• Bulletin of the Korean Chemical Society
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• v.19 no.12
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• pp.1351-1355
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• 1998

A simple apparatus for adding a modifying solvent to supercritical CO2 extractant was described. Small, fixed volumes (typically 100 μL) of liquid modifying solvents were delivered during the extraction process by use of an in-line high pressure loop injector and an air pump. Without disconnecting the extraction cell from the supercritical fluid extraction system, the modifying solvent was repeatedly delivered. The solvent modification device was optimized during the extraction of carbaryl and bis(acetylacetonato) copper(Ⅱ). Extraction recoveries from spiked filter paper and soil samples ranged between 22% and 109%, depending on the analyte and matrix components. The addition of polar modifying solvents were necessary to improve the extractability of the nonpolar CO2.

• Journal of the Korean Statistical Society
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• v.15 no.1
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• pp.71-78
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• 1986

In this paper, multivariate discrete distribution is dealt with, where a set of r distinct counts are misreported as another set of r counts. First, the variance for the one variable marginal case is expressed in the form of an inverted parabola. Next, for the multivariate negative binomial case, elements of the covariance matrix are evaluated with reference to asymptotic distributions. Finally, for the same case of multivariate negative binomial, Bayesian estimates of the parameters and of the modification rates are provided.

• Transactions of the Korean Society of Mechanical Engineers
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• v.18 no.10
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• pp.2640-2652
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• 1994

The stiffness of 6-node isotropic element is stiffer than that of 8-node isotropic element of same configuration. This phenomenon was called 'Relative Stiffness Stiffening Phenomenon'. In this paper, an equation of sampling point modification which correct this phenomenon was derived for the composite plate, as well as an equation for an isotropic plate. The relative stiffness stiffening phenomena of an isotropic plate element could be corrected by modifying Gauss sampling points in the numerical integration of stiffness matrix. This technique could also be successfully applied to the static analyses of composite plate modeled by the 3-dimensional 16-node elements. We predicted theoretical errors of stiffness versus the number of layers that result from the reduction of numerical integration order. These errors coincide very well with the actual errors of stiffness. Therefore, we can choose full integration of reduced integration based upon the permissible error criterion and the number of layers by using the thoretically predicted error.

• Journal of the Institute of Convergence Signal Processing
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• v.14 no.3
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• pp.169-180
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• 2013

The modification of conditional Fuzzy C-Means (CFCM) with Gaussian weights (CFCM_GW) is accomplished for blind equalization of channels in this paper. The proposed CFCM_GW can deal with both of linear and nonlinear channels, because it searches for the optimal desired states of an unknown channel in a direct manner, which is not dependent on the type of channel structure. In the search procedure of CFCM_GW, the Bayesian likelihood fitness function, the Gaussian weighted partition matrix and the conditional constraint are exploited. Especially, in contrast to the common Euclidean distance in conventional Fuzzy C-Means(FCM), the Gaussian weighted partition matrix and the conditional constraint in the proposed CFCM_GW make it more robust to the heavy noise communication environment. The selected channel states by CFCM_GW are always close to the optimal set of a channel even when the additive white Gaussian noise (AWGN) is heavily corrupted. These given channel states are utilized as the input of the Bayesian equalizer to reconstruct transmitted symbols. The simulation studies demonstrate that the performance of the proposed method is relatively superior to those of the existing conventional FCM based approaches in terms of accuracy and speed.

• Transactions of the Korean Society of Machine Tool Engineers
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• v.13 no.2
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• pp.75-80
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• 2004

Vehicle structures are composed of many substructure connected to one another by various types of mechanical joints. In vehicle engineering it is important to study these connected structures under various dynamic forces for the evaluations of fatigue life and stress concentration exactly. It is difficult to obtain the accurate load history of specified positions because of the errors such as modeling, measurement and etc. In the beginning of design exact load data are actually necessary for the fatigue strength and life analysis to minimize the cost and time of designing. In this paper, the procedure of practical dynamic force determination is developed by the combination of the principal stresses of F. E. Analysis and experiment. Least square pseudo inverse matrix is adopted to obtain in inverse matrix of analyzed stresses matrix. The error minimization method utilizes the inaccurate measured error and the shifting error that the whole data is stiffed over real data. The least square criterion is adopted to avoid these non. Finally, to verify the proposed procedure, a bus is analyzed. This measurement and prediction technology can be extended to the structural modification of any geometric shape in complex structure.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2003.05a
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• pp.59-64
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• 2003

The parameter modification of the initial FEM model to match it with the experimental results needs the modal information and the modal sensitivity matrix to the parameter change. There are two cases this methodology is ill-equip to deal with; the deficiency of the necessary modal information and the ill-conditioning of the sensitivity matrix. In this research, a novel concept of the feedback exciter that uses the summation of the white noise and the signals from the measurement sensors multiplied with feedback gains as the reference signal is proposed. There are 2 advantages using this external feedback excitation. First, we can use the change of the system response such as modal data by the active energy Path from the sensor to the exciter. This change of the system response can be additional clues to the system dynamics that we want to know. Secondly, the external energy Path alternates the offset of the Parameter change to the system response. That means the modal sensitivity of the parameters becomes different from the original sensitivities by the feedback excitation. Through the feedback loop, we can change the similar modal sensitivities of some updating parameters and consequently discriminate the parameters using the closed-loop modal data. To demonstrate the discrimination performance, the parameter estimation of an indeterminate structure by use of the feedback method is introduced.

• Advanced Composite Materials
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• v.18 no.3
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• pp.221-232
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• 2009

The allylamine plasma treatment is used to modify the surface properties of vapor grown carbon fibers (VGCF). It is to improve the interfacial bonding between the VGCF and epoxy matrix. The allylamine plasma process was performed by batch process in a vacuum chamber, using gas injection followed by plasma discharge for the durations of 20, 40 and 60 min. The interdependence of mechanical properties on the VGCF contents, treatment time and interfacial bonding between VGCF/ep was investigated. The interfacial bonding between VGCF and epoxy matrix was observed by scanning electron microscopy (SEM) micrographs of nanocomposites fracture surfaces. The changes in the mechanical properties of VGCF/ep, such as the tensile modulus and strength were discussed. The mechanical properties of allylamine plasma treated (AAPT) VGCF/ep were compared with those of raw VGCF/ep. The tensile strength and modulus of allyamine plasma treated VGCF40 (40 min treatment)/ep demonstrated a higher value than those of other samples. The mechanical properties were increased with the allyamine plasma treatment due to the improved adhesion at VGCF/ep interface. The modification of the carbon nanofibers surface was observed by transmission electron microscopy (TEM). SEM micrographs showed an excellent dispersion of VGCF in epoxy matrix by ultrasonic method.

• Wind and Structures
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• v.16 no.5
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• pp.517-540
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• 2013

This paper presents applications of proper orthogonal decomposition in both the time and frequency domains based on both cross spectral matrix and covariance matrix branches to analyze multi-variate unsteady pressure fields on prisms and to study spanwise and chordwise pressure distribution. Furthermore, modification of proper orthogonal decomposition is applied to a rectangular spanwise coherence matrix in order to investigate the spanwise correlation and coherence of the unsteady pressure fields. The unsteady pressure fields have been directly measured in wind tunnel tests on some typical prisms with slenderness ratios B/D=1, B/D=1 with a splitter plate in the wake, and B/D=5. Significance and contribution of the first covariance mode associated with the first principal coordinates as well as those of the first spectral eigenvalue and associated spectral mode are clarified by synthesis of the unsteady pressure fields and identification of intrinsic events inside the unsteady pressure fields. Spanwise coherence of the unsteady pressure fields has been mapped the first time ever for better understanding of their intrinsic characteristics.

• Advances in materials Research
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• v.11 no.3
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• pp.191-209
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• 2022

Very slow degradation of synthetic based polymers has created a severe environmental issue that increased awareness towards research in polymers of biodegradable property. Soy protein isolate (SPI) is a natural biopolymer used as matrix in green composites but it has limitations of low mechanical properties and high water sensitivity. To enhance mechanical properties and reduce water sensitivity of Jute-SPI composites, SPI was modified with pine rosin which is also a natural cross-linking agent. 30% glycerol on the weight basis of a matrix was used as a plasticizer. The fibre volume fraction was kept constant at 0.2 whereas the pine rosin in SPI ranged from 5% to 30% of the matrix. The effects of pine rosin on mechanical, thermal, water sensitivity and surface morphology have been characterized using various techniques. The mechanical properties and water absorbency were found to be optimum for 15% pine rosin in Jute-SPI composite. Therefore, Jute-SPI composite without pine rosin and with 15% pine rosin were chosen for investigation through characterization by Fourier transforms infrared spectroscopy (FTIR), Thermo-gravimetric analysis (TGA), X-Ray diffraction (XRD) and Scanning electron microscope (SEM). The surface morphology of the composite was influenced by pine rosin which is shown in the SEM image. TGA measurement showed that the thermal properties improved due to the addition of pine rosin. Antimicrobial test showed antimicrobial property in the composite occurring 15% pine rosin. The research paper concludes that the modification of SPI resin with an optimum percentage of pine rosin enhanced mechanical, thermal as well as water-resistant properties of jute fibre reinforced composites.

• Analytical Science and Technology
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• v.5 no.4
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• pp.349-358
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• 1992

The direct determination of lead in the whole-blood by graphite furnace atomic absorption spectrometric analysis was carried out by using the sample which was diluted five-fold with 1% Triton X-100. Matrix modification was tried to remove the interferences of blood matrix and also to get the optimum analytical condition. Good agreement with certificated values in reference materials(bovine blood) supplied by comparison program in Japan was obstained when 1% $(NH_4)_2HPO_4$ as matrix modifier and ashing temperature, $700^{\circ}C$ were used or 1% $(NH_4)_2HPO_4$ and 0.1% $PdCl_2$ as matrix modifier and ashed at $700^{\circ}C$. Standard deviations were appeared as 2.2~6.3% for 1% $(NH_4)_2HPO_4$ and 3.1~9.1% for 1% $(NH_4)_2HPO_4$ and 0.1% $PdCl_2$ in the range of $31{\sim}624{\mu}gPb/l$.