• Title/Summary/Keyword: Matrix addition

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Effect of Alloying Elements on Particulate Dispersion Behavior and Mechanical Properties in TiC Particulate Reinforced Magnesium Matrix Composites (TiC 입자강화 Mg 복합재료에 있어서 입자 분산거동 및 기계적 성질에 미치는 합금원소의 영향)

  • Lim, Suk-Won;Choh, Takao;Park, Yong-Jin
    • Journal of Korea Foundry Society
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    • v.14 no.3
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    • pp.240-247
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    • 1994
  • TiC particulate reinforced magnesium matrix composites were fabricated by melt stirring method. The effect of alloying elements on TiC particulate dispersion into molten magnesium and mechanical properties were investigated. The incorporation time is defined as the time required for dispersion of solid particles into molten metal. The incorporation time of TiC particles into molten pure magnesium was remarkably shorter and the particulated dispersion was more uniform than that of pure aluminum which was reported previously. The incorporation time was, prolonged by the addition of Al, Bi, Ca, Ce, Pb, Sn or Zn. The tensile strength increased and elongation decreased by the addition of Cu or Sn into the matrices and composites. Although, the tensile strength of the matrices and composites increased by alloying with Ca or Ce, the maximum elongation was observed at a content of about 1% for the matrices. By alloying with Zn, the tensile strength increased for the matrices and composites, but the elongation of the matrices increased. The pure magnesium and its alloy matrix composites reinforced with 20vol% TiC have the tensile strength of about 400MPa. This value is compared with the tensile strength of SiC whisker reinforced magnesium matrix composites fabricated by liquid infiltration method at the same volume fraction. There fore, the melt strirring method which has the advantages of simple process is considered to be efficient in fabricating magnesium matrix composites.

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The Thermal Stability and Elevated Temperature Mechanical Properties of Spray-Deposited $SiC_P$/Al-11.7Fe-1.3V-1.7Si Composite

  • Hao, L.;He, Y.Q.;Wang, Na;Chen, Z.H.;Chen, Z.G.;Yan, H.G.;Xu, Z.K.
    • Advanced Composite Materials
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    • v.18 no.4
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    • pp.351-364
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    • 2009
  • The thermal stability and elevated temperature mechanical properties of $SiC_P$/Al-11.7Fe-1.3V-1.7Si (Al-11.7Fe-1.3V-1.7Si reinforced with SiC particulates) composites sheets prepared by spray deposition (SD) $\rightarrow$ hot pressing $\rightarrow$ rolling process were investigated. The experimental results showed that the composite possessed high ${\sigma}_b$ (elevated temperature tensile strength), for instance, ${\sigma}_b$ was 315.8 MPa, which was tested at $315^{\circ}C$, meanwhile the figure was 232.6 MPa tested at $400^{\circ}C$, and the elongations were 2.5% and 1.4%, respectively. Furthermore, the composite sheets exhibited excellent thermal stability: the hardness showed no significant decline after annealing at $550^{\circ}C$ for 200 h or at $600^{\circ}C$ for 10 h. The good elevated temperature mechanical properties and excellent thermal stability should mainly be attributed to the formation of spherical ${\alpha}-Al_{12}(Fe,\;V)_3Si$ dispersed phase particulates in the aluminum matrix. Furthermore, the addition of SiC particles into the alloy is another important factor, which the following properties are responsible for. The resultant Si of the reaction between Al matrix and SiC particles diffused into Al matrix can stabilize ${\alpha}-Al_{12}(Fe,\;V)_3Si$ dispersed phase; in addition, the interface (Si layer) improved the wettability of Al/$SiC_P$, hence, elevated the bonding between them. Furthermore, the fine $Al_4C_3$ phase also strengthened the matrix as a dispersion-strengthened phase. Meanwhile, load is transferred from Al matrix to SiC particles, which increased the cooling rate of the melt droplets and improved the solution strengthening and dispersion strengthening.

Preparation and Sound Insulation Properties of Thermoplastic Elastomer Composites with CaCO3 Filler (탄산칼슘 분말을 충진시킨 열가소성 탄성체 복합재의 제조 및 차음 특성)

  • Choi, Jung-Woo;Hwang, Yeon
    • Korean Journal of Materials Research
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    • v.20 no.9
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    • pp.467-471
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    • 2010
  • Composites of ceramic powders and an elastomer-based matrix were prepared by mixing $CaCO_3$ powders with polyethylene and polypropylene elastomers, and their mechanical and sound insulation properties were measured. $CaCO_3$ powders with 0.7 ${\mu}m$ and 35 ${\mu}m$ particle size were added to elastomers up to 80 wt%. Scanning electron microscopy photographs showed uniform distribution of the $CaCO_3$ powders in the matrix. While density and surface hardness increased, melt index, tensile strength and elongation of the composites decreased as the amount of added $CaCO_3$ powders increased. As more $CaCO_3$ powders were added sound transmission loss of the composites increased owing to the increase of density. Addition of 0.7 ${\mu}m$ sized $CaCO_3$ powders resulted in a slightly higher transmission loss than the addition of 35 ${\mu}m$ sized powders because of the increased interface area between the elastomer matrix and the $CaCO_3$ powders. Composites with a polyethylene matrix showed higher transmission loss than those with a polypropylene matrix because the tensile strength and hardness of the polyethylene-based composites were low and their elongation was high.

Heat and Wear Resistance Characterization of SiCp Reinforced Al Matrix Composites (SiCp입자강화 Al 복합재료의 내열 및 마모특성)

  • Kim, Sug-Won;Kim, Wan-Ki;Woo, Kee-Do;Ahn, Haeng-Keun
    • Journal of Korea Foundry Society
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    • v.20 no.6
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    • pp.377-385
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    • 2000
  • Al matrix composites as the most promising MMCs can be expected to be excellent engineering materials in the nearest future. So as to improve material properties of composite, many manufacturing processes have been developed. Among them, squeeze casting process which offers fine microstructure and near-net-shape is one of the most successful MMCs manufacturing processes. But, in case of with subsieve size particles (under 44 ${\mu}m$), it is very difficult to homogeneously distribute particles in matrix of Al matrix composite by various casting processes, including squeeze casting used so far. Duplex process which was developed in previous study was used to distribute the particle of subsieve size more homogeneously in matrix of Al matrix composite. Microstructures, wear and heat resistance characterization of Al-Si-Cu-Mg-(Ni)/SiCp manufactured by duplex process were examined to clarify the effect of manufacturing conditions, particle size of reinforcement and alloying elements. Al matrix composites reinforced with SiCp(10 ${\mu}m$) have the lowest wear amount among composites reinforced with 3 ${\mu}m$, 5 ${\mu}m$ and 10 ${\mu}m$ SiCp. The wear amount of Al matrix composites with 10 wt.% SiCp(3, 5, 10 ${\mu}m$) was decreased according to the increase of the sliding speed because abrasive wear takes place at high sliding speed of 4m/s and worn debris with block type occurs at low sliding speed of 1m/s. As for heat resistance, it is made clear that remarkable heat resistance property can be obtained by addition of Ni element in Al matrix composites.

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The Effect of Multi-walled Carbon Nanotubes on the Molecular Orientation of Poly(vinyl alcohol) in Drawn Composite Films

  • Wang, Xiao;Park, Soo-Young;Yoon, Kwan-Han;Lyoo, Won-Seok;Min, Byung-Gil
    • Fibers and Polymers
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    • v.7 no.4
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    • pp.323-327
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    • 2006
  • Poly(vinyl alcohol) (PVA)/multi-walled carbon nanotube (MWNT) composite films were prepared by casting a DMSO solution of PVA and MWNTs, whereby the MWNTs were dispersed by sonication. A significant improvement in the mechanical properties of the PVA drawn films was achieved by the addition of a small amount of MWNTs. The initial modulus and the tensile strength of the PVA drawn film increased by 30 % and 45 %, respectively, with the addition of 1 wt% MWNTs, which are close to those calculated from the rule of mixtures, and were strongly dependent upon the orientation of the PVA matrix. The mechanical properties, however, were not improved with a further increase in the MWNT content. The orientation of MWNTs in the composite was not well developed compared to that of the PVA matrix. This result suggests that the improvement of the molecular orientation of the PVA matrix plays a major role in the increase of the mechanical propeties of the drawn PVA/MWNT composite films.

Fabrication and Mechanical Properties of Cordierite/$ZrO_2$ Composites by Pressureless Sintering

  • Enhai Sun;Choa, Yong-Ho;Tohru Sekino;Koichi Niihara
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 2000.06a
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    • pp.233-242
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    • 2000
  • Cordierite/ZrO$_2$ composites with 5 to 25wt% ZrO$_2$ were fabricated by prssureless sintering, and their densification behavior, fracture strength, fracture toughness, microstructure and thermal expansion behavior were studied. The ZrO$_2$ addition into cordierite matrix affects the densification behavior and mechanical properties of the composites. By dispersing 25wt% ZrO$_2$, densified cordierite/ZrO$_2$ composite with a relative density of 98.5% was obtained at optimum sintering condition of 144$0^{\circ}C$/2H. Both fracture strength and toughness were increased from 140 to 290MPa and from 1.6 to 3.5 MPam$\frac{1}{2}$, respectively, by dispersing 25wt% ZrO$_2$ into the cordierite matrix. ZrO$_2$ particles were homogenously dispersed into cordierite matrix, which intragranular particles were fine(<100nm) and intergranular particles were coarse. The toughening mechanisms in the present composites were mainly attributed to martensitic transformation toughening. Then, the addition of ZrO$_2$ is likely to have little deleterious effect upon thermal expansion coefficient of cordierite.

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Modification of Hydroxyapatite-gelatin Nanocomposite using Side Group Reaction of Ca2+-RCOO-

  • Chang, Myung-Chul;Yang, Hae-Kwon
    • Journal of the Korean Ceramic Society
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    • v.49 no.1
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    • pp.72-77
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    • 2012
  • In the preparation of a hydroxyapatite [HAp]/gelatin [GEL] nanocomposite, the GEL matrix in aqueous solution of $H_3PO_4$ was modified by the introduction of aspartic acid [Asp], asparagine [Asn], and glycine [Gly]. The addition of Asp, Asn and Gly greatly affected the slurry formation of HAp/GEL nanocomposite and the resulting dry body showed variations in toughness with the addition of the different amino acids. The introduction of Asn into HAp/GEL nanocomposite was effective for producing the organic-inorganic interaction between HAp and GEL, and caused the increase of toughness. The formation reaction of the modified HAP/GEL nanocomposites was investigated by using XRD and FT-IR. The organic-organic interaction between the GEL matrix and the additives of Asp, Asn and Gly was confirmed from FT-IR analysis, and the organic-inorganic interaction between HAp nanocrystallites and the modified GEL matrix was also discussed, using FT-IR spectra patterns. Nanocrystallites of HAp were covalently bound with the GEL macromolecules and differently influenced by the modification species of Asp, Asn, and Gly.

Plastic behavior of circular discs with temperature-dependent properties containing an elastic inclusion

  • Zarandi, Somayeh Bagherinejad;Wang, Yun-Che;Novozhilova, Olga V.
    • Structural Engineering and Mechanics
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    • v.58 no.4
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    • pp.731-743
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    • 2016
  • Plastic behaviors, based on the von Mises yield criterion, of circular discs containing a purely elastic, circular inclusion under uniform temperature loading are studied with the finite element analysis. Temperature-dependent mechanical properties are considered for the matrix material only. In addition to analyzing the plane stress and plane strain disc, a 3D thin disc and cylinder are also analyzed to compare the plane problems. We determined the elastic irreversible temperature and global plastic collapse temperature by the finite element calculations for the plane and 3D problem. In addition to the global plastic collapse, for the elastically hard case, the plane stress problem and 3D thin disc may exhibit a local plastic collapse, i.e. significant pile up along the thickness direction, near the inclusion-matrix interface. The pileup cannot be correctly modeled by the plane stress analysis. Furthermore, due to numerical difficulties originated from large deformation, only the lower bound of global plastic collapse temperature of the plane stress problem can be identified. Without considerations of temperature-dependent mechanical properties, the von Mises stress in the matrix would be largely overestimated.

Double Line Voltage Synthesis Strategy for Three-to-Five Phase Direct Matrix Converters

  • Wang, Rutian;Zhao, Yanfeng;Mu, Xingjun;Wang, Weiquan
    • Journal of Power Electronics
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    • v.18 no.1
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    • pp.81-91
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    • 2018
  • This paper proposes a double line voltage synthesis (DLVS) strategy for three-to-five phase direct matrix converters. In the proposed strategy, the input and expected output voltages are divided into 6 segments and 10 segments, respectively. In addition, in order to obtain the maximum voltage transfer ratio (VTR), the input line voltages and "source key" should be selected reasonably according to different combinations of input and output segments. Then, the corresponding duty ratios are calculated to determine the switch sequences in different segment combinations. The output voltages and currents are still sinusoidal and symmetrical with little lower order harmonics under unbalanced or distorted input voltages by using this strategy. In addition, the common mode voltage (CMV) can be suppressed by rearranging some of the switching states. This strategy is analyzed and studied by a simulation model established in MATLAB/Simulink and an experimental platform, which is controlled by a DSP and FPGA. Simulation and experimental results verify the feasibility and validity of the proposed DLVS strategy.

12-Oxoeicosatetraenoic acid, a candidate signal for placenta separation, activates matrix metalloproteinase and induces apoptosis in bovine trophoblast cells

  • Hachiro Kamada
    • Animal Bioscience
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    • v.36 no.3
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    • pp.429-440
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    • 2023
  • Objective: 12-oxo-5Z,8Z,10E,14Z-eicosatetraenoic acid (12-KETE), a metabolite of arachidonic acid, is a strong candidate signal for placenta separation following calf discharge at delivery. In the present study, the effects of 12-KETE on bovine trophoblast cells were investigated to determine its function in the placentome at delivery. Methods: Bovine trophoblast cells derived from blastocysts were used. They were cocultured with or without fibroblasts derived from bovine placentome and/or bovine uterine epithelial cells. 12-KETE was added to the culture medium. Results: Bovine trophoblast cells contained binucleate cells and strongly expressed caudal type homeobox 2 (CDX-2) genes. Addition of 12-KETE to the trophoblast cell colony without feeder cells or that on a fibroblast monolayer induced rapid exfoliation of the colony. After 12-KETE addition, trophoblast cells emitted strong fluorescence caused by the degradation of dye-quenched collagen, indicating that 12-KETE activated matrix metalloproteinase of the trophoblast cells. Exfoliated cell colonies were stained with YOPRO-1, but not propidium iodide (PI). Moreover, DNA fragmentation and Bcl-2 associated X protein (Bax) gene (apoptosis stimulator) upregulation were observed in exfoliated cells, indicating that 12- KETE induced trophoblast cell apoptosis. These results were consistent with previous in vivo observations; however, even a lower concentration of 12-KETE activated trophoblast protease. Meanwhile, fibroblasts derived from the bovine placentome converted arachidonic acid to 12-KETE. Conclusion: These observations indicate that 12-KETE may serve as a signal for placenta separation at delivery.