• Title/Summary/Keyword: Melt flow rate

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Nb doped strontium titanate single crystal growth by floating zone method (Floating zone법에 의한 Nb를 첨가한 strontium titanate 단결정 성장)

  • Jeon, Byong-Sik;Cho, Hyun;Orr, Keun-Ho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.5 no.3
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    • pp.215-222
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    • 1995
  • Nb doped strontium titanate single crystals were grown by the floating zone method. The doping amount of $Nb_2O_5$ was 0.2 wt %. Those crystals were grown in air and N z atmosphere and the growth rate was 5 mmlhr and rotation speed of upper and lower shaft was 30 rpm. The shapes of melt - feed rod interface depending on sintering temperatures were observed. In air atmosphere, the flow rate of air was 1.5 ${\ell}/min$ and in $N_2$ atmosphere, that of $N_2$ gas was 0.5 ${\ell}/min$. As grown crystals were analyseQ by XRD, Laue back - reflection and chemical etching. After annealing in $N_2$ atmosphere, resistivities of crystals were measured and the activation energies of each samples were calculated.

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Critical-speed Increase of Optical Disk by Applying Residual Stresses (잔류응력 부과에 의한 광디스크의 임계속도 증가)

  • Kim, Nam Woong;Na, Sang Sik
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.5
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    • pp.2092-2099
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    • 2013
  • Through the data transfer race in industry since 1990s, the operational speed of optical disk drive(ODD) becomes commonly over 10,000 rpm. Such high speed operation inevitably causes the vibration, which is also the disturbances in the read-write process of pick-up servo-controller. Generally the vibration disturbance problem can be solved by the vibration isolation using the rubber mount and the increase of robustness of the pick-up servo-controller. Optical disk itself has not been targeted for the vibration reduction, because it is manufactured under the standardized format. In this paper we focused on the increase of critical speed of optical disk, that is, the improvement of dynamic characteristics, with the control of residual stresses which are come from the injection molding process. To do this, first, the residual stresses induced from the injection molding process are calculated using finite element method. The major design parameters of the process conditions are flow rate and melt temperature, which control the residual stresses in optical disk. Second, the critical speed of optical disk is calculated with modal analysis considering residual stress distributions. It was found out that the critical speed can be improved by the control of operational parameters in the injection molding process.

Research for High Quality Ingot Production in Large Diameter Continuous Czochralski Method (대구경 연속성장 초크랄스키법에서 고품질 잉곳 생산을 위한 연구)

  • Lee, Yu Ri;Jung, Jae Hak
    • Current Photovoltaic Research
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    • v.4 no.3
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    • pp.124-129
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    • 2016
  • Recently industry has voiced a need for optimally designing the production process of low-cost, high-quality ingots by improving productivity and reducing production costs with the Czochralski process. Crystalline defect control is important for the production of high-quality ingots. Also oxygen is one of the most important impurities that influence crystalline defects in single crystals. Oxygen is dissolved into the silicon melt from the silica crucible and incorporated into the crystalline a far larger amount than other additives or impurities. Then it is eluted during the cooling process, there by causing various defect. Excessive quantities of oxygen degrade the quality of silicone. However an appropriate amount of oxygen can be beneficial. because it eliminates metallic impurities within the silicone. Therefore, when growing crystals, an attempt should be made not to eliminate oxygen, but to uniformly maintain its concentration. Thus, the control of oxygen concentration is essential for crystalline growth. At present, the control of oxygen concentration is actively being studied based on the interdependence of various factors such as crystal rotation, crucible rotation, argon flow, pressure, magnet position and magnetic strength. However for methods using a magnetic field, the initial investment and operating costs of the equipment affect the wafer pricing. Hence in this study simulations were performed with the purpose of producing low-cost, high-quality ingots through the development of a process to optimize oxygen concentration without the use of magnets and through the following. a process appropriate to the defect-free range was determined by regulating the pulling rate of the crystals.

Modeling of Billet Shape in Spray Forming Process (분무성형공정에서의 빌렛형상 모델링)

  • Jang, Dong-Hun;Gang, Sin-Il;Lee, Eon-Sik
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.21 no.6
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    • pp.961-970
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    • 1997
  • A numerical method is presented to predict and analyze the shape of a growing billet produced from the "spray forming process" which is a fairly new near-net shape manufacturing process. It is important to understand the mechanism of billet growing because one can obtain a billet with the desired final shape without secondary operations by accurate control of the billet shape, and it can also serve as a base for heat transfer and deformation analysis. The shape of a growing billet is determined by the flow rate of the alloy melt, the mode of nozzle scanning which is due to cam profile, the initial positio of the spray nozzle, scanning angle, and the withdrawal speed of the substrate. In the present study, a theoretical model is first established to predict the shape of the billet and next the effects of the most dominent processing conditions, such as withdrawal speed of the substrate and the cam profile, on the shape of the growing billet are studied. Process conditions are obtained to produce a billet with uniform diameter and flat top surface, and an ASP30 high speed steel billet is manufactured using the same process conditions established from the simulation.imulation.

Bio-based Polypropylene Composites: Plausible Sustainable Alternative to Plastics in Automotive Applications

  • Ji Won Kwon;Sarbaranjan Paria;In Soo Han;Hyeok Jee;Sung Hwa Park;Sang Hwan Choi;Jeong Seok Oh
    • Elastomers and Composites
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    • v.59 no.2
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    • pp.51-63
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    • 2024
  • Polypropylene (PP) is a commodity plastic that is widely used owing to its cost-effectiveness, lightweight nature, easy processability, and outstanding chemical and thermomechanical characteristics. However, the imperative to address energy and environmental crises has spurred global initiatives toward a circular economy, necessitating sustainable alternatives to traditional fossil-fuel-derived plastics. In this study, we conducted a series of comparative investigations of bio-based polypropylene (bio-PP) blends with current PP of the same and different grades. An extrusion-based processing methodology was employed for the bio-PP composites. Talc was used as an active filler for the preparation of the composites. A comparative analysis with the current petroleum-based PP indicated that the thermal properties and tensile characteristics of the bio-PP blends and composites remained largely unaltered, signifying the feasibility of bio-PP as a potential substitute for the current PP. To achieve a higher Young's modulus, elongation at break (EAB), and melt flow index (MFI), we prepared different composites of PP of different grades and bio-PP with varying talc contents. Interestingly, at higher biomass contents, the composites exhibited higher MFI and EAB values with comparable Young's moduli. Notably, the impact strengths of the composites with various biomass and talc contents remained unaltered. In-depth investigations through surface analysis confirmed the uniform dispersion of talc within the composite matrix. Furthermore, the moldability of the bio-PP composites was substantiated by comprehensive rheological property assessments encompassing shear rate and shear viscosity. Thus, from these outcomes, the fabricated bio-PP-based composites could be an alternative to petroleum-based PP composites for sustainable automobile applications.

Reuse Technology of LiCl Salt Waste Generated from Electrolytic Reduction Process of Spent Oxide Fuel (전해환원공정발생 LiCl 염폐기물 재생기술)

  • Cho, Yung-Zun;Jung, Jin-Seok;Lee, Han-Soo;Kim, In-Tae
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.8 no.1
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    • pp.57-63
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    • 2010
  • Layer crystallization process was tested for the separation(or concentration) of cesium and strontium fission products in a LiCl waste salt generated from an electrolytic reduction process of a spent oxide fuel. In a crystallization process, impurities (CsCl and $SrCl_2$) are concentrated in a small fraction of the LiCl salt by the solubility difference between the melt phase and the crystal phase. Based on the phase diagram of LiCl-CsCl-$SrCl_2$ system, the separation possibility by using crystallization was determined and the molten salt temperature profile during layer crystallization operation was predicted by using mathematical calculation. In the layer crystallization process, the crystal growth rate strongly affects the crystal structure and therefore the separation efficiency. In the conditions of about 20-25 l/min cooling air flow rate and less than 0.2g/min/$cm^2$ crystal flux, the separation efficiency of both CsCl and $SrCl_2$ showed about 90% by the layer crystallization process, assuming a LiCl salt reuse rate of 90wt%.

Reformation of Naphtha Cracking Bottom Oil for the Preparation of Carbon Fiber Precursor Pitch (탄소섬유용 프리커서 피치를 제조하기 위한 나프타 분해 잔사유의 개질)

  • Kim, Myoung Cheol;Eom, Sang Yong;Ryu, Seung Kon;Edie, Dan D.
    • Korean Chemical Engineering Research
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    • v.43 no.6
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    • pp.745-750
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    • 2005
  • Naphtha cracking bottoms(NCB) oil was reformed by varying the heat treatment temperature, treatment time, and nitrogen flow rate in preparation of precursor pitch for isotropic pitch-based carbon fibers and activated carbon fibers. The reformed pitches were investigated in the yield, softening point, elementary analysis, and molecular weight distribution, and then the precursors reformed were melt spun to certify the optimum reforming conditions. The optimum precursor pitch was prepared when the NCB oil was reformed at $380^{\circ}C$, 3 h and 1.25 vvm $N_2$, and it's the softening point was around $240^{\circ}C$. The reforming resulted in product yield of 21 wt%. The C/H mole ratio of the precursor pitch increased from 1.07 to 1.34, the aromaticity increased from 0.85 to 0.88. The insolubles in benzene and quinoline were 30.0 wt% and 1.5 wt%, respectively. The spinning temperature was about $50^{\circ}C$ higher than the softening point. The molecular weights of the precursor components were distributed from 250 to 1250, and 80% of them were in the range of 250 to 700.

A Study on the Mechanical and Rheological Properties of the Recycled Polyethylene Composites with Ground Waste Tire Powder (재생 폴리에틸렌/폐타이어 분말 복합체의 기계적 특성 및 유변학적 특성에 관한 연구)

  • Kye, H.;Shin, K.;Bang, D.
    • Elastomers and Composites
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    • v.41 no.2
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    • pp.97-107
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    • 2006
  • The recycled polyethylene composites with various ratio of ground waste tire powder were manufactured by using a fully intermeshing co-rotating twin screw extruder for the reuse of waste tire scrap. In this investigation, the ground waste tire powders (GWTP) were blended with virgin HDPE and recycled polyethylene in the weight ratio of 0 to 50 wt.%. Mechanical properties such as tensile strength, elongation at break and impact strength were measured by using ASTM standard. The experimental results for the various composite showed that the tensile strength of composites decreased with increasing GWTP ratio, while elongation at break increased with the amounts of GWTP. On the other hand, the impact strength for the three kinds of composites showed maximum at the 30 wt.% of GWTP and then decreased. Morphology of the fracture surface tends to be rough with increasing waste tire powder content. Rheological properties were investigated by measuring the shear viscosity against shear rates and softening temperatures. They showed that melt viscosity of rubber composites in this study subsequently increased with increasing GWTP content as a result of increase of flow resistance against external stress and followed a Power-law behavior.

Feasibility Study of Wetland-pond Systems for Water Quality Improvement and Agricultural Reuse (습지-연못 연계시스템에 의한 수질개선과 농업적 재이용 타당성 분석)

  • Jang, Jae-Ho;Jung, Kwang-Wook;Ham, Jong-Hwa;Yoon, Chun-Gyeong
    • Korean Journal of Ecology and Environment
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    • v.37 no.3 s.108
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    • pp.344-354
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    • 2004
  • A pilot study was performed from September 2000 to April 2004 to examine the feasibility of the wetland-pond system for the agricultural reuse of reclaimed water. The wetland system was a subsurface flow type, with a hydraulic residence time of 3.5 days, and the subsequent pond was 8 $m^3$ in volume (2 m ${\times}$ 2 m ${\times}$ 2 m) and operated with intermittent-discharge and continuous flow types. The wetland system was effective in treating the sewage; median removal efficiencies of $BOD_5$ and TSS were above 70.0%, with mean effluent concentrations of 27.1 and 16.8 mg $L^{-1}$, respectively, for these constituents. However, they did often exceed the effluent water quality standards of 20 mg $L^{-1}$. Removal of T-N and T-P was relatively less effective and mean effluent concentrations were approximately 103.2 and 7.2 mg $L^{-1}$, respectively. The wetland system demonstrated high removal rate (92 ${\sim}$ 90%) of microorganisms, but effluent concentrations were in the range of 300 ${\sim}$ 16,000 MPN 100 $mL^{-1}$ which is still high for agricultural reuse. The subsequent pond system provided further treatment of the wetland effluent, and especially additional microorganisms removal in addition to wetland-pond system could reduce the mean concentration to 1,000 MPN 100 $mL^{-1}$ from about $10^5$ MPN 100 $mL^{-1}$ of wetland influent. Other parameters in the pond system showed seasonal variation, and the upper layer of the pond water column became remarkably clear immediately after ice melt. Overall, the wetland system was found to be adequate for treating sewage with stable removal efficiency, and the subsequent pond was effective for further polishing. This study concerned agricultural reuse of reclaimed water using natural systems. Considering stable performance and effective removal of bacterial indicators as well as other water quality parameters, low maintenance, and cost-effectiveness, wetland- pond system was thought to be an effective and feasible alternative for agricultural reuse of reclaimed water in rural area.