• Elastomers and Composites
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• v.42 no.2
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• pp.75-85
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• 2007

In this study, the new adhesion system was studied to improve the adhesion strength between polyester cord and rubber matrix. In order to enhance the adhesion strength through polyester cord's surface treatment, the NaOH solution was used. The NaOH solution concentrations of 0.03, 0.05, 0.1, 0.2, 0.5, 1 and 5 wt.% were used in surface modifying the polyester cord. The optimum condition showing the maximum adhesion strength of polyester cord with SBR compound containing bonding agent was at NaOH concentration of 0.05 wt.% with treatment time of 10 minutes. When the NaOH solution concentration was above 1 wt.%, the polyester cord due to the excess surface modification was damaged, and resulted in breakage during the adhesion test. Also, the adhesion strength between polyester and SBR could be improved by coating the polyester cord with triallylcyanurate(TC) adhesive. The drying condition of polyester cord coated with TC attributed to the adhesion strength. The maximum adhesion strength was obtained by using the polyester cord dried at $220^{\circ}C$ rather than dried at room temperature.

• Journal of the Korean Applied Science and Technology
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• v.33 no.1
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• pp.168-175
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• 2016

The surface of glass fiber bundle was modified with functionalized silanes and phenolic resin to improve the tensile strength as well as the adhesion of glass fiber to matrix phenolic resin. The surface modification of reinforcing glass fiber can play a significant role in controlling whole composite characteristics. We applied surface modification of glass fiber with two different functionalized silanes, such as glycidyltrimethoxysilane(G-silane) and aminopropyltriethoxysilane (A-silane), and phenol formaldehyde(PF) resin in one pot or separated process under different coating compositions and temperatures. Thermal treatment temperature is very important factor to improve the mechanical properties of modified glass fiber. Modified glass fiber bundle treated at $170^{\circ}C$ showed the highest tensile strength of $10.05g_f/D$. Surface analyses by scanning electron microscope(SEM) and FT-IR spectroscopy were used to characterize the surface coatings on glass fiber bundles. Mechanical property changes as functions of treatment conditions and coupling agent types were also explained.

• Elastomers and Composites
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• v.48 no.1
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• pp.18-23
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• 2013

Nylon 12 elastomer was slightly crosslinked in molten state by the addition of small amount of dicumyl peroxide (DCP) as a crosslink agent and triallycyanuate (TAC) as a co-agent during melt compounding at $160^{\circ}C$ in an internal mixer. The effect of the peroxide crosslinking on mechanical, dynamic mechanical and rheological properties of the nylon 12 elastomer was investigated by means of tensile testing, dynamic mechanical analysis (DMA) and small amplitude oscillating rheometer, respectively. With modification, there is an improvement in tensile modulus and Young's modulus with decease in elongation at break. DMA results for peroxide modified nylon 12 elastomers demonstrated that the glass transiaiton temperature of PTMG segment shifted to higher temperature and the storage modulus remained constant above the melting temperature of nylon 12 segments. Melt rheological studies revealed that the peroxide modified nylon 12 elastomer exhibited a more solid like behavior and stronger shear thinning behavior compared to neat nylon 12 elastomer, which was more prominent at higher TAC content in the polymer matrix. The peroxide modified nylon 12 elastomer exhibited good elastic recoverability and improved mechanical properties without sacrificing melt processibilty, and especially the service temperature range increased as compared to neat nylon 12 elastomer.

• Metals and materials international
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• v.24 no.6
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• pp.1193-1201
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• 2018

Dilatometry is a useful technique to obtain experimental data concerning transformation. In this paper, a dilation conversional model was established to calculate carbides fraction in AISI H13 hot-work tool steel based on the measured length changes. After carbides precipitation, the alloy contents in the matrix changed. In the usual models, the content of carbon atoms after precipitation is considered as the only element that affects the lattice constant and the content of the alloy elements such as Cr, Mo, Mn, V are often ignored. In the model introduced in this paper, the alloying elements (Cr, Mo, Mn, V) changes caused by carbides precipitation are incorporated. The carbides were identified using scanning electron microscope and transmission electron microscope. The relationship between lattice constant of carbides and temperature are measured by high-temperature X-ray diffraction. The results indicate that the carbides observed in all specimens cooled at different rates are V-rich MC and Cr-rich $M_{23}C_6$, and most of them are V-rich MC, only very few are Cr-rich $M_{23}C_6$. The model including the effects of substitutional alloying elements shows a good improvement on carbides fraction predictions. In addition, lower cooling rate advances the carbides precipitation for AISI H13 specimens. The results between experiments and mathematical model agree well.

• Korean journal of food and cookery science
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• v.12 no.4
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• pp.571-576
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• 1996

The moisture-dependent gelation characteristics of five different proteins are evaluated to understand the modification of gel strength when they are added in surimi gel. Compressive force and penetration force of protein gels gradually decreased with increase of moisture level, with showing markedly decrease at certain point of moisture level called critical moisture level. The critical moisture level for gelation of SPI-1, SPI-2, EW, WPC and LA were 79.4%, 81.6%, 91.4％, 87,8% and 84.7%, respectively. Beyond this critical level of water, protein gel matrix begins to lose its water binding and structural integrity. The mnisture that was not re tained by a protein was available to diluting the protein matrix and eventually weakened the overall gel strength. EW and MPI showed higher water retention than those of SPI, WPC and LA. The compressive force of SPI, WPC and LA-incorporated surimi gel at the varying moisture levels strongly correlated with the amount if water retained at corresponding moisture level within those protein (r=0.99).

• Transactions on Electrical and Electronic Materials
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• v.15 no.6
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• pp.291-296
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• 2014

In recent years, researchers have extensively investigated polymers filled with inorganic nanoparticles because these materials present improved physical properties relative to those of conventional unfilled polymers. Oxides, silica in particular, are the most commonly used inorganic particles because they possess good properties and can be fabricated at a low cost. However, oxides are hydrophilic in nature, and this leads to the presence of water at the interface between the nanoparticles and the polymer matrix. Due to the predominance of particle-matrix interfaces in nanocomposites, the presence of water at the interlayer region can be problematic. Moreover, the hydrophobic nature of most polymers, particularly for polyolefins such as polyethylene, may make it difficult to remove this interfacial water. In this paper, as-received and moistened samples of agglomerated nanosilica/polyethylene were dried using an isothermal treatment at $60^{\circ}C$, and the efficacy of this treatment was studied using dielectric spectroscopy. The Maxwell-Wagner-Sillars relaxation peaks were observed to shift to lower frequencies by three decades, and this was linked to a modification of the water content, due to drying, at the interfaces between silica and polyethylene and at the interfaces within the nanosilica agglomerates. The evolution of the extracted retardation time is explained by the nanosilica hydrophily and the free volume introduced by the nanoparticles.

• Korean Chemical Engineering Research
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• v.55 no.3
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• pp.287-295
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• 2017

Using nanotechnology, magnetic nanoparticles of iron oxide were produced via co-precipitation method and followed modification with organic compounds. In the next step, functionalized monomer was provided via coupling ${\beta}$-cyclodextrine and allylamine onto modified magnetic nanoparticles. These nanoparticles were used to establish the adsorption rate of celecoxib. Magnetic nanoparticles are modified by (3-mercaptopropyl)trimethoxysilane. Nano-adsorbent was characterized by analytical and spectroscopic methods, such as Fourier transform infrared spectroscopy, elemental analysis, thermo-gravimetric analysis, and transmission electron microscopy (TEM). Laboratory parameters, such as the kinetics of adsorption isotherms, pH, reaction temperature and capacity were optimized. Finally, by using this nano-adsorbent in the optimized condition, extraction of celecoxib from biological samples as urine, drug matrix and blood plasma was carried out by high performance liquid chromatography with sensitivity and high accuracy.

• Transactions of the Korean Society of Mechanical Engineers
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• v.14 no.2
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• pp.339-348
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• 1990

Techniques which are able to predict and control dynamic characteristics, not affecting the vibrational characteristics on the modification of structural design, are being studied. As one of these techniques, experimental modal analysis is widely applied by many researchers. In this study, modal analysis is performed using transfer matrix method by a macro computer. The developed program would estimate the structural modal parameters precisely, and the validity of this program is certified by comparing with the experimental results of .GAMMA A. structure. Estimated modal parameters(natural frequency, vibrational mode, equivalent mass, etc.) are in accord with the experimental results. Also, the optimal location of the additive mass is determined by the evaluation of the vibrational mode and the equivalent mass. The relation between the additive mass and the equivalent mass is specified, and we come to know that the ratio of equivalent mass to additive mass alter linearly within the range of 20%.

• The Journal of the Korea Contents Association
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• v.11 no.1
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• pp.404-410
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• 2011

For the simulation of one-dimensional unsteady flow, the Taylor-Galerkin finite element method was adopted to the discretization of the Saint Venant equation. The model was applied to the backwater problem in a single channel and the flood routing in dendritic channel networks. The numerical solutions were compared with previously published results of finite difference and finite element methods and good agreement was observed. The model solves the continuity and the momentum equations in a sequential manner and this leads to easy implementation. Since the final system of matrix is tri-diagonal with a few additional entry due to channel junctions, the tri-diagonal matrix solution algorithm can be used with minor modification. So it is fast and economical in terms of memory for storing matrices.

• Bulletin of the Korean Chemical Society
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• v.31 no.9
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• pp.2637-2643
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• 2010

In order to develop a new line injection system for spin draw yarn (FD SDY) fibers, the effect of various parameters in extrusion and melt line conditions on the dispersion and distribution of $TiO_2$ particles within FD PET fibers was investigated. As a result, the dispersibility of $TiO_2$ particles in a PET matrix is found to depend on the particle size and its surface characteristics. Surface modification of $TiO_2$ by dimethyl polysiloxane resulted in the improved dispersibility and affinity of $TiO_2$ particles in the PET matrix. Especially, residence time, mixing temperature, and mixing shear rate in the new line injection system under the SDY spinning process were very important parameters to minimize the agglomeration of $TiO_2$ particles. The FD SDY prepared by the new line injection system was superior to those using the polymerization process and the conventional masterbatch chip dosing process in the color-L and color-b values of the fibers.