• Earthquakes and Structures
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• v.12 no.2
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• pp.251-262
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• 2017

The present research intends to study the effects of the seismic soil-foundation-structure interaction (SFSI) on the dynamic response of various buildings. Two methods including direct and Cone model were studied through 3D finite element method using ABAQUS software. Cone model as an approximate method to consider the SFSI phenomenon was developed and evaluated for both high and low rise buildings. Effect of soil nonlinearity, foundation rigidity and embedment as well as friction coefficient between soil-foundation interfaces during seismic excitation are investigated. Validity and performance of both approaches are evaluated as reference graphs for Cone model and infinite boundary condition, soil nonlinearity and amplification factor for direct method. A series of calculations by DeepSoil for inverse earthquake record modification was conducted. A comparison of the two methods was carried out by root-mean-square-deviation (RMSD) tool for maximum lateral displacement and story shear forces which verifies that Cone model results have good agreement with direct method. It was concluded that Cone method is a convenient, fast and rather accurate method as an approximate way to count for soil media.

• Journal of Microbiology and Biotechnology
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• v.23 no.9
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• pp.1229-1243
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• 2013

In this paper, an air isolate (NITT6L) has been screened based on hemolytic activity, emulsification activity, drop collapsing test, and oil displacement test, as well as lipase activity. It was found that strain NITT6L was able to reduce the surface tension of the medium from 61.5 to 39.83 mN/m and could form stable emulsions with tested vegetable oils. Morphological, biochemical, 16S rRNA sequencing analyses, and fatty acid methyl ester analysis using gas chromatography confirmed that the air isolate under study was Pseudomonas aeruginosa. Characterization of the biosurfactant using agar double diffusion assay revealed that the biosurfactant was anionic in nature, and CTAB-methylene blue assay and Molisch test revealed its glycolipid nature. The FT-IR spectrum confirmed that the crude biosurfactant was a rhamnolipid. Using unoptimized medium containing sucrose as the carbon source, the isolate was found to produce 0.3 mg/ml of rhamnolipid in batch cultivation (shake flask) at $37^{\circ}C$ and pH 7. Optimization of the medium components was carried out using design of experiments and the yield of rhamnolipid has been enhanced to 4.6 mg/ml in 72 h of fermentation.

• Structural Engineering and Mechanics
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• v.64 no.3
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• pp.381-390
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• 2017

Present paper deals with the large amplitude flexural vibration of carbon nanotube reinforced composite (CNTRC) plates. Distribution of CNTs as reinforcements may be uniform or functionally graded (FG). The equivalent material properties of the composite media are obtained according to a refined rule of mixtures which contains efficiency parameters. To account for the large deformations, von $K{\acute{a}}rm{\acute{a}}n$ type of geometrical nonlinearity is included into the formulation. The matrix representation of the governing equations is obtained according to the Ritz method where the basic shape functions are written in terms of the Chebyshev polynomials. Time dependency of the problem is eliminated by means of the Galerkin method and the resulting nonlinear eigenvalue problem is solved employing a direct displacement control approach. Results are obtained for completely clamped and completely simply supported plates. Results are first validated for the especial cases of FG-CNTRC and cross-ply laminated plates. Afterwards, parametric studies are given for FG-CNTRC plates with different boundary conditions. It is shown that, nonlinear frequencies are highly dependent to the volume fraction and dispersion profiles of CNTs. Furthermore, mode redistribution is observed in both simply supported and clamped FG-CNTRC plates.

• Bulletin of the Korean Chemical Society
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• v.32 no.3
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• pp.768-778
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• 2011

Calixpyrroles and related macrocycles are non-planer synthetic anion receptors that have attracted considerable attentions in recent years. Although the synthesis of calix[4]pyrrole (known as meso-octamethylporphyrinogen) was reported more than 100 years ago, the anion binding properties were first discovered in 1996. The simple calix[4]pyrroles can be synthesized in single step in high yield by condensation of pyrrole with acetone. The compounds showed preferential binding for halide anions including fluoride, phosphate, carboxylate, and chloride in organic media. Efforts to improve the anion affinity of calix[4]pyrrole and to enhance its selectivity have led to the synthesis of a variety of new calixpyrrole derivatives. Among the various modifications, introduction of straps on one side of the calix[4]pyrroles are the most effective. Incorporation of aromatic rings other than pyrroles also exhibited interesting binding behaviour. Introduction of signalling units as part of the strapping element enable to detect the anions on chromogenic or fluorogenic fashion. Finding of the anion transport properties across the membrane and cytotoxic effects of the calix[4]pyrroles open new window for calixpyrrole-related research. The polymer-incorporated systems have also been employed as anion complexants in solvent-solvent extraction. These old, yet easy-to-make macrocycles have well advanced more recently with the discovery of the ion-pair complexation properties. In this review, the synthetic developments and anion binding properties of calixpyrroles for the last decades will be discussed and will cover the advances in calixpyrrole chemistry.

• Journal of Radiopharmaceuticals and Molecular Probes
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• v.2 no.1
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• pp.17-21
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• 2016

Alkali metal fluoride sources (MFs) such as potassium fluoride (KF) have been widely used as a fluoride source in the nucleophilic displacement reaction. However, they have low solubility and nucleophilicity in most of the organic solvents. Bulky fluoride sources such as tetrabutylammonium fluoride (TBAF) were substituted for MFs to improve these properties. However, hygroscopic property of TBAF makes it less convenient for handling as well as its strong basic property can make the side-reaction occur. Recently, novel fluoride sources have been developed to solve these problems. In this paper, we would like to introduce coordinated fluoride sources as a new fluoride sources such as tetrabutylammonium tetra(t-butyl alcohol)-coordinated fluoride, crown ether metal complex fluoride, and various bulky alcohols coordinated fluoride complexes. In particular, bulky alcohol coordinated fluoride source could generated by the controlled hydrogen-bonded of fluoride with alcohols and these fluoride sources have better stability and reactivity with showing low hygroscopic property. The study of these fluoride sources will help to understand the characteristic of [$^{18}F$]fluoride for increasing the radiochemical yield in the [$^{18}F$]radiofluorination.

• Structural Engineering and Mechanics
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• v.51 no.4
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• pp.685-705
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• 2014

This paper presents a new formulation for forward scalar wave simulations in semi-infinite media. Perfectly-Matched-Layers (PMLs) are used as a wave absorbing boundary layer to surround a finite computational domain truncated from the semi-infinite domain. In this work, a hybrid formulation was developed for the simulation of scalar wave motion in two-dimensional PML-truncated domains. In this formulation, displacements and stresses are considered as unknowns in the PML domain, while only displacements are considered to be unknowns in the interior domain. This formulation reduces computational cost compared to fully-mixed formulations. To obtain governing wave equations in the PML region, complex coordinate stretching transformation was introduced to equilibrium, constitutive, and compatibility equations in the frequency domain. Then, equations were converted back to the time-domain using the inverse Fourier transform. The resulting equations are mixed (contain both displacements and stresses), and are coupled with the displacement-only equation in the regular domain. The Newmark method was used for the time integration of the semi-discrete equations.

• Geomechanics and Engineering
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• v.29 no.1
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• pp.53-63
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• 2022

Simplified analytical solutions are developed for the dynamic analyses of an axially loaded pile foundation embedded in a transverse-isotropic, fluid-filled, poro-visco-elastic soil with rigid substratum. The pile is modeled as a viscoelastic Rayleigh-Love rod, while the surrounding soil is regarded as a transversely isotropic, liquid-saturated, viscoelastic, porous medium of which the mechanical behavior is represented by the Boer's poroelastic media model and the fractional derivative model. Upon the separation of variables, the frequency-domain responses for the impedance function of the pile top, and the vertical displacement and the axial force along the pile shaft are gained. Then by virtue of the convolution theorem and the inverse Fourier transform, the time-domain velocity response of the pile head is derived. The presented solutions are validated, compared to the existing solution, the finite element model (FEM) results, and the field test data. Parametric analyses are made to show the effect of the soil anisotropy and the excitation frequency on the pile-soil dynamic responses.

• Journal of the Korean earth science society
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• v.32 no.6
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• pp.640-653
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• 2011

We simulate the propagation of earthquake waves in the continental margin of Antarctica using the elastic wave modeling algorithm, which is modified to be suitable for acoustic-elastic coupled media and earthquake source. To simulate the various types of earthquake source, the staggered-grid finite-difference method, which is composed of velocity-stress formulae, can be more appropriate to use than the conventional, displacement-based, finite-difference method. We simulate the elastic wave propagation generated by earthquakes combining 3D staggered-grid finite-difference algorithm composed of displacement-velocity-stress formulae with double couple mechanisms for earthquake source. Through numerical tests for left-lateral strike-slip fault, normal fault and reverse fault, we could confirm that the first arrival of P waves at the surface is in a good agreement with the theoretically-predicted results based on the focal mechanism of an earthquake. Numerical results for a model made after the subduction zone in the continental margin of Antarctica showed that earthquake waves, generated by the reverse fault and propagating through the continental crust, the oceanic crust and the ocean, are accurately described.

• Journal of the Korean Geotechnical Society
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• v.18 no.6
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• pp.5-16
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• 2002

A hydrogeomechanical numerical model is presented to evaluate rainfall impacts on groundwater flow in slopes and slope stability. This numerical model is developed based on the fully coupled poroelastic governing equations for groundwater flow in deforming variably saturated geologic media and the Galerkin finite element method. A series of numerical experiments using the model developed are then applied to an unsaturated slope under various rainfall rates. The numerical simulation results show that the overall hydromechanical slope stability deteriorates, and the potential failure nay initiate from the slope toe and propagate toward the slope crest as the rainfall rate increases. From the viewpoint of hydrogeology, the pressure head and hence the total hydraulic head increase as the rainfall rate increases. As a result, the groundwater table rises, the unsaturated zone reduces, the seepage face expands from the slope toe toward the slope crest, and the groundwater flow velocity increases along the seepage face. From the viewpoint of geomechanics, the horizontal displacement increases, and the vertical displacement decreases toward the slope toe as the rainfall rate increases. This may result from the buoyancy effect associated with the groundwater table rise as the rainfall rate increases. As a result, the overall deformation intensifies toward the slope toe, and the unstable zone, in which the factor of safety against shear failure is less than 1, becomes thicker near the slope toe and propagates from the slope toe toward the slope crest. The numerical simulation results also suggest that the potential tension failure is likely to occur within the slope between the potential shear failure surface and the ground surface.

• Tribology and Lubricants
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• v.11 no.5
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• pp.128-135
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• 1995

Atomic force microscopy/friction force microscopy (AFM/FFM) techniques are increasingly used for tribological studies of engineering surfaces at scales, ranging from atomic and molecular to microscales. These techniques have been used to study surface roughness, adhesion, friction, scratching/wear, indentation, detection of material transfer, and boundary lubrication and for nanofabrication/nanomachining purposes. Micro/nanotribological studies of single-crystal silicon, natural diamond, magnetic media (magnetic tapes and disks) and magnetic heads have been conducted. Commonly measured roughness parameters are found to be scale dependent, requiring the need of scale-independent fractal parameters to characterize surface roughness. Measurements of atomic-scale friction of a freshly-cleaved highly-oriented pyrolytic graphite exhibited the same periodicity as that of corresponding topography. However, the peaks in friction and those in corresponding topography were displaced relative to each other. Variations in atomic-scale friction and the observed displacement has been explained by the variations in interatomic forces in the normal and lateral directions. Local variation in microscale friction is found to correspond to the local slope suggesting that a ratchet mechanism is responsible for this variation. Directionality in the friction is observed on both micro- and macro scales which results from the surface preparation and anisotropy in surface roughness. Microscale friction is generally found to be smaller than the macrofriction as there is less ploughing contribution in microscale measurements. Microscale friction is load dependent and friction values increase with an increase in the normal load approaching to the macrofriction at contact stresses higher than the hardness of the softer material. Wear rate for single-crystal silicon is approximately constant for various loads and test durations. However, for magnetic disks with a multilayered thin-film structure, the wear of the diamond like carbon overcoat is catastrophic. Breakdown of thin films can be detected with AFM. Evolution of the wear has also been studied using AFM. Wear is found to be initiated at nono scratches. AFM has been modified to obtain load-displacement curves and for nanoindentation hardness measurements with depth of indentation as low as 1 mm. Scratching and indentation on nanoscales are the powerful ways to screen for adhesion and resistance to deformation of ultrathin fdms. Detection of material transfer on a nanoscale is possible with AFM. Boundary lubrication studies and measurement of lubricant-film thichness with a lateral resolution on a nanoscale have been conducted using AFM. Self-assembled monolyers and chemically-bonded lubricant films with a mobile fraction are superior in wear resistance. Finally, AFM has also shown to be useful for nanofabrication/nanomachining. Friction and wear on micro-and nanoscales have been found to be generally smaller compared to that at macroscales. Therefore, micro/nanotribological studies may help def'me the regimes for ultra-low friction and near zero wear.