• 공업화학
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• 제28권6호
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• pp.626-631
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• 2017

투명 플라스틱 소재를 광학용으로 적용하기 위해서는 표면경도 및 내열성과 같은 물성의 개선이 필요하다. 본 연구에서는 이러한 물성의 개선을 위하여 자외선 경화형 유기/무기 하이브리드를 합성하였다. 유기소재 안에 무기 성분이 균일하게 최적상태로 분산되도록 하기 위하여 졸-겔 반응을 기초로 하여 동시에 반응이 진행되도록 하였다. 이러한 졸-겔 반응과 빠른 자외선 경화반응을 적절히 조합하여 우레탄 아크릴레이트 유기소재 안에 무기 성분의 분산성이 향상되도록 하여 투명성이 우수한 코팅층을 형성시킬 수 있었다. 자외선 경화형 유기/무기 하이브리드의 경화도와 코팅 물성을 변화시키기 위하여 다양한 종류의 알콕시 실란을 사용하였다. 이러한 자외선 경화형 유기/무기 하이브리드 코팅에서의 무기 성분의 함량에 따라 표면 경도와 내열성을 조절할 수 있었다.

• 지구물리와물리탐사
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• 제5권3호
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• pp.169-177
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• 2002

일반 반사법 탐사 모델링에서 효율적인 주파수영역 수치모델링의 실용화를 위해 무엇보다 해결해야할 과제는 파장당 격자수를 줄이는 것이다. 본 연구에서는 이에 착안하여 수치분산 및 수치이방성을 최소화시키면서 한 파장당 필요한 격자수를 줄일 수 있는 가중평균 유한요소법을 개발하였다. 강성행렬과 질량행렬은 네 개의 사각형 유한요소로 확장하였으며, 모든 격자점이 포함되도록 유한요소를 배열하여 조합하였다. 확장된 네 개의 강성행렬과 질량행렬은 가중평균계수를 주어 선형결합하는 방법으로 가중평균하였다. 가중평균계수는 확장된 25점 평균차분법을 사용하여 가중평균계수를 결정하였다. 또한, 정확도 향상은 2차원 균질모델 과 수평층 모델에서 해석해와 한 파장당 4개의 격자점을 준 가중평균 유한요소법 수치해 비교를 통하여 검증하였다. 또한, 석유탐사에서 활용성이 높은 향사구조 모델을 선정하여 이의 반응을 관찰한 결과 지층경계면외에 네 개의 사각형 유한요소들의 구성으로 인한 인위적인 파의 도달이 인식되지 않았다. 따라서, 본 연구에서 고안된 가중평균 유한요소법은 주파수영역에서 폭 넓은 수치모델링연구을 가능하게 할 것이다.

• 한국전산구조공학회논문집
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• 제16권1호
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• pp.69-76
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• 2003

최근 들어 심해역에 대한 개발과 합섬섬유 재질 케이블의 발달로 인하여 저장력 케이블의 사용이 증가되었다. 저장력 케이블은 장력에 의한 복원력이 작기 때문에 대변위가 발생하게 되며, 따라서 기하학적 비선형이 강하게 나타나게 된다. 또한 해양환경에서는 유체 비선형도 작용하게 된다. 본 연구에서는 수치해석적 방법을 통하여 불균일하게 구성된 예인되는 저장력 케이블의 3차원 동적거동 해석을 수행한다. 수치해석에서는 유체 및 기하학적 비선형과 굽힘강성이 고려되며, 유한차분법(음해법)을 적용하여 풀이된다. 비선형 해를 구하기 위해서 뉴톤-랍슨 방법을 사용한다. 대형 행렬을 풀이하기 위하여 불록삼중대각행렬 풀이법이 적용되는데, 이 방법은 일반적인 행렬 풀이법인 가우스-조르단 방법에 비하여 계산시간을 상당히 줄일 수 있었다. 선배열 음탐 케이블에 대한 다양한 예제해석을 수행하였으며, 해석결과는 미국 우즈홀 해양연구소에서 개발된 프로그램 결과와 잘 일치하였다.

• 대한방사성의약품학회지
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• 제3권2호
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• pp.54-58
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• 2017

Matrix-assisted laser desorption/ionization time-of-flight mass spectrometry(MALDI-TOF MS) is one of the powerful methods that enable analysis of small molecules as well as large molecules up to about 500,000 Da without severe fragmentation. MALDI-TOF MS, thus, has been a very useful an analytical tool for the confirmation of synthetic molecules, probing PTMs, and identifying structures of a given protein. In recent nuclear medicine, MALDI-TOF MS liner ion mode helps researcher calculate the average number of chelator(or linkage) per an antibody conjugate, such as DOTA-(or DFO-) trastuzumab for labeling a medical radioisotope. This simple technique can be utilized to improve the labeling method and control the quality at the development of antibody-based radiopharmaceuticals, which is very effected to diagnosis and therapy for in vivo tumor cells, with radioisotopes like $^{89}Zr$, $^{64}Cu$, and 177Lu. To minimize the error, MALDI-TOF MS measurement is repeatedly performed for each sample in this study, and external calibration is carried out after data collection.

• 동굴
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• 제71호
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• pp.1-4
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• 2006

Chloromethylnaphthalene is a valuable compound for obtaining of the plant growing stimulator - -napthylacetic acid. Chloromethylation of naphthalene by paraformaldehyde in the presence of glacial acetic acid, phosphoric and hydrochloric acids at temperature 80 - 85C and duration - 6 hours the -chloromethylnaphthalene yield was 55-57%. Using Box-Wilson method for mathematical planning of experiment carried out optimization of its synthesis for purpose increasing -chloromethylnaphthalene yield. Preliminary, one - factor experiments were carried out for selecting independence main parameters influencing on the synthesis. A full factor experiment of 23 with extended matrix of planning was used for optimization. Aiming to increase the -chloromethylnaphthalene yield, the obtained mathematical model was used for program of sharp raising on the reply surface. The received optimal conditions for the -chloromethylnaphthalene synthesis were selected as following: molar ratio of naphthalene parapfsormaldehyde of 1 : 2 temperature - 105C duration of the reaction - 3 hours. The yield of -chloromethylnaphthalene under these optimal conditions was 75%.

• ETRI Journal
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• 제35권2호
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• pp.311-320
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• 2013

In most spectral clustering approaches, the Gaussian kernel-based similarity measure is used to construct the affinity matrix. However, such a similarity measure does not work well on a dataset with a nonlinear and elongated structure. In this paper, we present a new similarity measure to deal with the nonlinearity issue. The maximum flow between data points is computed as the new similarity, which can satisfy the requirement for similarity in the clustering method. Additionally, the new similarity carries the global and local relations between data. We apply it to spectral clustering and compare the proposed similarity measure with other state-of-the-art methods on both synthetic and real-world data. The experiment results show the superiority of the new similarity: 1) The max-flow-based similarity measure can significantly improve the performance of spectral clustering; 2) It is robust and not sensitive to the parameters.

• 한국정보통신학회:학술대회논문집
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• 한국해양정보통신학회 2004년도 SMICS 2004 International Symposium on Maritime and Communication Sciences
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• pp.36-37
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• 2004

$\alpha$-Chloromethylnaphthalene is a valuable compound for obtaining of the plant growing stimulator - $\alpha$-napthylacetic acid. Chloromethylation of naphthalene by paraformaldehyde in the presence of glacial acetic acid, phosphoric and hydrochloric acids at temperature 80-85$^{\circ}C$ and duration - 6 hours the $\alpha$-chloromethyl-naphthalene yield was 55-57%. Using Box-Wilson method for mathematical planning of experiment carried out optimization of its synthesis for purpose increasing $\alpha$-chloromethylnaphthalene yield. Preliminary, one - factor experiments were carried out for selecting independence main parameters influencing on the synthesis. A full factor experiment of 2$^3$with extended matrix of planning was used for optimization. Aiming to increase the $\alpha$-chloromethylnaphthalene yield, the obtained mathematical model was used for program of sharp raising on the reply surface. The received optimal conditions for the $\alpha$-chloromethylnaphthalene synthesis were selected as following: molar ratio of naphthalene - parapfsormaldehyde of 1 : 2; temperature -105$^{\circ}C$; duration of the reaction -3 hours. The yield of $\alpha$-chloromethylnaphthalene under these optimal conditions was 75 %.

• Corrosion Science and Technology
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• 제21권6호
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• pp.445-453
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• 2022

SiO_x was prepared from a mixture of Si and SiO₂ via high-energy ball milling as a negative electrode material for Li-ion batteries. The molar ratio of Si to SiO₂ as precursors and the milling time were varied to identify the synthetic condition that could exhibit desirable anode performances. With an appropriate milling time, the material showed a unique microstructure in which amorphous Si nanoparticles were intimately embedded within the SiO₂ matrix. The interface between the Si and SiO₂ was composed of silicon suboxides with Si oxidation states from 0 to +4 as proven by X-ray photoelectron spectroscopy and electrochemical analysis. With the addition of a conductive carbon (Super P carbon black) as a coating material, the SiO_x/C manifested superior specific capacity to a commercial SiO_x/C composite without compromising its cycle-life performance. The simple mechanochemical method described in this study will shed light on cost-effective synthesis of high-capacity silicon oxides as promising anode materials.

• 한국수자원학회:학술대회논문집
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• 한국수자원학회 2023년도 학술발표회
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• pp.25-25
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• 2023

The ensemble optimal interpolation (EnOI) scheme is a sub-optimal alternative to the ensemble Kalman filter (EnKF) with a reduced computational demand making it potentially more suitable for operational applications. Since only one model is integrated forward instead of an ensemble of model realizations, online estimation of the background error covariance matrix is not possible in the EnOI scheme. In this study, we investigate two Gaussian noise based ensemble generation strategies to produce dynamic covariance matrices for assimilation of water level observations into a distributed hydrological model. In the first approach, spatially correlated noise, sampled from a normal distribution with a fixed fractional error parameter (which controls its standard deviation), is added to the model forecast state vector to prepare the ensembles. In the second method, we use an adaptive error estimation technique based on the innovation diagnostics to estimate this error parameter within the assimilation framework. The results from a real and a set of synthetic experiments indicate that the EnOI scheme can provide better results when an optimal EnKF is not identified, but performs worse than the ensemble filter when the true error characteristics are known. Furthermore, while the adaptive approach is able to reduce the sensitivity to the fractional error parameter affecting the first (non-adaptive) approach, results are usually worse at ungauged locations with the former.

• 한국환경농학회지
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• 제30권3호
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• pp.323-329
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• 2011

BACKGROUND: The conazoles, difenoconazole, diniconazole, hexaconazole, penconazole and tetraconazole are a large class of synthetic fungicides used extensively for foliage and seed treatments in agricultural crops. The extensive use of conazoles has brought concerns on the potentiality of environmental contamination and toxicity. Thus studies on the development of methods for monitoring the conazoles are required. METHODS AND RESULTS: A modified quick, easy, effective, rugged and safe (QuEChERS) method was involved in sample preparation. Quadrapole time of flight mass spectrometer (Q-TOF MS) in electron spray ionization (ESI) mode was employed to determine conazoles in garlic samples. The limit of detection (LOD) and limit of quantification (LOQ) of conazoles by Q-TOF-MS ranged from 0.001 to 0.002 mg/L and 0.002 to 0.005 mg/L, respectively. Q-TOF-MS analysis exhibited less than 2.6 ppm error of accurate mass measurements for the detection of conazoles spiked at 0.05 mg/L in garlic matrix. Recovery values of conazoles fortified in garlic samples at 0.02, 0.05 and 0.1 mg/L were between 79.2 and 106.2% with a maximum 11.8% of standard deviation. No detectable conazoles were found in the domestic market samples by using the Q-TOF-MS method. CONCLUSION(s): High degree of confirmation for conazoles by accurate mass measurements demonstrated that Q-TOF-MS analysis combined with a QuEChERS method may be applicable to simultaneous determination of conazoles in garlic samples.