the operation method using the spherical beads and the backwashing simultaneously is more effective than each method.

Effects of Ultrasonic Waves on Filtration Performance and Fermentation in an Internal Membrane-Filtration Bioreactor

  • PARK, BYUNG GEON;WOO GI LEE;WEI ZHANG;YONG KEUN CHANG;HO NAM CHANG
    • Journal of Microbiology and Biotechnology
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    • v.9 no.3
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    • pp.243-248
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    • 1999
  • Ultrasonic wave technology was employed to improve filtration performance and ethanol production in a bioreactor equipped with an internal ceramic-membrane filter module. The filtration performance was found to depend on the power and the pattern of ultrasonic wave irradiation. Under the optimized conditions (irradiation time: 25 see, period: 5 min, and ultrasonic power: 60 W), the flux was improved with the periodic-pause method by 200-700% compared with the control (with no irradiation), while the improvement was only 30 to 90% without the periodic-pause method. The final ethanol concentration also increased slightly. However, in a more severe condition (irradiation time: 2.5 min, period: 5 min, and ultrasonic power: 110 W), the irradiation of ultrasonic waves was observed to disturb cell integrity and viability, and thus to decrease ethanol production.

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Development of photocatalytic PVA/$TiO_2$ nanofiber membrane by electrospinning and its application for Air Filtration

  • Linh, Nguyen Thuy Ba;Lee, Byong-Taek
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2010.05a
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    • pp.38.1-38.1
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    • 2010
  • Nanofibers have a large potential in air filtration applications. In this work, we have developed a photocatalytic polyvinyl alcohol PVA/$TiO_2$ nanofibers membrane for the treatment of air filtration by using electrospinning method. PVA were electrospun into nanofibrous membranes and $TiO_2$ nanoparticles were loaded in PVA nanofibers in various contents from 10% (w/w) to 50% (w/w). The UV-Vis spectra were conducted for testing the existence of $TiO_2$ nanoparticles in PVA fibers. SEM analysis indicated that $TiO_2$ nanoparticles were loaded on the surface of PVA fibers and dispersed linearly along the fiber direction, which originated from the effect of polarization and orientation caused by high electric field. X-ray diffraction (XRD) was used to determine the crystalline of the membrane. Tensile strength was measured to evaluate the physical properties of the membrane. Therefore, our work suggested that PVA/$TiO_2$ nanofiber membrane has a potential application in air filtration area.

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A new method for in line electrokinetic characterization of cakes

  • Lanteri, Yannick;Ballout, Wael;Fievet, Patrick;Deon, Sebastien;Szymczyk, Anthony;Sauvade, Patrick
    • Membrane and Water Treatment
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    • v.4 no.3
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    • pp.157-174
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    • 2013
  • The present study is devoted to the validation of a new method for in line electrokinetic characterisation of deposits on membrane surfaces. This method is based upon simultaneous measurements of transversal streaming potential and permeates flux at constant pressure before and during the deposit formation. Dead-end filtration experiments were conducted with negative flat membranes forming a narrow slit channel, negative hollow fiber membranes and mono-dispersed suspensions of (negatively charged) polystyrene latex and (positively charged) melamine particles at various concentrations. It was observed that the overall streaming potential coefficient increased in absolute value with the deposited latex quantity, whereas it decreased and changed of sign during the filtration of melamine suspensions. By considering a resistance-in-series model, the streaming potential coefficient of the single deposit ($SP_d$) was deduced from the electrokinetic and hydraulic measurements. The independence of $SP_d$ with respect to growth kinetics validates the measurement method and the reliability of the proposed procedure for calculating $SP_d$. It was found that $SP_d$ levelled off much more quickly when filtration was performed through the slit channel. This different behaviour could result from a non-uniform distribution of the deposit thickness along the membrane given that the position of measuring electrodes is different between the two cells.

Chemically enhanced steam cleaning for the control of ceramic membrane fouling caused by manganese and humic acid (망간과 휴믹산에 의한 세라믹 막 오염의 제어를 위한 약품 스팀세정의 적용)

  • An, Sun-A;Park, Cheol-Gyu;Lee, Jin-San;Kim, Han-Seung
    • Journal of Korean Society of Water and Wastewater
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    • v.35 no.6
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    • pp.425-436
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    • 2021
  • In this study, chemically enhanced steam cleaning(CESC) was applied as a novel and efficient method for the control of organic and inorganic fouling in ceramic membrane filtration. The constant filtration regression model and the resistance in series model(RISM) were used to investigate the membrane fouling mechanisms. For total filtration, the coefficient of determination(R2) with an approximate value of 1 was obtained in the intermediate blocking model which is considered as the dominant contamination mechanism. In addition, most of the coefficient values showed similar values and this means that the complex fouling was formed during the filtration period. In the RISM, R c/R f increased about 4.37 times in chemically enhanced steam cleaning compared to physical backwashing, which implies that the internal fouling resistance was converted to cake layer resistance, so that the membrane fouling hardly to be removed by physical backwashing could be efficiently removed by chemically enhanced steam cleaning. The results of flux recovery rate showed that high-temperature steam may loosen the structure of the membrane cake layer due to the increase in diffusivity and solubility of chemicals and finally enhance the cleaning effect. As a consequence, it is expected that chemically enhanced steam cleaning can drastically improve the efficiency of membrane filtration process when the characteristics of the foulant are identified.

Industrial dairy wastewater purification by shear-enhanced membrane filtration: The effects of vibration

  • Kertesz, Szabolcs
    • Membrane and Water Treatment
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    • v.5 no.2
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    • pp.73-86
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    • 2014
  • Membrane fouling is a major challenge limiting the use of membrane applications. In this study high induced shear rates were utilized at the membrane surface in order to reduce the organic and inorganic scaling by using the torsional vibration of flat sheet membranes. The performances of a vibratory shear-enhanced processing (VSEP) system for the ultrafiltration (UF), nanofiltration (NF) and reverse osmosis (RO) membrane filtration of industrial dairy wastewater were investigated. The vibration and non-vibration methods were compared with the same membrane and operational parameters during the purification of real dairy industrial process wastewater. In the initial experiments, short-term tests were carried out in which the effects of vibration amplitude, recirculation flow rate and transmembrane pressure were measured and compared. The permeate flux, turbidity, conductivity and chemical oxygen demand (COD) reduction of dairy wastewater were investigated by using UF, NF and RO membranes with vibration and non-vibration methods. In the subsequent experiments, concentration tests were also carried out. Finally, scanning electron microscopy (SEM) revealed that the vibration method gave a better performance, which can be attributed to the higher membrane shear rate, which reduces the concentration of solids at the membrane, and the transmission.

Influence of Ion Exchange Capacity on the Performance of Ultrafiltration Membrane Prepared from Anion Charged Poly(bis[4-(3-aminophenoxy)phenyl]sulfone pyromellite)imide Derivatives (음이온성 Poly(bis[4-(3-aminophenoxy)phenyl]sulfone pyromellite)Imide Derivatives 한외여과막의 투과특성)

  • Jong-Young Jeon
    • Membrane Journal
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    • v.14 no.1
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    • pp.26-36
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    • 2004
  • Ultrafiltration membranes based on anion charged poly(bis[4-(3-aminophenoxy)phenyl]sulfone pyromellite) imide derivatives (ACPI) were prepared by the phase inversion method. The polymers have good solubility in aprotic polar solvents. The composition of casting solution and the casting conditions played an important role in determining the permeation characteristics of membrane because the membrane structure could be controlled by the preparation conditions. The extent of fouling-repression was observed by the relative ratio of permeate flux ($J_t$)/pure water flux ($J_0$) and the membrane filtration index (MFI). The characteristics were measured by aqueous solution of bovine serum albumin (BSA) over a pH range of 2.5-9.0. The ACPI membrane having a hydrophilic property was less fouled than the membrane prepared from the original polyimide. With increasing the ion exchange capacity of ACPI membrane, th $\varepsilon$ relative ratio of flux was higher while the membrane filtration index was lower as compared with the original polyimide membrane. From the further away from isoelectric point of bovin serum albumin, the permeation was higher as well as the formation of fouling was more diminish. ACPI membranes having various their properties could be obtained. Further, it was proved that their permeation properties could be determined from the preparation conditions, various operating conditions, and dim $\varepsilon$ rent ion exchange capacity of anion charged polyimide derivatives.

Effect of Ozonation on Cross-flow Filtration of Polysulfone Ultrafiltration Membrane (폴리설펀 한외여과막공정에서 오존의 영향)

  • 박영규
    • Membrane Journal
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    • v.11 no.4
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    • pp.179-189
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    • 2001
  • Effect of ozonation on permeate flux was studied by using polysulfone ultrafiltration membrane. The filtration was first carried out by permeating phenol solutions under 3$kg_{f}$/$cm^2$ until steady-state flux was obtained. Then, the ozone of concentration range between 10 and 45 mg/1.min was ozonated in water for reducing the fouling on the UF membrane. Treatment of chemical wastewater by combined ozone and membrane filtration methods was also investigated for the final purpose. The Fenton method assisted by chemical coagulation was employed as a prtreatment method and found to be highly efficient in removing a large amount of organic compounds. And it was found that the ozonation made the permeate flux enhance in the phenol solution and phenolic-chemical wastewaster by 10% and oxidation by ozone and hydrogen peroxide was more effective. Evidence was presented that TMP decreased in more ozone concentrated water and it was found that the ozone-mediated membrane would have a limited role to prevent the membrane fouling rather than to eliminate fully.

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