• Journal of Korean Ophthalmic Optics Society
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• v.18 no.4
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• pp.365-371
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• 2013

Purpose: In this study, we evaluated the physical and thermal properties of the compositions made by blending glass fiber (GF) of different contents into glass fiber polyamide-66, and investigated if the compositions applying to the glasses frame to replace the TR-90, which is polyamide-12 resin used as an injection-type spectacle frame material. Methods: To investigate the characteristics change of polyamide-66 (PA-66) compositions with the change of the content of glass fibers, we produced a composition of the content by using a twin-screw extruder. The mechanical strength of the composition production was measured and coating properties as well as cutting processability were evaluated. We evaluated the applicability of the glasses frame by comparison the results of new compositions with characterizations of traditional TR. Results: For the results of the characterization of Polyamide-66/GF composition, we found that the higher increase of content of the glass fiber, the less mold shrinkage rate, and the mechanical strength was increased. Tensile strength increased from $498kg/cm^2$ for 0 wt% of the content of the glass fibers to $849kg/cm^2$ for 30 wt% of the content of the glass fibers. As a result of a coating evaluation, the strength of coating was 4B in the GF 5wt% and 5B, which was extremely good coating characteristics, in the over than GF 5 wt%. Conclusions: In case that 30 wt% of the glass fiber was blended, the mechanical strength was greatly improved, the hardness was increased, injection temperature increased due to increase of the viscosity, and the flow mark of the product may occur. The paint coating of PA-66 blended with glass fiber was all excellent. With general evaluating physical properties and workability properties it was determined that around 10 wt% of the content of the glass fibers was possible to apply a spectacle frame.

• Korean Chemical Engineering Research
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• v.55 no.3
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• pp.395-400
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• 2017

Coke strength was increased by adding ash-free coal (AFC) binder. In this study, the effect of the AFC binder on the physical and chemical properties of coke was experimentally investigated to understand the molecular mechanism for the improved coke strength. For reduced $CO_2$ emission in steelmaking industry, torrefied biomass fuel mixed with coal binder is also considered. The interface between the base coal and AFC was thus examined using Scanning Electron Microscope (SEM). The coke strength was commonly measured by performing the indirect tensile test and Nuclear Magnetic Resonance (NMR) spectroscopy in $^1H$ and $^{13}C$ modes. For comprehensive mechanism study of the enhanced coke strength thus obtained, ordinary coal for thermal power plant use was carbonized with AFC for subsequent SEM examination. The NMR spectroscopy results of coke samples positively revealed that the tensile strength was proportional to the average number of aromatic rings.

• Explosives and Blasting
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• v.41 no.3
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• pp.38-61
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• 2023

An Excavation Damaged Zone(EDZ) caused by blasting impact changes rock properties, in situ stress distribution, etc., and its effects are noticeable at around a radioactive waste repository located at deep underground. In particular, the increase in permeability due to the formation of cracks may significantly increase the amount of groundwater inflow and the possibility of radioactive nuclide outflow. In this study, FLAC2D and FLAC3D were used to analyze the mechanical and thermal behaviors for three categories: a)No EDZ, b)Uniform EDZ, and c)Random EDZ. It was found that the tunnel displacement in the Random EDZ case was 423% higher than that in the No EDZ case and was 16% higher than that in the Uniform EDZ case. Tunnel inflow in the Random EDZ was also 17.3% and 10.8% higher than that in the No EDZ and the Uniform EDZ case, respectively. The permeability around the tunnel was increased by up to 10 times in the corner of the tunnel wall and roof due to the stress redistribution after excavation. From the computer simulation, it was found that the permeability around the tunnel wall was partially increased but the overall tunnel inflow was decreased with increase of stress ratio. Mechanical analysis using FLAC 3D showed similar results. Slight difference between 2D and 3D could be explained with the development of plastic zone during the advance of tunnel excavation in 3D.

• Applied Chemistry for Engineering
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• v.9 no.6
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• pp.884-888
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• 1998

Effects of heating time under high temperature on the thermal and mechanical properties of neutron shielding materials based on modified (KNS-102), hydrogenated(KNS-106) bisphenol-A type epoxy resin and phenol-novolac(KNS-611) type epoxy resin for radioactive material shipping casks have been investigated. At early stages, the initial decomposition temperatures of the shielding materials of KNS-102, KNS-106 and KNS-611 increased with the heating time under high temperature, but it was rarely affected by the heating time in the later stages. In addition, the thermal conductivities of KNS-102 and KNS-106 decreased with heating time, but that of KNS-611 increased with the heating time. On the contrary, the thermal expansion coefficients of neutron shielding materials decreased with increase of heating time. At the high temperature, the tensile strength and flexural strength of the shielding materials of KNS-102 and KNS-611 increased with heating time, but those of KNS-106 decreased with increase of heating time. And the heating time under high temperature on the neutron shielding materials did not show measurable loss of weight and hydrogen content.

• Polymer(Korea)
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• v.29 no.2
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• pp.183-189
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• 2005

Films of poly(vinyl alcohol)(PVA)/chitosan blends and its blend hydrogels were prepared by the solution casting method. The state of miscibility of the blends and blend hydrogels were examined over the entire composition range by differential scanning carorimetry (DSC), thermogravimetry (TGA), and dynamic mechanical analysis (DMA). DSC analysis shows the depression of melting point of PVA in the blends and the decrease of crystallization temperature of PVA in the blends were observed with increasing chitosan content in the blends. TGA analysis indicates that chitosan was thermally more stable than PVA and the thermal stability of PVA in the blends was higher than that of pure PVA, due to some interactions between two component polymers in the blend. The glass transition temperature $(T_g)$ of the chitosan and of PVA, measured by DMA, were at 160 and $90^{\circ}C$, respectively. The $T_g$ of the blends was changed with the content of chitosan in the blends. The results of thermal and viscoelastic analysis indicate some miscibility between component polymers in the blend exists. Moisture and cross linking in the blend and blend hydrogel, which strongly change thermal and physical properties of hydrophilic polymers, affected the miscibility of chitosan and PVA to a small extent.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.21 no.1
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• pp.21-26
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• 2011

Ni-YSZ (Yttria Stabilized Zirconia) composite powders were fabricated by glycine nitrate process. The prepared powders were sintered at $1300{\sim}1400^{\circ}C$ for 4 h in air and reduced at $1000^{\circ}C$ for 2 h in a nitrogen and hydrogen atmosphere. The microstructure, electrical conductivity, thermal expansion and mechanical properties of the Ni-YSZ cermets have been investigated with respect to the volume contents of Ni. A porous microstructure consisting of homogeneously distributed Ni and YSZ phases together with well-connected grains was observed. It was found that the open porosity, electrical conductivity, thermal expansion and bending strength of the cermets are sensitive to the volume content of Ni. The Ni-YSZ cermet containing 40 vol% Ni was ascertained to be the optimum composition. This composition offers sufficient open porosity of more than 30 %, superior electrical conductivities of 917.4 S/cm at $1000^{\circ}C$ and a moderate average thermal expansion coefficient of $12.6{\times}10^{-6}^{\circ}C^{-1}$ between room temperature and $1000^{\circ}C$.

• The Journal of Engineering Geology
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• v.17 no.3
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• pp.359-365
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• 2007

Freezing and thawing cycle is one of the major weathering-induced factors in the mechanical weathering of the rock mass. This natural process accelerates rock weathering process by breaking down the parent rock materials and makes soil or weathered rock formation in a rock slope surface zone. It can also cause reduction of the shear strength in slopes. It is important to calculate the deterioration depth caused by freezing-thawing for a slope stability analysis. In this study, deterioration depths of rock slope due to freezing-thawing were calculated using the 1-D heat conductivity equation. The temperature distribution analysis was also carried out using collected temperature distribution data for last five years of several major cities in Korea. The analysis was performed based on the distributed rock types in study areas. Thermal conductivities, specific heats and densities of the calculation rocks are tested in the laboratory. They are thermal properties of rocks as input parameters for calculating deterioration depths. Finally, the paper is showing the calculated deterioration depths of each rock type slopes in several major cities of Korea.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.32 no.5
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• pp.212-217
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• 2022

Large thermal stress due to the difference between silicon carbide and graphite's coefficients of thermal expansion could be formed during crystal growing process of silicon carbide (SiC) at high temperature. The large thermal stress could separate the SiC seed crystals from graphite components, which bring about the drop of the seed crystal during crystal growth. However, the bonding properties of SiC seed crystal module has hardly reported so far. In this study, SiC and graphite were bonded using 3 types of bonding agents and a three-point bending tests using a mixed-mode flexure test were conducted for the bonded samples to evaluate the bonding characteristics between SiC and graphite. Raman spectroscopy, X-ray Photoelectron Spectroscopy, and X-ray Computed Tomography were used to analyze the bonding characteristics and the microstructures of the SiC-graphite interfaces bonded with the bonding agents. As results, an excellent bonding agent was chosen to fabricate SiC seed crystal module with 50 mm in diameter. An SiC single crystal with 50 mm in diameter was successfully grown without falling out during top seeded solution growth of SiC at high temperature.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.13 no.2
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• pp.919-925
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• 2012

We tried to blend PLLA and PDLA at overall compositions to form PLA stereocomplexes (SC). The presence of the SC crystalline phase in the PLLA matrix was verified by differential scanning calorimetry (DSC). As a result, a various PDLA composition of the PLA SC blends can influence PLA SC formation. And the largest amount of PLA SC crystallites was formed when PLLA/PDLA ratio is 50/50. In addition, we have tried to do PLA SC toughening with two impact modifiers in 92/8, 85/15 ratio of PLLA/PDLA to enhance the mechanical properties such as impact strength. Thermal and mechanical properties of PLA SC were investigated by DSC, HDT, Izod impact tester and UTM. PLA SC formation decreased when 10-20 wt% of Strong120 (impact modifier) was added. On the other hand, there is no effect on PLA SC formation when 10-20% of Elvaloy (impact modifier) was added. HDT values dramatically increased over $100^{\circ}C$ with the addition of PDLA. However, HDT decreased as Strong120 and Elvaloy content increased. Finally, we could find well balanced composition of toughened PLA SC with 10wt% of impact modifier in flexural modulus and impact strength.

• Proceedings of the Korean Vacuum Society Conference
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• 2016.02a
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• pp.286-286
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• 2016

Hexagonal boron nitride (hBN) is a dielectric insulator with a two-dimensional (2D) layered structure. It is an appealing substrate dielectric for many applications due to its favorable properties, such as a wide band gap energy, chemical inertness and high thermal conductivity[1]. Furthermore, its remarkable mechanical strength renders few-layered hBN a flexible and transparent substrate, ideal for next-generation electronics and optoelectronics in applications. However, the difficulty of preparing high quality large-area hBN films has hindered their widespread use. Generally, large-area hBN layers prepared by chemical vapor deposition (CVD) usually exhibit polycrystalline structures with a typical average grain size of several microns. It has been reported that grain boundaries or dislocations in hBN can degrade its electronic or mechanical properties. Accordingly, large-area single crystalline hBN layers are desired to fully realize the potential advantages of hBN in device applications. In this presentation, we report the growth and transfer of centimeter-sized, nearly single crystal hexagonal boron nitride (hBN) few-layer films using Ni(111) single crystal substrates. The hBN films were grown on Ni(111) substrates using atmospheric pressure chemical vapor deposition (APCVD). The grown films were transferred to arbitrary substrates via an electrochemical delamination technique, and remaining Ni(111) substrates were repeatedly re-used. The crystallinity of the grown films from the atomic to centimeter scale was confirmed based on transmission electron microscopy (TEM) and reflection high energy electron diffraction (RHEED). Careful study of the growth parameters was also carried out. Moreover, various characterizations confirmed that the grown films exhibited typical characteristics of hexagonal boron nitride layers over the entire area. Our results suggest that hBN can be widely used in various applications where large-area, high quality, and single crystalline 2D insulating layers are required.