• Title/Summary/Keyword: Melting treatment

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The Electrode Characteristics of the Zr-based Hydrogen Absorbing Alloy Fabricated by the Rapid Solidification Process (급속응고법으로 제작한 Zr기 수소저장합금의 전극특성)

  • Han, Dong-Su;Jeong, Won-Seop;Kim, In-Gon
    • Korean Journal of Materials Research
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    • v.9 no.4
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    • pp.386-391
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    • 1999
  • The charge-discharge, the high-rate dischargeability, and the self discharge characteristics of the electrodes composed of rapidly solidified ZrV\ulcornerMn\ulcornerMo\ulcornerNi\ulcorneralloy, which has the form of partial substitution of Mn, Mo, Ni for V in $ZrV_2$ were studied. The alloys were prepared using Arc & RSP(Rapid Solidification Process) at the rotating roller speed of 2000 and 5000 rpm. Some of them were received heat treatment at$ 560 ^{\circ}C$ for 1 hour after the solidification to investigate the effect of the heat treatment. It was fond that cycle life was significantly improved by RSP, whereas discharge capacity, activation rte and high rate dischargeability were decreased compared with the conventional arc melting method. The capacity loss seems to be due to the loss of the crystallinity and the increase of the cycle life ascribed to the presence of the amporphous phase as well as the refined grain size of less than 0.2$\mu\textrm{m}$. Heat treatment of the alloy cooled at 2000 rpm improved the cycle life. In case of the alloys cooled at 5000 rpm, both the discharge capacity and the activation rate were significantly improved by the heat treatment.

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Location Problem on the Treatment Facility of Waste FRP Ships (폐 FRP 선박 처리시설 입지선정문제)

  • Park, HyunJi;Shin, JaeHun;Kim, KiDong
    • Journal of Industrial Technology
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    • v.38 no.1
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    • pp.9-13
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    • 2018
  • FRP(Fiber Reinforced Plastic) ships are easy to manufacture and repair. Also they are more durable and cheaper than steel wires and neck lines. Therefore FRP ships are widely used in small ships. In Korea, the amount of waste FRP ships is increasing. It is expected that a large amount of waste FRP ships will be generated. Waste FRP ships are emerging as a social problem, such as the difficulty in preserving the marine environment. To improve this, a waste FRP ship melting process system has been developed. In order to construct an effective waste FRP ship processing system, it is necessary to study the treatment facilities location problem. In this paper, we suggest mathematical model to solve optimal location problem of waste FRP Ships and discuss on results by applying it to nine regions selected as candidates for treatment facilities.

Physicochemical Properties of Enzymatically Modified Maize Starch Using 4-${\alpha}$-Glucanotransferase

  • Park, Jin-Hee;Park, Kwan-Hwa;Jane, Jay-Iin
    • Food Science and Biotechnology
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    • v.16 no.6
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    • pp.902-909
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    • 2007
  • Granular maize starch was treated with Thermus scotoductus 4-${\alpha}$-glucanotransferase (${\alpha}$-GTase), and its physicochemical properties were determined. The gelatinization and pasting temperatures of ${\alpha}$-GTase-modified starch were decreased by higher enzyme concentrations. ${\alpha}$-GTase treatment lowered the peak, setback, and [mal viscosity of the starch. At a higher level of enzyme treatment, the melting peak of the amylose-lipid complex was undetectable on the DSC thermogram. Also, ${\alpha}$-GTase-modified starch showed a slower retrogradation rate. The enzyme treatment changed the dynamic rheological properties of the starch, leading to decreases in its elastic (G') and viscous (G") moduli. ${\alpha}$-GTase-modified starch showed more liquid-like characteristics, whereas normal maize starch was more elastic and solid-like. Gel permeation chromatography of modified starch showed that amylose was degraded, and a low molecular-weight fraction with $M_w$ of $1.1{\times}10^5$ was produced. Branch chain-length (BCL) distribution of modified starch showed increases in BCL (DP>20), which could result from the glucans degraded from amylose molecules transferred to the branch chains of amylopectin by inter-/intra-molecular transglycosylation of ${\alpha}$-GTase. These new physicochemical functionalities of the modified starch produced by ${\alpha}$-GTase treatment are applicable to starch-based products in various industries.

Phase transformation of $REBa_2Cu_3O_{7-x}$ (RE=Nd, Gd, Dy) Superconductor during Continuous Cooling and Isothermal Heat Treatment (등온열처리와 냉각에 따른 $REBa_2Cu_3O_{7-x}$ (RE=Nd, Gd, Dy) 초전도체의 상변화)

  • O, Yong-Taek;Shin, Dong-Chan;Han, Young-Hee;Sung, Tae-Hyun;Jeong, Nyeon-Ho
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.05a
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    • pp.42-45
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    • 2003
  • The phase transformation of $REBa_2Cu_3O_{7-x}$ (RE=Nd, Gd, Dy) was investigated using isothermal heat-treatment and continuous cooling in air. During continuous cooling, the $REBa_2Cu_3O_{7-x}$ (RE=123) superconducting phase with well-distributed $REBa_2Cu_3O_{7-x}$ (RE-211) was obtainde at a cooling rate of $0.001^{\circ}C$/s. Single phase RE-123 (Nd, Gd, Dy) was stable at $1050^{\circ}C$, $1050^{\circ}C$, and $950^{\circ}C$ during isothermal heat-treatment, respectively. Above these temperatures the RE-211 phase existed within the RE-123 grains. The RE-123, RE-211, $BaCu_2Od_2$, and CuO phases coexisted at $50^{\circ}C$ below the partial melting temperature for each respective rare-earth RE-123.

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Effect of Heat Treatment on the Physical Properties of LM PET Jacquard Fabrics (저융점 폴리에스터 자카드직물의 물성에 대한 열처리 효과)

  • Lee, Sun Young;Kim, Jeong Hwa;Kim, Eui Hwa;Lee, Jung Soon;Lee, Seung Goo
    • Textile Coloration and Finishing
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    • v.25 no.3
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    • pp.206-214
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    • 2013
  • There has been an increasing demand for high performance and energy-saving of blind. In order to develop the eco-friendly blind textiles, heat treatment process has been utilized for LM(Low Melting) polyester fabrics and the changes of the physical properties of the treated fabrics were examined according to temperature of heat treatment. Morphology, surface reflectance, contact angle, luster, thermal property and mechanical property of heat treated LM polyester fabrics were investigated. As results, morphology analysis of thermal treated fabrics confirmed that degree of fusion of LM polyester yarns improved with increase of temperature. Surface reflectance of thermal treated fabrics decreased with increase of temperature. Luster and contact angle of a water droplet on thermal treated fabrics increased slightly with increase of temperature. The mechanical properties of the fabrics by KES-FB system were found to be temperature-dependent and especially, bending and shear properties among them were highly related to temperature.

A Process for Recycling of Used Steel Can and Automatic Treatment System (스틸 폐캔 再活用방법과 自動化 처리장치)

  • 박형규
    • Resources Recycling
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    • v.9 no.6
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    • pp.53-57
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    • 2000
  • In the present paper, a current technical progress for recycling of used steel can is described. The developed technology was a kind of pre-treatment through an automatic equipment system to increase recycling and melting efficiency of used steel co. The process consisted of several unit processes such as breaking of steel can bale, removing dust, separation of aluminum can, delacquering, and compressing to bale. Also, aluminum powders were recovered as a by-product at the delacquering step. The process was carried out automatically through by use of the developed equipment system. The automatic system could be very available in mass treatment of used steel can.

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Effect of Hydrothermal and Enzymatic Treatments on the Physicochemical Properties of Waxy Maize Flour (열수 및 효소 처리에 의한 찰옥수수가루의 물리화학적 특성)

  • Lee, Dong-Jin;Choi, So-Mang;Lim, Seung-Taik
    • Korean Journal of Food Science and Technology
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    • v.48 no.2
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    • pp.165-171
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    • 2016
  • Physicochemical properties of waxy maize flours prepared by hydrothermal and enzymatic treatments were evaluated. Waxy maize flours were hydrothermally treated using heat-moisture treatment (HMT) and annealing (ANN) and enzymatically treated using commercial enzymes (cellulase, proteinase, and pectinase). The HMT-modified waxy maize flours had low water absorption index (WAI), melting enthalpy, viscosity, and crystallinity. However, ANN-modified and enzymatically modified waxy maize flours had high WAI, melting enthalpy, and viscosity. X-ray diffraction analysis of ANN-modified and enzymatically modified waxy maize flours revealed a typical A-type pattern and displayed sharper crystalline peaks than those observed for the control groups (native waxy maize flours). In contrast, the crystallinity of HMT-modified waxy maize flours were decreased by hydrothermal treatment.

Comparison of Enzyme Resistant Starches Formed during Heat-Moisture Treatment and Retrogradation of High Amylose Corn Starches (수분-열처리와 노화에 의해 고아밀로오스 옥수수전분으로부터 형성된 효소저항전분의 특성비교)

  • Kweon, Mee-Ra;Shin, Mal-Shick
    • Applied Biological Chemistry
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    • v.40 no.6
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    • pp.508-513
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    • 1997
  • Thermal characteristics and granular morphology on enzyme-resistant starches (RS) formed during heat-moisture treatment (HMT) and retrogradation were investigated in high amylose corn starches, Hylon V and Hylon VII. With each treatment, both starches showed a similar trend in the increase of RS, but RS yield of Hylon VII is higher than that of Hylon V. Specially, RS was increased remarkably by HMT. It was more than doubled from 11.4% to 26.6% for Hylon V and from 15.9% to 32.8% for Hylon VII. A small increase of RS resulted from retrogradation. HMT on starch increased gelatinization temperature, decreased enthalpy. Retrograded starch exhibited small three endothermic transitions at $94^{\circ}C$, $110^{\circ}C$ and $140^{\circ}C$ in differential scanning calorimetry (DSC) thermogram due to the remained ungelatinized starch granules, dissociation of amylose-lipid complex and melting of recrystallized amylose, respectively. Enzyme-resistant starches isolated from native and heat-moisture treated starches showed a broad endothermic transition at higher temperature than native starch, while retrograded starch exhibited a very sharp peak at ${\sim}150^{\circ}C$ due to the melting of amylose crystallites. Under microscopy, starch granules with HMT was not changed, but retrograded starches showed the aggregates of starch granules because amylose leached out during gelatinization. Iodine stained RS clearly showed the differences in enzyme hydrolysis on the native, heat-moisture treated and retrograded starches.

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Corrosion Behavior of As-Cast and Solution-Treated AZ91-4%RE Magnesium Alloy (주조 상태 및 용체화처리한 AZ91-4%RE 마그네슘 합금의 부식 거동)

  • Han, Jin-Gu;Hyun, Soong-Keun;Jun, Joong-Hwan
    • Journal of the Korean Society for Heat Treatment
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    • v.31 no.5
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    • pp.220-230
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    • 2018
  • The objective of this study is to investigate the effect of solution treatment on the microstructure and corrosion behavior of cast AZ91-4%RE magnesium alloy. In the as-cast state, microstructure of the AZ91-4%RE alloy was characterized by intermetallic ${\beta}(Mg_{17}Al_{12})$, $Al_{11}RE_3$ and $Al_2RE$ phase particles distributed in ${\alpha}-(Mg)$ matrix. After solution treatment, the ${\beta}$ particles with low melting point dissolved into the matrix, but Al-RE phases still remained due to their high thermal stabilities. It was found from the immersion and potentiodynamic polarization tests that corrosion rate of the AZ91-4%RE alloy increased after the solution treatment. On the contrary, EIS tests and EDS compositional analyses on the surface corrosion products indicated that the stability of the corrosion product was improved after the solution treatment. Examinations on the corroded microstructures for the ascast and solution-treated samples revealed that dissolution of the ${\beta}$ particles which play a beneficial role in suppressing corrosion propagation, would be responsible for the deterioration of corrosion resistance after the solution treatment. This result implies that the microstructural features such as amount, size and distribution of secondary phases that determine corrosion mechanism, are more influential on the corrosion rate in comparison with the stability of surface corrosion product.

Fabrication of Cu-Sheathed YBCO Thick Films by Screen Printing Method Using $Y_2$BaCu$O_5$ and BaC$O_3$ Powders (Y211 및 BaCO$_3$ 분말로 Screen Printing 법을 이용한 Cu-sheath의 YBCO 후막 제조)

  • 김경진;한상철;한영희;박병삼;정년호;윤희중;오제명;최희락;성태현
    • Progress in Superconductivity
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    • v.5 no.2
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    • pp.132-135
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    • 2004
  • We fabricated YBCO thick films by using a screen printing method with $Y_2$BaCuO$_{5}$(Y211) and BaCO$_3$ powders on Cu-substrate in $N_2$ atmosphere. Cu-sheathed YBCO thick film process is more simple and economic than YBCO coated conductor methods. The heat treatment is performed in the range of 860 - 875 $^{\circ}C$ for 5 min in the tube furnace of $N_2$ atmosphere. The flow rate of $N_2$ gas is fixed 60 $m\ell$/min. Microstructure and phases of thick films were investigated by optical microscope, X-ray diffraction(XRD) and SEM. At heat-treatment temperature, the thick films were partially melted by liquid reaction between CuO of oxidized copper substrate and the powders screen-printed on Cu-sheath. During the heat-treatment procedure, YBCO superconducting grains nucleate.e.

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