• Title/Summary/Keyword: Matrix degradation

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Half lives of Gaseous Organochlorine Pesticides in Atmosphere (대기 중에서 가스상 유기염소계 살충제의 반감기)

  • Choi, Min-Kyu;Chun, Man-Young
    • Environmental Analysis Health and Toxicology
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    • v.22 no.2 s.57
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    • pp.177-184
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    • 2007
  • Gaseous organochlorine pesticides (OCPs : heptachlor epoxide, p, p'-DDE, ${\gamma}-HCH,\;{\alpha}-chlordane,\;{\gamma}-chlordane$ and trans-nonachlor) concentration was measured using PUF high volume sampler from June, 2000 to June, 2002 in the semi-rural atmosphere. The OCPs concentration in atmosphere, which is estimated by the slope (m) of Clausius-Clapeyron equation and phase-transition energy $({\Delta}H)$, was influenced by revolatilization from environmental matrix (soil, water and tree leaves) and a long range transportation of air mass. But the former affected OCPs concentration more than the latter. The degradation rate constants (k) of OCPs calculated using multiple regression analysis and revised standard temperature method were in good agreement each other. The value of k of ${\gamma}-HCH$ was very low as -0.0007, but the range of k of other components were $-0.00l8{\sim}-0.0038$. The half-life $({\tau})$ which was calculated by k of ${\gamma}-HCH$ was 2.6 years-the longest one, but that of heptachlor epoxide was in 0.5 year-the shortest one. $({\tau})\;of\;{\alpha}-chlordane,\;{\gamma}-chlordane$ and trans-nonachlor in technical chlordane was 1.0, 1.1 and 0.7 year respectively.

An Experimental Study on NOx Degradation Efficiency and Physical Characteristics of Maximum Size 40 mm Porous Concrete (굵은골재 최대치수 40 mm 투수 콘크리트의 물리적 특성과 질소산화물 제거에 관한 연구)

  • Hong, Chong-Hyun;Kim, Moon-Hoon;Ryu, Seong-Pil;Choung, Kwang-Ok
    • Journal of Environmental Science International
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    • v.15 no.5
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    • pp.431-438
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    • 2006
  • The strength, water permeability, and photo-degradation efficiency of NOx of porous concrete with a new concept were studied in this paper. The porous concrete was comprised of coarse aggregate of maximum size 40 mm, cement, silica fume, water and air-entraining(AE) water reducing agent. The strength of porous concrete was strongly related to its matrix proportion and compaction energy. An experimental test was carried out to study the parameters of cement proportions and silica fume content for pavement applications of porous concrete which were paving a footpath, a bikeway, a parking lot, and a driveway. The regressed equations of relation-ships between compressive strength and flexural strength, and coefficient permeability and void ratios were indicated as y=7.69x+71.74 and $y=0.42e^{0.28x}$. A method of making an air purification-functioning road, which was spraying a mixture of a photocatalyst, cement, and water onto the surface of the road, was suggested.

Inter-lamina Shear Strength of MWNT-reinforced Thin-Ply CFRP under LEO Space Environment

  • Moon, Jin Bum;Kim, Chun-Gon
    • Composites Research
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    • v.30 no.1
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    • pp.7-14
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    • 2017
  • In this paper, the inter-lamina shear strength (ILSS) of multi-wall carbon nanotube (MWNT) reinforced carbon fiber reinforced plastics (CFRP) and thin-ply composites were verified under low earth orbit (LEO) space environment. CFRP, MWNT reinforced CFRP, thin-ply CFRP and MWNT reinforced thin-ply CFRP were tested after aging by using accelerated ground simulation equipment. The used ground simulation equipment can simulate high vacuum ($2.5{\times}10^{-6}torr$), atomic oxygen (AO, $9.15{\times}10^{14}atoms/cm^2{\cdot}s$), ultraviolet light (UV, 200 nm wave length) and thermal cycling ($-70{\sim}100^{\circ}C$) simultaneously. The duration of aging experiment was twenty hours, which is an equivalent duration to that of STS-4 space shuttle condition. After the aging experiment, ILSS were measured at room temperature ($27^{\circ}C$), high temperature ($100^{\circ}C$) and low temperature ($-100^{\circ}C$) to verify the effect of operation temperature. The MWNT and thin-ply shows good improvement of ILSS at ground condition especially with the thin-ply. And after LEO exposure large degradation of ILSS was observed at MWNT added composite due to the thermal cycle. And the degradation rate was much higher under the high temperature condition. But, at the low temperature condition, the ILSS was largely recovered due to the matrix toughening effect.

Anti-Photoaging Effects of Angelica acutiloba Root Ethanol Extract in Human Dermal Fibroblasts

  • Park, Min Ah;Sim, Mi Ja;Kim, Young Chul
    • Toxicological Research
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    • v.33 no.2
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    • pp.125-134
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    • 2017
  • The effects that ultraviolet rays elicit on collagen synthesis and degradation are the most common causes of wrinkle formation and photo-aging in skin. The objectives of this study were to evaluate the effects of Angelica acutiloba root ethanol extract (AAEE) to promote collagen synthesis and inhibit collagen degradation in human dermal fibroblasts. By examining total polyphenol and flavonoid contents, electron donating ability, radical scavenging activity, and superoxide dismutase-like activity, we found that AAEE exhibited fairly good antioxidant activity. Treatment with AAEE significantly increased type I procollagen production by cultured fibroblasts, as well as reduced ultraviolet-induced matrix metalloproteinase-1 (MMP-1) expression and MMP-2 activity in a dose-dependent manner (p < 0.05). In addition, AAEE significantly increased TIMP-1 mRNA expression (p < 0.05), although without an associated dose-dependent increase in TIMP-1 protein expression. In summary, we suggest that AAEE may be a potentially effective agent for the prevention or alleviation of skin-wrinkle formation induced by ultraviolet rays.

Seismic Analysis of Flat Slab Structures considering Stiffness Degradation (강성저감을 고려한 플랫슬래브 구조물의 지진해석)

  • 김현수;이승재;이동근
    • Proceedings of the Earthquake Engineering Society of Korea Conference
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    • 2003.09a
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    • pp.191-198
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    • 2003
  • Flat slab system has been adopted in many buildings constructed recently because of the advantage of reduced floor heights to meet the economical and architectural demands. Structural engineers commonly use the equivalent frame method(EFM) with equivalent beams proposed by Jacob S. Grossman in practical engineering for the analysis of flat slab structures. However, in many cases, when it is difficult to use the EFM, it is necessary to use a refined finite element model for an accurate analysis. But it would take significant amount of computational time and memory if the entire building structure were subdivided into a finer mesh. An efficient analytical method is proposed in this study to obtain accurate results in significantly reduced computational time. The proposed method employs super elements developed using the matrix condensation technique and fictitious beams are used in the development of super elements to enforce the compatibility at the interfaces of super elements. The stiffness degradation of flat slab system considered in the EFM was taken into account by reducing the elastic modulus of floor slabs in this study. Static and dynamic analyses of example structures were peformed and the efficiency and accuracy of the proposed method were verified by comparing the results with those of the refined finite element model and the EFM.

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THE AGING EFFECT Of K3B/IM7 IN $80^{\circ}C$ WATER

  • Kim Hyungwon
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • v.y2005m4
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    • pp.31-34
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    • 2005
  • Hygrothermal aging of the laminates of $Avimid^{R}$ K3B/IM7 in $80^{\circ}C$ water was studied as a function of immersion time prior to forming microcracks. The factors causing the $80^{\circ}C$ water to degradation of the laminates could be the degradation of the matrix toughness, change in residual stresses or interfacial damage between the fiber and matrix. The times to saturation in $80^{\circ}C$ water for the laminates and the neat resin are 100 hours and 500 hours. After 500 hours aging of the neat resin in $80^{\circ}C$ water, the glass transition temperature was changed less than $1\%$ by DSC test and the weight gain was $1.55\%$ increase. After 500 hours aging, the fracture toughness of the neat resin was decreased about $37\%$ by 3-point bending test. After 100 hours aging of the [+45/0/-45/90]s K3B/IM7 laminates in $80^{\circ}C$ water, the weight gain was $0.41\%$ increase. The $80^{\circ}C$ water diffusion rate into the neat resin was faster than into the laminates. In 100 hours, the loss of the microcracking toughness of the laminates was $28\%$ of the original toughness by our own microcracking fracture toughness criterion.

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Anti-osteoarthritis effect of Boswellia serrata gum resin extract in monosodium iodoacetate-induced osteoarthritic Sprague-Dawley rats (Monosodium iodoacetate 유도 골관절염 동물모델에서 보스웰리아 검레진 추출물의 항골관절염 효과 연구)

  • Jae In Jung;Ryong Kim;Eun Ji Kim
    • Journal of Nutrition and Health
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    • v.56 no.3
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    • pp.231-246
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    • 2023
  • Purpose: The aim of this study was to investigate the anti-osteoarthritic effect of the ethanol extract of Boswellia serrata gum resin (FJH-UBS) enriched with keto-β-boswellic acid and 3-O-acetyl-11-keto-β-boswellic acid compared to the conventional Boswellia serrata extract by adding the process of removing oil with hexane, in the monosodium iodoacetate (MIA)-induced osteoarthritis rat model. Methods: Sprague-Dawley (SD) rats were orally administered 0, 40, or 80 mg of FJH-UBS/kg body weight (BW)/day for 5 weeks and injected with MIA intra-articularly into right knee joints on day 15 to induce osteoarthritis. Changes in the knee joint microarchitecture, cartilage degradation, the expression of inflammatory mediators, cytokines, and matrix metalloproteinases (MMPs) in serum and synovia were observed. Results: Oral administration of FJH-UBS (80 mg/kg BW/day) reduced MIA-induced knee swelling and cartilage degradation and increased the expression of type II collagen and aggrecan in articular cartilage. Furthermore, FJH-UBS administration reduced MIA-induced increases in the serum levels of prostaglandin E2, leukotriene B4, interleukin (IL)-1β, IL-6, and MMP-13, and MIA-induced increases in the mRNA expressions of inducible nitric oxide synthase, cyclooxygenase-2, 5-lipoxygenase, IL-1β, IL-6, TNF-α, MMP-2, MMP-9, and MMP-13 in the synovia of knee joints. Conclusion: These results indicate that FJH-UBS exerts its anti-osteoarthritic effects by suppressing the expressions of inflammatory cytokines and MMPs and, thus, cartilage degradation. Furthermore, they suggest that FJH-UBS has potential use as a functional food that improves joint and cartilage health.

Matrix Decomposition for Low Computational Complexity in Orthogonal Precoding of N-continuous Schemes for Sidelobe Suppression of OFDM Signals

  • Kawasaki, Hikaru;Matsui, Takahiro;Ohta, Masaya;Yamashita, Katsumi
    • IEIE Transactions on Smart Processing and Computing
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    • v.6 no.2
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    • pp.117-123
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    • 2017
  • N-continuous orthogonal frequency division multiplexing (OFDM) is a precoding method for sidelobe suppression of OFDM signals and seamlessly connects OFDM symbols up to the high-order derivative for sidelobe suppression, which is suitable for suppressing out-of-band radiation. However, it severely degrades the error rate as it increases the continuous derivative order. Two schemes for orthogonal precoding of N-continuous OFDM have been proposed to achieve an ideal error rate while maintaining sidelobe suppression performance; however, the large size of the precoder matrices in both schemes causes very high computational complexity for precoding and decoding. This paper proposes matrix decomposition of precoder matrices with a large size in the orthogonal precoding schemes in order to reduce computational complexity. Numerical experiments show that the proposed method can drastically reduce computational complexity without any performance degradation.

Fracture Behavior for Carbon Fiber Reinforced Plastic by Immersion (흡수에 따른 탄소섬유 강화수지의 파괴거동)

  • Kim, O. G.;Nam, K. W.;Ahn, B. H.
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.32 no.4
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    • pp.402-410
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    • 1996
  • Recently carbon fiber reinforced plastic(CFRP) has been used structural materials in corrosive environment such as for water, chemical tank and chemical pipes. However, mechanical properties of such materials may change when CFRP are exposed to corrosive environment for long periods of time. Therefore, it is important to understand the effect of moisture absorption on mechanical properties of the CFRP. In this study, degradation behavior of immersed carbon fiber/epoxy resin composite material was investigated using acoustic emission(AE) technique. Fracture toughness test are performed on the compact tension(CT) test specimens that are pilled by two types of laminates $[0^{\circ}_2$/$90^{\circ}_2]_3s$ and $[0^{\circ}_2$/$90^{\circ}_2]_6s$During the fracture toughness test, AE test was carried out to monitor the damage of CFRP by moisture absorption. In spite of the change of moisture absorption rate, the fracture toughness of CFRP was not change. As immersion time increased, AE event count numbers decreased in low amplitude range of AE for amplitude distribution histogram. The event in low amplitude range was known to be generated by debonding of matrix-fiber interface. Therefore, decrease of AE event count numbers in low amplitude range represents that debonding of matrix-fiber interface which was probably generated by moisture absorption.

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Subspace-Based Adaptive Beamforming with Off-Diagonal Elements (비 대각요소를 이용한 부공간에서의 적응 빔 형성 기법)

  • Choi Yang-Ho;Eom Jae-Hyuck
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.29 no.1A
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    • pp.84-92
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    • 2004
  • Eigenstructure-based adaptive beamfoming has advantages of fast convergence and the insentivity to errors in the arrival angle of the desired signal. Eigen-decomposing the sample matrix to extract a basis for the Sl (signal plus interference) subspace, however, is very computationally expensive. In this paper, we present a simple subspace based beamforming which utilizes off-diagonal elements of the sample matrix to estimate the Sl subspace. The outputs of overlapped subarrays are combined to produce the final adaptive output, which improves SINR (signal-to-interference-plus-noise ratio) comapred to exploiting a single subarray. The proposed adaptive beamformer, which employs an efficient angle estimation is very roubust to errors in both the arrival angles and the number of the incident signals, while the eigenstructure-based beamforer suffers from severe performance degradation.