• 제목/요약/키워드: Melt properties

검색결과 859건 처리시간 0.023초

Thermotropic Liquid Crystal Polymer or Silica Nano-particle Filled Polyester Composite Fibers

  • Kim, Seong-Hun;Kim, Jun-Young;Ahn, Seon-Hoon
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 2003년도 The Korea-Japan Joint Symposium
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    • pp.65-66
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    • 2003
  • Ternary blend fibers (TBFs) based on melt blends of PEN, PET, and TLCP were prepared by melt blending and spinning to achieve high performance fibers. The reinforcement effect and the TLCP fibrillar structure resulted in the improvement of mechanical properties for TBFs. Molecular orientation was an important factor in determining the tensile strength and modulus of TBFs. Another part of this research is silica nano-particle filled PEN composites were melt-blended to improve mechanical and physicalproperties, and processability. The tensile modulus and strength were improved adding silica nano-particles to the PEN. The decreased melt viscosity by the fumed silica resulted in the improvement of the processability. The fumed silica may act as a nucleating agent in the PEN matrix.

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Temperature Field and Cooling Rate of Laser Cladding with Wire Feeding

  • Kim, Jae-Do;Peng, Yun
    • Journal of Mechanical Science and Technology
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    • 제14권8호
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    • pp.851-860
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    • 2000
  • Temperature field and cooling rate are important parameters to influence the properties of clad layer and the heat affected zone. In this paper the temperature field and cooling rate of laser cladding are studied by a two-dimensional time-dependent finite element model. Experiment has been carried out by Nd:YAG laser cladding with wire feeding. Research results indicate that at the beginning of cladding, the width and depth of melt pool increase with cladding time. The cooling rate is related to position, cladding time, cladding speed, and preheating temperature. The temperature near melt pool changes rapidly while the temperature far from melt pool changes slowly. With the increase of cladding time, cooling rate decreases. The further the distance from the melt pool, the lower the temperature and the slower the cooling rate. The faster the cladding speed, the faster the cooling rate. The higher the preheating temperature, the slower the cooling rate. The FEM results coincide well with the experiment results.

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Grain growth and superconducting properties of melt-processed (Y-Sm-Nd)-Ba-Cu-O composite oxides

  • Kim, So-Jung
    • 한국결정성장학회지
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    • 제15권4호
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    • pp.141-144
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    • 2005
  • [ $(Y_{0.5}Sm_{0.25}Nd_{0.25})Ba_2Cu_3O_y$ ] [(YSN)-123] high $T_c$ composite superconductors with $CeO_2$ addition were systematically investigated by top seeded melt growth (TSMG) process in air atmosphere. A melt textured $NdBa_2Cu_3O_y$ (Nd-123) single crystal was used as a seed for achieving the c-axis alignment large grains perpendicular to the surface of (YSN)-123 composite oxides. The size of $(Y_{0.5}Sm_{0.25}Nd_{0.25})_2BaCuO_5$ [(YSN)211] nonsuperconducting inclusions of the melt textured (YSN)-123 samples with $CeO_2$ addition were remarkably reduced and uniformly distributed within the (YSN)123 superconducting matrix except in the region very close to the Nd-123 seed crystal. The sample showed a sharp superconducting transition of 91 K.

Recent Development of Bulk High-Tc Superconductors

  • 유상임
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 춘계학술대회 논문집 초전도 자성체
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    • pp.88-95
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    • 2002
  • Recent development in the field of RE-Ba-Cu-O (REBCO, RE: Y or rare earth elements) bulk high-Tc superconductors (HTS) is reviewed in the present paper. After the fatal weak link problem of sintered REBCO superconductors has been overcome by melt processing, this field has been greatly advanced during last ten years. The critical current density $J_c$ at 77 K has been enhanced by introducing effective flux pinning sites into the $REBa_2Cu_3O_y$ (RE123) superconducting matrix. Large melt-textured REBCO bulk crystals have been fabricated with the TSMG(top-seeded melt growth) technique. Mechanical properties of REBCO bulks have been improved by using the Ag additive or epoxy resin. Real bulk applications such as current lead, fault current limiter, flywheel energy storage system, magnetic field source, magnetic separation system, and etc., surely come true near future.

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Magnetic Properties and Microstructures of Melt Spun Misch Metal-Ferroboron Alloys

  • Ko, K.Y.;Booth, J.G.;Al-Kanani, H.J.;Lee, H.Y.
    • Journal of Magnetics
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    • 제1권2호
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    • pp.82-85
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    • 1996
  • Magnetic properties and microstructures of melt spun misch metal-ferroboron alloys were investigated. The major phase is the tetragonal (rare earth)$_2Fe_{14}B$ phase. Magnetic properties showed coercivity of 5.6 kOe, remanence of 7.85 kG, and so energy product 8.9 MGOe. Microsturctures in optimum properties showed that matrix was composed of Ce-rich phase while second phase La-rich-oxygen phase with less amount of Fe element than matrix, and triple junction with La-rich phase contrary to matrix.

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Modification and Properties of Polypropylene Fibers Using Aluminosiloxane

  • Yoon, Cheol-Soo;Ji, Dong-Sun
    • Fibers and Polymers
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    • 제4권4호
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    • pp.210-214
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    • 2003
  • Siloxylated polypropylene fibers composed of polypropylene (PP) and aluminosiloxane (AS) were prepared by melt blending followed by spinning. The effects of blend compositions on the thermal behaviors, surface and tensile properties of PP/AS blend fibers were investigated by DSC, WAXD, SEM, static honestometer, etc. The heat of fusion of PP/AS blends decreased with increasing AS contents. In addition, the peak intensity of PP/AS blends in X-ray diffraction patterns decreased with increasing AS contents. It was observed that the silicone molecules exist and well distribute on the surface of siloxylated polypropylene fibers. From the results of the half-life period measurements, the anti-static properties of PP fibers siloxylated with AS was found to be significantly modified.

고분자 래핑(wrapping)에 의한 전처리가 ABS/MWNT 나노복합체의 물성에 미치는 영향 (Effect of Polymer Wrapping on the Properties of ABS/MWNT Nanocomposites)

  • 김정환;민병길
    • 한국염색가공학회지
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    • 제22권1호
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    • pp.37-42
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    • 2010
  • ABS/MWNT nanocomposites were prepared by using MWNT wrapped with SAN through melt compounding. Effect of wrapping of MWNT by SAN on the morphology, mechanical and electrical properties of ABS/MWNT were analyzed. It was found that SAN could wrap MWNT effectively indicated by the increased thickness after wrapping, which is presumably due to helical structure of polyacrylonitrile component in a block copolymer of SAN. MWNT was observed to be dispersed more evenly in ABS matrix by SAN wrapping, which resulted in improved tensile properties of the composites. On the other hand, there was little effect on the impact strength and electrical properties of ABS having inherently high impact strength.

Synthesis of Thermally Stable Organosilicate for Exfoliated Poly(ethylene terephthalate) Nanocomposite with Superior Tensile Properties

  • Kim, Ki-Hong;Kim, Keon-Hyong;Huh, June;Jo, Won-Ho
    • Macromolecular Research
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    • 제15권2호
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    • pp.178-184
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    • 2007
  • A poly(ethylene terephthalate) (PET)/organosilicate nanocomposite, with enhanced mechanical properties, has been prepared using the melt intercalation method. For this purpose, a new organic modifier has been synthesized for the preparation of organosilicate, which is thermally stable and compatible with PET. The use of the new organosilicate yielded almost exfoliated PET nanocomposite; whereas, the PET nanocomposites prepared by use of commercial organoclays (Cloisite 15A and 30B) show only an intercalated morphology. Particularly, the use of the new organosilicate showed an enhanced tensile modulus, and without sacrifice of the tensile strength and elongation on breaking, while the use of commercial organoclays only exhibit a trade-off between those mechanical properties.

Effects of seed geometry on the crystal growth and the magnetic properties of single grain REBCO bulk superconductors

  • Lee, Hwi-Joo;Park, Soon-dong;Jun, Bung-Hyuck;Kim, Chan-Joong;Lee, Hee-Gyoun
    • 한국초전도ㆍ저온공학회논문지
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    • 제19권3호
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    • pp.33-39
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    • 2017
  • This study presents that the orientation and the geometry of seed affect on the growth behavior of melt processed single grain REBCO bulk superconductor and its magnetic properties. The effects of seed geometry have been investigated for thin $30mm{\times}30mm$ rectangular powder compacts. Single grain REBCO bulk superconductors have been grown successfully by a top seed melt growth method for 8-mm thick vertical thin REBCO slab. Asymmetric structures have been developed at the front surface and at the rear surface of the specimen. Higher magnetic properties have been obtained for the specimen that c-axis is normal to the specimen surface. The relationships between microstructure, grain growth and magnetic properties have been discussed.

Melt-blown법에 의해 제조된 Polypropylene 부직포의 방사 조건별 특성과 기능화된 Zr-MOF 함유량에 따른 소취율 변화에 대한 연구 (Deodorization Rate according to Zr-MOF Content and the Properties from Spinning Conditions of Polypropylene Non-woven Fabric Manufactured by Melt-blown Method)

  • 최익성;민문홍;김한일;이우승;노경규;박성우
    • 한국염색가공학회지
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    • 제30권3호
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    • pp.199-207
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    • 2018
  • In this study, the properties of polypropylene(PP) non-woven fabric spun under various conditions by the Melt-blown method were verified, and the deodorant content and deodorization of PP non-woven fabric after deodorant-treatment were investigated. PP non-woven fabrics are manufactured by varying the temperature of spin beam, hot air temperature and amount, the RPM of collector R/O and the distance between collector and spinneret, which affects the structure of the non-woven fabric. After that, the structural characteristics and air permeability of the non-woven fabric were measured. The experimental results show that the amount of air, the distance between the collector and the spinneret significantly affect the structural characteristics and air permeability of the PP non-woven fabric. And, regardless of the weight of the PP non-woven fabric, the deodorizing effect of UiO-66 MOF deodorant add-on ratio and content was higher.