• Title/Summary/Keyword: Mechanical and electrochemical characteristics

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Machining Characteristics according to Electrochemical Polishing (ECP) Conditions of Stainless Steel Mesh (스테인리스 망의 전기화학 폴리싱(ECP) 조건에 따른 가공 특성)

  • Kim, Uk Su;Park, Jeong Woo
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.14 no.6
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    • pp.41-48
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    • 2015
  • Stainless steel mesh has been used as a filter in various fields, including domestic, medical, etc. However, the surface before machining may have an adverse effect the product quality and performance because it is not smooth. Especially, adsorbed impurities in the surface result in difficulty in cleaning. Therefore, in this paper, we propose an improved surface quality through electrochemical polishing (ECP). Two electrodes, composed of STS304 (anode) and copper (cathode) underwent machining with two conditions according to polishing time and current density. As the polishing time and current density increase, the surface of curvature decreases, and roughness and material removal rate (MRR) improves. The machined surface roughness and image were obtained through the atomic force microscope (AFM) and stereoscopic microscope. The study also analyzed hydrophilic effect through contact angles. This obtains corrosion resistance, smoothness, hydrophilic property, etc.

An Experimental Study on the Characteristics of Electrochemical Reactions of RDF/RPF in the Direct Carbon Fuel Cell (직접탄소 연료전지에서 RDF 및 RPF의 전기화학반응 특성에 관한 실험적 연구)

  • Ahn, Seong Yool;Rhie, Young Hoon;Eom, Seong Yong;Sung, Yeon Mo;Moon, Cheor Eon;Kang, Ki Joong;Choi, Gyung Min;Kim, Duck Jool
    • Transactions of the Korean hydrogen and new energy society
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    • v.23 no.5
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    • pp.513-520
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    • 2012
  • The electrochemical reaction of refuse derived fuel (RDF) and refuse plastic/paper fuel (RPF) was investigated in the direct carbon fuel cell (DCFC) system. The open circuit voltage (OCV) of RPF was higher than RDF and other coals because of its thermal reactive characteristic under carbon dioxide. The thermal reactivity of fuels was investigated by thermogravimetric analysis method. and the reaction rate of RPF was higher than other fuels. The behavior of all sample's potential was analogous in the beginning region of electrochemical reactions due to similar functional groups on the surface of fuels analyzed by X-ray Photoelectron Spectroscopy experiments. The potential level of RDF and RPF decreased rapidly comparing to coals in the next of the electrochemical reaction because the surface area and pore volume investigated by nitrogen gas adsorption tests were smaller than coals. This characteristic signifies the contact surface between electrolyte and fuel is restricted. The potential of fuels was maintained to the high current density region over 40 $mA/cm^2$ by total carbon component. The maximum power density of RDF and RPF reached up to 45~70% comparing to coal. The obvious improvement of maximum power density by increasing operating temperature was observed in both refuse fuels.

Corrosion Resistance Properties of Rice Husk Ash Blended Concrete

  • Ganesan, K.;Rajagopal, K.;Thangavel, K.
    • Corrosion Science and Technology
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    • v.6 no.1
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    • pp.12-17
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    • 2007
  • Portland cement incorporating supplementary cementing material develops excellent mechanical properties and long term durability characteristics. India is a leading rice producing country and rice husk is considered as waste in the rice milling industries. In this present work, the rice husk ash (RHA) was added to concrete as cement replacement from 0 to 30%. Corrosion performance of reinforcing steel embedded in RHA blended concretes was studied using linear polarization, AC impedance and gravimetric methods. The corrosion rate of steel bars embedded in RHA concretes were compared with control concrete. The results clearly indicate that the corrosion rate of reinforcing steel embedded in concrete is significantly reduced with the incorporation of RHA. A good correlation among gravimetric method and electrochemical methods was observed. Electrochemical impedance study showed 98 percentage reduction in corrosion rate to the RHA blended concrete with 15% replacement than control concrete.

Improvement of Current-Voltage Characteristics for optimization Electrolyte (최적의 전해액 선정을 위한 전류-전압 특성고찰)

  • Park, Sung-Woo;Han, Sang-Jun;Lee, Young-Kyun;Lee, Woo-Sun;Seo, Yong-Jin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.544-544
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    • 2008
  • Metal-CMP 공정시 높은 압력을 가해 줌으로 인하여 금속배선의 디싱 현상과 에로젼 현상이 발생하고 다공성의 하부층에 균열이 생기는 문제점을 개선하고자, 낮은 하력에서 금속막의 광역 평탄화를 이룰 수 있는 ECMP(Electrochemical Chemical Mechanical Polishing)가 생겨나게 되었다. 본 논문에서는 다양한 전해액의 전류-전압 특성 곡선을 비교 분석하여, 패시베이션막이 형성되는 곳을 알 수 있었고, CV와 LSV 법을 통해 전기화학적인 특성을 고찰하였다.

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The Study on the Electrochemical Polarization Characteristics of Hydrogen Embrittlement for Ferrite Stainless Steel with Welding Conditions (용접조건에 따른 페라이트 스테인리스강에 대한 수소취성의 전기화학적 분극특성에 관한 연구)

  • Choi, Byung-Il;Lim, Uh-Joh
    • Journal of the Korean Institute of Gas
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    • v.9 no.4 s.29
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    • pp.30-35
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    • 2005
  • In order to examine the electrochemical polarization characteristics of hydrogen embrittlement far STS444 with welding conditions, this paper carried out the accelerated hydrogen osmosis test and the electrochemical polarization test. That is, in $0.5M\; H_2SO_4+0.001M\;As_2O_3$ solution, the hydrogen embrittlement behavior of STS444 added to load of $1,400kg/cm^2$ together with hydrogen osmosis by current of $30mA/cm^2$ far 60 min. was considered. In researching the electrochemical polarization characteristics of hydrogen embrittlement for STS444 with welding conditions, the previous study clarified that tensile strength or elongation became low influenced by absorption of oil or water before welding. In this paper, we proposed the advanced mechanism of hydrogen embrittlement that integrated electrochemical corrosion with the existing mechanism of hydrogen embrirtlement.

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A Study on the Machining Characteristics of the Electropolishing of Aluminum (알루미늄 재의 전해연마 가공특성에 관한 연구)

  • 조규선;박봉진;이은상
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1997.10a
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    • pp.943-946
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    • 1997
  • Electropolishing is the controlled electrochemical removal of surface metal, resultmg in a brilliant appearance andimproved properties. Sometimes described as "reverse plating," the process has a leveling effect, which produces smoothnessand increased reflectivity. Unlike conventional mechanical finishing systems, the electropolishing does not smear, bend,stress or fracture the crystalline metal surface to achieve smoothness. Instead, electropolishing removes metal from thesurface producing a unidirectional pattern that is stress-free, microscopically smooth and often highly reflective. In addition,improved corrosion resistance and passivity are achieved on many ferrous and some non-ferrous alloys. Pure aluminium doesnot electropolish well, if at all, but most other alloys of aluminum electropolish excellently.Therefore, the aim of this study is to determine the characteristics of electropolishing aluminium alloy in term of currentdensity, machining time, temperature, electrode gap and workpiece surface measurementkpiece surface measurement

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Numerical Study on Oxygen Depletion Characteristics of Porous Cathodes in Anode-Supported Solid Oxide Fuel Cells (음극지지 고체산화물 연료전지 다공성 양극에서의 산소고갈 특성에 관한 수치해석 연구)

  • Shin, Dongwoo;Nam, Jin Hyun;Kim, Charn-Jung
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.41 no.4
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    • pp.257-268
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    • 2017
  • This paper proposes an efficient two-dimensional simulation model for solid oxide fuel cells (SOFCs) based on the electrochemical effectiveness model. The effectiveness model is known to accurately predict the current generation performance of SOFC electrodes, by considering the complex reaction/transport processes that occur within thin active functional layers near the electrolyte. After validation tests, the two-dimensional simulation model was used to calculate the distribution of current density and oxygen concentration transverse to the flow channel in anode-supported SOFCs, with which the oxygen depletion characteristics were investigated in detail. In addition, simulations were also conducted to determine the minimum number of grids required in the transverse direction to efficiently obtain accurate results.

Investigation of the Electrochemical Characteristics of Electropolished Super Austenite Stainless Steel with Seawater Temperature (전해연마한 슈퍼오스테나이트 스테인리스강의 해수온도에 따른 전기화학적 특성 연구)

  • Hyun-Kyu Hwang;Seong-Jong Kim
    • Corrosion Science and Technology
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    • v.22 no.3
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    • pp.164-174
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    • 2023
  • Electropolishing technology uses an electrochemical reaction and improves surface roughness, glossiness, and corrosion resistance. In this investigation, electropolishing was performed to improve the corrosion resistance of super austenitic stainless steel. As a result of electropolishing, surface roughness (0.16 ㎛) was improved by about 76.5% compared to mechanical polishing (0.68 ㎛). In addition, the electropolished surface was smooth because the average and variance values of the depth histogram were small. Tafel analysis was performed after a potentiodynamic polarization experiment with seawater temperature, and the microstructure was compared and analyzed. The corrosion current density at 30 ℃, 60 ℃, and 90 ℃ was reduced by 0.083 ㎂/cm2, 0.296 ㎂/cm2, and 0.341 ㎂/cm2, respectively. Pitting occurred in the mechanical polished specimen at 30 ℃, but partial intergranular corrosion was observed in the electropolished specimen, and pitting occurred predominantly at both 60 ℃ and 90 ℃. In addition, the damage depths of the electropolished specimen were shallower than those of mechanical polishing at 30 ℃ and 60 ℃, but the opposite result was seen at 90 ℃.