• Elastomers and Composites
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• v.48 no.2
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• pp.161-166
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• 2013

Thermal degradation behavior of chlorine cure-site ACM and carboxylic cure-site ACM rubbers was studied by non-isothermal TGA thermal analysis. Carboxylic cure-site ACM rubber exhibited comparatively more thermally stable than chlorine cure-site ACM, showing higher peak temperature, at which maximum reaction rate occurred. Activation energies from Kissinger method were calculated as 118.6 kJ/mol for the chlorine cure-site ACM and 105.5 kJ/mol for the carboxylic cure-site ACM, showing similar values from Flynn-Wall-Ozawa analysis over the conversion range of 0.1~0.2. From the analysis of the reaction order change, both samples seemed thermally decomposed through the multiple reaction mechanism as is the common rubber materials.

• Journal of Microbiology and Biotechnology
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• v.10 no.6
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• pp.759-763
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• 2000

Cell-free culture broth of Phanerochaete chrysosporium has been adopted to biologically degrade 2,4,5-trichlorophenol. Two different medium compositions of nitrogen-sufficient and nitrogen-limited were compared for their distribution of isozymes, activity of lignin peroxidase, and production of oxalate. The two different culture broths were tested for their ability to degrade 2,4,5-trichlorophenol, and the biodegradation efficiency was estimated in terms of the disappearance of 2,4,5-trichlorophenol. The degradation efficiency for the nitrogen-limited culture broth was higher than that of the nitrogen-sufficient culture broth, since the nitrogen-limited culture broth induced lignin peroxidases (LiPs) and manganese peroxidases (MnPs), and contained sufficient oxalate for producing necessary radicals. Finally, the possible mechanism of 2,4,5-CP degradation using the nitrogen-limited culture broth was proposed.

• Composites Research
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• v.21 no.2
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• pp.8-14
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• 2008

Decrease of strength in composite material is generally caused by water absorption. It makes fracture of material, and loss of money or human lives. The objective of this study is to investigate the causes of decrease in strength by water absorption. Mechanism of water absorption was supposed as three steps. This mechanism is consisted of absorption into resin, absorption between resin and surface treatment agent, and delamination between fiber and resin. Conditions of test were supplied differently; kinds of fiber and resin, immersion time etc. Both of reversible reaction and irreversible reaction occurred simultaneously. Most of decrease in strength was finished at 2.5% water absorption, and the strength was recovered. At 4% water absorption, most of decrease was caused by irreversible reaction, therefore, there was a tendency not to be recovered in strength.

• Composites Research
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• v.17 no.1
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• pp.47-54
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• 2004

Vacuum hot pressing has been used for the development of titanium metal matrix composites using foil-fiber-foil technique. Subsequent micro-mechanical characteristics of the composites are then investigated by means of several experimental methods. The levels of consolidation, together with mechanism based failure processes of the materials have been analyzed by employing a thermo-acoustic emission technique. As shown by the results, fiber strength degradation occurs during the consolidation, and particularly residual stresses results from the thermal expansion mismatch between fiber and matrix materials during cooling process are incorporated in the changes of mechanical properties of the finished products. In industrial applications, both qualitative and quantitative evaluations of the material-mechanical characteristics are particularly important, and therefore must be included in process development. The present paper represents a methodology by which this can be achieved.

• Proceedings of the Korea Concrete Institute Conference
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• 2004.05a
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• pp.636-639
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• 2004

Reinforced concrete structures have been used for a long time. However, corrosion problem in reinforcing steel is inevitable, which results in the degradation of performance and the shortening of the life of structures. To overcome such problems, FRP(Fiber Reinforced Polymer) rebars have been developed. Due to their corrosion resistance and their superior mechanical properties, FRP rebars are increasingly applied to concrete structures in other countries. To obtain the composite action between FRP rebars and concrete, sufficient bond between two materials must be secured. But, the behavior of FRP rebars is different from that of steel rebars. Therefore, it is necessary to understand and develop the proper bond mechanism of FRP rebars to use them in concrete structures. This paper presents analytical results to investigate the bond-slip relationship between FRP rebars and concrete based on pull out tests.

• Computers and Concrete
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• v.19 no.2
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• pp.161-169
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• 2017

Chloride induced reinforcement corrosion is widely accepted to be the most frequent mechanism causing premature degradation of reinforced concrete structures. The electrochemical impedance of reinforcing steel in diatomite- and zeolite-containing concrete exposed to sodium chloride was assessed. Chemical, physical and mineralogical properties of three concrete samples (20% diatomite, 20% zeolite, and a reference containing neither) were correlated with corrosion investigations. The steel-reinforced samples were exposed to 3.5% NaCl solution for 500 days, and measured every 15 days via EIS method. Results indicated that porosity and capillary spaces increase the diffusion rate of water and electrolytes throughout the concrete, making it more susceptible to cracking. Reinforcement in the reference concrete was the most corroded compare to the zeolite and the diatomite samples.

• Corrosion Science and Technology
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• v.20 no.1
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• pp.22-25
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• 2021

In the past, Alloy 600 nickel-based alloys have been widely used in steam generators. However, most of them have been replaced by thermally treated alloy 690 tubes in recent years because mill annealed alloy 600 materials are known to be susceptible to stress corrosion cracking. Unlike this general perception, some steam generators using mill annealed alloy 600 tubes show excellent performance even though they are designed, manufactured, and operated in the same way. Therefore, various analyses were carried out to determine causes for the degradation of steam generators. Based on the general stress corrosion cracking mechanism, tube material susceptibility, residual stress, and sludge deposits of steam generators were compared to identify factors affecting stress corrosion cracking. It was found that mill annealed alloy 600 steam generator tubes showed higher resistance to stress corrosion cracking when the amount of sludge deposits on tube surface was smaller and residual stress generated during the fabrication was lower.

• Korean Journal of Metals and Materials
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• v.47 no.10
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• pp.675-680
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• 2009

Effects of $85^{\circ}C/85%$ Temperature/Humidity (T/H) treatment conditions on the peel strength of an electroless-plated Ni/polyimide system were investigated from a $180^{\circ}$ peel test. Peel strength between electroless-plated Ni and polyimide monotonically decreased from $37.4{\pm}5.6g/mm$ to $22.0{\pm}2.7g/mm$ for variation of T/H treatment time from 0 to 1000 hrs. The interfacial bonding mechanism between Ni and polyimide appears to be closely related to Ni-O bonding at the Ni/polyimide interface. The decrease in peel strength due to T/H treatment appears to be related to polyimide degradation due to moisture penetration through the interface and the bulk polyimide itself.

• Earthquakes and Structures
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• v.14 no.3
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• pp.261-271
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• 2018

Fiber reinforced cementitious composites (FRCC) materials that exhibit strain-hardening and multiple cracking properties under tension were recently developed as innovative building materials for construction. This study aims at exploring the use of FRCC on the seismic performance of coupling beams with conventional reinforcement. Experimental tests were conducted on seven FRCC precast coupling beams with small span-to-depth ratios and one ordinary concrete coupling beam for comparison. The crack and failure modes of the specimens under the low cycle reversed loading were observed, and the hysteretic characteristics, deformation capacity, energy dissipation capacity and stiffness degradation were also investigated. The results show that the FRCC coupling beams have good ductility and energy dissipation capacities compared with the ordinary concrete coupling beam. As the confinement stirrups and span-to-depth ratio increase, the deformation capacity and energy dissipation capacity of coupling beams can be improved significantly. Finally, based on the experimental analysis and shear mechanism, a formula for the shear capacity of the coupling beams with small span-to-depth ratios was also presented, and the calculated results agreed well with the experimental results.

• Journal of the Korean Ceramic Society
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• v.45 no.11
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• pp.688-693
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• 2008

This paper presents a study on the photocatalytic reaction about the composite particles of $TiO_2$-coated phosphors under visible light irradiation. Nanocrystalline titanium dioxide layers were directly coated on the alkaline earth aluminate phosphor, $CaAl_2O_4:Eu^{2+},\;Nd^{3+}$ particles by an sol-gel processing method. The photocatalytic reaction was analyzed with the degradation of methylene blue (MB) aqueous solution under UV and visible light irradiations. $TiO_2$-coated phosphor powders showed different photocatalytic mechanism, compared with pure $TiO_2$ (P-25, Degussa). Under UV-irradiation, $TiO_2$-coated phosphor powders showed slow photocatalytic reactivity in the early stage and fast in the latter, compared with that of pure $TiO_2$. However, $TiO_2$-coated phosphor powders showed much faster photocatalytic reactivity than that of pure $TiO_2$ under visible irradiation. In addition, the characterizations of the $TiO_2$-coated phosphor powders were conducted by a X-ray diffractometer (XRD), transmission electron microscope (TEM), and energy dispersive spectroscopy (EDS).