• Title/Summary/Keyword: Melting behavior

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Analysis on the Hydrologic Behavior of Heavy Snowfall in East Coast Region (동해안 지역 폭설의 수문학적 거동 분석)

  • Kim, Nam-Won;Chung, Il-Moon
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.39 no.2
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    • pp.257-262
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    • 2019
  • In order to investigate hydrological behavior of the east coast snowfall in February 2014, this study analyzed the changes of the hydrological components due to the snowmelt in the Ssangcheon watershed nearby Sokcho city. The temporal changes of hydrological components through snowfall and snowmelt processes were simulated using SWAT-MODFLOW. As a result of the analysis, snow accumulated until February is fully melted from the late March, 2014, and the stream discharge of April is more than doubled compared to the case of not considering snowmelt. The soil moisture also increased by up to 21 % due to the melting and the groundwater level rose by about 40 cm until the end of April. Thus, the heavy snowfall in February 2014 is considered to play an important role in securing water resources in this region.

Low-Temperature Sintering Behavior of Aluminum Nitride Ceramics with Added Copper Oxide or Copper

  • Hwang, Jin-Geun;Oh, Kyung-Sik;Chung, Tai-Joo;Kim, Tae-Heui;Paek, Yeong-Kyeun
    • Journal of the Korean Ceramic Society
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    • v.56 no.1
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    • pp.104-110
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    • 2019
  • The low-temperature sintering behavior of AlN was investigated through a conventional method. $CaF_2$, CuO and Cu were selected as additives based on their low melting points. When sintered at $1600^{\circ}C$ for 8 h in $N_2$ atmosphere, a sample density > 98% was obtained. The X-ray data indicated that eutectic reactions below $1200^{\circ}C$ were found. Therefore, the current systems have lower liquid formation temperatures than other systems. The liquid phase showed high dihedral angles at triple grain junctions, indicating that the liquid had poor wettability on the grain surfaces. Eventually, the liquid was likely to vaporize due to the unfavorable wetting condition. As a result, a microstructure with clean grain boundaries was obtained, resulting in higher contiguity between grains. From EDS analysis, oxygen impurity seems to be well removed in AlN lattice. Therefore, it is believed that the current systems are beneficial for reducing sintering temperature and improving oxygen removal.

Peeling Behavior of Backsheet according to Surface Temperature of Photovoltaic Module (태양광 모듈 표면 온도 제어에 따른 백시트 박리 거동)

  • Kim, Jeong-Hun;Lee, Jun-Kyu;Ahn, Young-Soo;Yeo, Jeong-Gu;Lee, Jin-Seok;Kang, Gi-Hwan;Cho, Churl-Hee
    • Korean Journal of Materials Research
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    • v.29 no.11
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    • pp.703-708
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    • 2019
  • In this study, we investigate the relationship between the peeling behavior of the backsheet of a photovoltaic(PV) module and its surface temperature in order facilitate removal of the backsheet from the PV module. At low temperatures, the backsheet does not peel off whereas, at high temperatures, part of the backsheet remains on the surface of the PV module after the peeling process. The backsheet material remaining on the surface of the PV module is confirmed by X-ray diffraction(XRD) analysis to be poly-ethylene(PE). Differential scanning calorimetry(DSC) is also performed to investigate the interfacial characteristics of the layers of the PV module. In particular, DSC provides the melting temperature($T_m$) of laminated ethylene vinyl acetate(EVA) and of the backsheet on the PV module. It is found that the backsheet does not peel off below the $T_m$ of ethylene of EVA, while the PE layer of the backsheet remains on the surface of the PV module above the $T_m$ of the PE. Thus, the backsheet is best removed at a temperature between the $T_m$ of ethylene and that of PE layer.

A study on the growth behavior of AlN single crystal according to the change of N2 in HVPE propcess (HVPE(Hydride Vapor Phase Epitaxy) 법을 적용한 N2 양의 변화에 따른 AlN 단결정의 성장 거동에 관한 연구)

  • Kyung-Pil Yin;Seung-Min Kang
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.34 no.2
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    • pp.61-65
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    • 2024
  • HVPE (Hydride vapor phase epitaxy) is a method of manufacturing thin films or single crystals using gaseous raw materials. This is a method that applies the principles of chemical vapor deposition to grow a single crystal of a material with low meltability or high melting point, and is one of the methods that can obtain a gallium nitride (GaN) single crystal. Recently, much research has been conducted to grow aluminum nitride (AlN) single crystals using this method, but good results have not yet been obtained. In this study, we attempted to grow AlN single crystals using the HVPE method. Nitrogen was used as a carrier gas in the growth process, and the growth results according to changes in the amount of nitrogen (N2) were examined. Changes in growth crystals as the amount of nitrogen increased were confirmed. The shape of the grown AlN single crystal was observed using an optical microscope, and the rocking curve was measured using double crystal X-ray diffractometry (DCXRD) to confirm the creation of the AlN crystal. The crystallinity of single crystals was also investigated.

Preparation and PTC Characteristics of Poly(dimethylsiloxane) Modified EPDM/HDPE Composite (Poly(dimethylsiloxane) 변성 EPDM/HDPE 복합체의 제조와 PTC 특성)

  • Kang, Doo-Whan;Kim, Sung-Soo
    • Polymer(Korea)
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    • v.32 no.4
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    • pp.353-358
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    • 2008
  • Maleated ethylene-propylene-diene terpolymer (MEPDM) was prepared from solution polymerization of EPDM and maleic anhydride. MEPDM-grafted-poly (dimethylsiloxane) (PDMS) copolymer (MEPDM-g-PDMS) was prepared from copolymerization of MEPDM with $\alpha$,$\omega$-hydroxyl group terminated PDMS. The MEPDM-g-PDMS was compounded with HDPE and 4-ethoxybenzoic acid modified MWCNT at $180^{\circ}C$ and positive temperature coefficient (PCT) behavior of the MWCNT composite was investigated. Surface modification of MWCNT enabled it to be more uniformly dispersed in polymer matrix and decreased aggregation of particles. Electrical resistivity of the composite was abruptly increased at melting temperature and PTC intensity of 2.3 was obtained at 15% loading of surface modified CNT.

Effect of GaGe Sputtering Power on Ga Doping in Phase Change Memory Materials (상 변화 메모리 재료 내의 Ga 주입에 미치는 GaGe 스퍼터링 전력의 영향)

  • Jung, Soon-Won;Lee, Seung-Yun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.5
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    • pp.285-290
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    • 2015
  • The phase change memory material is an active element in phase change memory and exhibits reversible phase transition behavior by thermal energy input. The doping of the phase change memory material with Ga leads to the increase of its crystallization temperature and the improvement of its amorphous stability. In this study, we investigated the effect of GaGe sputtering power on the formation of the phase change memory material including Ga. The deposition rate linearly increased to a maximum of 127 nm and the surface roughness remained uniform as the GaGe sputtering power increased in the range from 0 to 75 W. The Ga concentration in the thin film material abruptly increased at the critical sputtering power of 60 W. This influence of GaGe sputtering power was confirmed to result from a combined sputtering-evaporation process of Ga occurring due to the low melting point of Ga ($29.77^{\circ}C$).

Studies of Degradation Behavior of Stereochemical Poly(lactide) Blend Fibers Prepared by Electrospinning (전기방사에 의한 이성질 폴리락타이드 블렌드의 섬유제조와 분해거동에 관한 연구)

  • Jang, Ei-Sup;Lee, Won-Ki
    • Journal of Environmental Science International
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    • v.23 no.3
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    • pp.473-481
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    • 2014
  • Poly(lactide)s(PLA) is an attractive material to solve the problem of waste plastic accumulation in nature because of its biodegradability. The lactide exists in three stereoisomeric configurations: L-lactide, D-lactide, and meso-lactide. PLA stereocomplexes, formed by the mixing of two enantiomers, poly(L-lactide)(PLLA) and poly(D-lactide)(PDLA), have many favorable characteristics because the stereocomplex showed $50^{\circ}C$ higher melting point than each enantiomeric polymer and the resistance toward degradation increased. In this study, we investigated the influence of the composition and the optical purity of each component on the formation of stereocomplexes. Also, the nanofibers of stereochemical PLA and their blends were prepared by electrospinning method. The properties of the obtained fibers were analyzed by differential scanning calorimetry and scanning electron microscopy. The results showed that a degree of stereocomplex was controlled by change of optical purity of each component. The enzymatic degradation of the fibers were strongly dependent on the stereocomplex.

Corrosion Characteristics of Ti alloy for Removable Partial Denture (국소의치용 티타늄 합금의 부식 특성)

  • Kim, Jeong-Jae;Kim, Won-Gi
    • The Journal of the Korea Contents Association
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    • v.14 no.4
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    • pp.237-242
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    • 2014
  • In this study, surface characteristics and corrosion behaviors have been investigated in addition to Zr elements on the low elastic modulus Ti-30Ta alloy. Low elastic modulus Ti-30Ta-xZr(x : 3, 7 and 15 wt %) alloys were prepared by arc melting and then heat treated at $1000^{\circ}C$ for 24 hrs in an argon atmosphere. Microstructures of the alloys were examined by field emission scanning electron microscope(FE-SEM) and X-ray diffractometer(XRD). Electrochemical experiments were performed using a conventional three-electrode configuration with a sample working electrode, a high density carbon counter electrode and a saturated calomel reference electrode. According to the result of polarization behavior in the Ti-30Ta-xZr alloys, the current density of homogenized Ti-30Ta-15Zr in the passive region was lower than the other alloys.

PTC/NTC Behaviors of Nanostructured Carbon Black-filled HDPE Polymer Composites

  • Park, Soo-Jin;Seo, Min-Kang;Lee, Jae-Rock
    • Carbon letters
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    • v.2 no.3_4
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    • pp.159-164
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    • 2001
  • In this study, the effects of carbon black (CB) content and anodic oxidation treatment with $AgNO_3$ on positive temperature coefficient (PTC) behavior of CB/HDPE nanocomposites were investigated. Also, the addition of elastomer as a toughing agent was studied. The 20~50 wt% of CB, 0~5 wtt% of elastomer, and 1 wt% of $AgNO_3$-filled HDPE nanocomposites were prepared using the internal mixer in 60 rpm at $160{\circ}C$ and the compression-molded at $180{\circ}C$ for 10 min. As a result, the room temperature resistivity and PTC intensity of the composites were dependent, to a large extent, on the content of CB, addition of elastomer, and surface chemical properties that were controlled in the relative arrangements of the carbon black aggregates in a polymeric matrix. Moreover, the composites with relatively low room temperature resistivity and suitable PTC intensity could be achieved by treatment of $AgNO_3$. Consequently, it was noted that PTC effect was due to the deagglomeration or the breakage of the conductive networks caused by thermal expansion or crystalline melting of the polymeric matrix.

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Preparation and characterization of ibuprofen-loaded alginate microspheres using ethylenediamine as a crosslinker

  • Maiti, Sabyasachi;Sa, Biswanath
    • Advances in Traditional Medicine
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    • v.8 no.2
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    • pp.178-186
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    • 2008
  • In this study, ionotropic gelation method was used for the preparation of ibuprofen-loaded calcium alginate (CALG) and ethylenediamine (EDA) treated calcium alginate (EDA-CALG) microspheres. The effect of EDA-treatment on drug entrapment efficiency, particle size, morphology, swelling behavior and in vitro release characteristics of the microspheres was investigated by varying its concentration from 0.5 to 2% (v/v). The reduction in drug entrapment efficiency by a maximum of 44.60% was noted for EDA-CALG microspheres compared to untreated CALG microspheres. The particle size and swelling index of EDA-CALG microspheres were reduced with increasing EDA concentration. All the microspheres were observed to retain their spherical shapes with rough surfaces. EDA-CALG microspheres prepared using 1% and 2% v/v EDA, released almost all of its content within 7 h in pH 6.8 phosphate buffer, however, CALG microspheres were found to release the same within 3 h. The intensity of melting endothermic peak of ibuprofen reduced significantly at lower drug load as experienced from DSC thermograms. The FT-IR spectrum of pure ibuprofen, ibuprofen-loaded CALG and EDA-CALG microspheres showed the characteristic band of C = O stretching vibration of ibuprofen. Hence, this study revealed that EDA can be employed for the preparation of ibuprofen-loaded CALG microspheres to retard the drug release to some extent.