• KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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• v.8 no.2
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• pp.49-59
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• 2002

The main function of plastic materials in food packaging is to preserve a food for safe transportation and storage. The interactions between food and plastic materials in food packaging have become increasingly important for food quality and safety because monomer, low molecular weight components, or additives of plastic packaging materials can migrate into a food. The use of antioxidants in plastic materials can help protect the degradation of film itself and retard the oxidation of a packaged food containing lipid, through the migration of antioxidant from the packaging to a product via an evaporation / sorption mechanism. Nowadays, antioxidant (BHT) impregnated plastic materials are used for commercial food packaging application with the intention of achieving an extended shelf life of food in USA. Alpha tocopherol, as one of the most important free radical scavengers, has been well known in biological systems. Moreover, the potential use of alpha tocopherol as an additive for polymers used in the packaging industry may offer the most positive perception from both consumers and manufacturers. Alpha tocopherol has been used as an antioxidant for polyolefin resins fabricated to both bottles and film and has applications in the food packaging industry as a replacement for BHT. Today, alpha tocopherol offers an attractive choice for use as an antioxidant in polymers. This paper provides an overview of antioxidant effectiveness and applications for its use by the food packaging industry based on the evaporation-sorption mechanism of a packaging model product, where quality is associated with lipid oxidation. Important analytical techniques for predicting antioxidant interaction between the package system and product are discussed.

• Progress in Superconductivity and Cryogenics
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• v.17 no.3
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• pp.13-17
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• 2015

In superconducting coil applications particularly in wet wound coils, coated conductor (CC) tapes are subjected to different type of stresses. These include hoop stress acting along the length of the CC tape and the Lorentz force acting perpendicular to the CC tape's surface. Since the latter is commonly associated with delamination problem of multi-layered CC tapes, more understanding and attention on the delamination phenomena induced in the case of coil applications are needed. Difference on the coefficient of thermal expansion (CTE) of each constituent layer of the CC tape, the bobbin, and the impregnating materials is the main causes of delamination in CC tapes when subjected to thermal cycling. The CC tape might also experience cyclic loading due to the energizing scheme (on - off) during operation. In the design of degradation-free superconducting coils, therefore, characterization of the delamination behaviors including mechanism and strength in REBCO CC tapes becomes critical. In this study, transverse tensile tests were conducted under different loading conditions using different size of upper anvils on the GdBCO CC tapes. The mechanical and electromechanical delamination strength behaviors of the CC tapes under transverse tensile loading were examined and a two-parameter Weibull distribution analysis was conducted in statistical aspects. As a result, the CC tape showed similar range of mechanical delamination strength regardless of cross-head speed adopted. On the other hand, cyclic loading might have affected the CC tape in both upper anvil sizes adopted.

• Journal of Electrochemical Science and Technology
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• v.14 no.4
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• pp.361-368
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• 2023

In lithium-sulfur (Li-S) batteries, encapsulation of sulfur in activated carbon (AC) materials is a promising strategy for preventing the dissolution of lithium polysulfide into electrolytes and enhancing cycle life, because instead of solid-liquid-solid reactions, quasi-solid-state (QSS) reactions occur in the AC micropores. While a high weight fraction of sulfur in S/AC composites is essential for achieving a high energy density of Li-S cells, the deterioration mechanisms under such conditions are still unclear. In this study, we report the deterioration mechanisms during charge-discharge cycling when the discharge products overflow from the AC. Analysis using scanning electron microscopy and energy-dispersive X-ray spectrometry confirms that the sulfur in the S/AC composites migrates outside the AC as cycling progresses, and it is barely present in the AC after 20 cycles, which corresponds to the capacity decay of the cell. Impedance analysis clearly shows that the electrical resistance of the S/AC composite and the charge-transfer resistance of QSS reactions significantly increase as a result of sulfur migration. On the other hand, the charge-discharge cycling performance under limited-capacity conditions, where the discharge products are encapsulated inside the AC, is extremely stable. These results reveal the degradation mechanism of a Li-S cell with micro-porous carbon and provide crucial insights into the design of a S/AC composite cathode and its operating conditions needed to achieve stable cycling performance.

• Journal of Ginseng Research
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• v.48 no.1
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• pp.40-51
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• 2024

Background: Ginsenoside 20(S)-Rg3 shows promising tumor-suppressive effects in ovarian cancer via inhibiting NF-kB signaling. This study aimed to explore the downstream tumor suppressive mechanisms of ginsenoside Rg3 via this signaling pathway. Materials and methods: A systematical screening was applied to examine the expression profile of 41 kinesin family member genes in ovarian cancer. The regulatory effect of ginsenoside Rg3 on KIF20A expression was studied. In addition, we explored interacting proteins of KIF20A and their molecular regulations in ovarian cancer. RNA-seq data from The Cancer Genome Atlas (TCGA) was used for bioinformatic analysis. Epithelial ovarian cancer cell lines SKOV3 and A2780 were used as in vitro and in vivo cell models. Commercial human ovarian cancer tissue arrays were used for immunohistochemistry staining. Results: KIF20A is a biomarker of poor prognosis among the kinesin genes. It promotes ovarian cancer cell growth in vitro and in vivo. Ginsenoside Rg3 can suppress the transcription of KIF20A. GST pull-down and co-immunoprecipitation (IP) assays confirmed that KIF20A physically interacts with BTRC (β-TrCP1), a substrate recognition subunit for SCF^β-TrCP E3 ubiquitin ligase. In vitro ubiquitination and cycloheximide (CHX) chase assays showed that via interacting with BTRC, KIF20A reduces BTRC-mediated CDC25A poly-ubiquitination and enhances its stability. Ginsenoside Rg3 treatment partly abrogates KIF20A overexpression-induced CDC25A upregulation. Conclusion: This study revealed a novel anti-tumor mechanism of ginsenoside Rg3. It can inhibit KIF20A transcription and promote CDC25A proteasomal degradation in epithelial ovarian cancer.

• Transactions of the Korean Society of Machine Tool Engineers
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• v.16 no.3
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• pp.125-132
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• 2007

The purpose of present paper is to investigate a fracture characteristics of the finite-width single-edge-notch(SEN) carbon fiber/epoxy reinforced plastics(CFRP) plates by using an acoustic emission(AE). Uni-directionally oriented 10 plies CFRPs specimen which had different notch length were prepared for monotonic tensile test. Matrix cracking appeared over whole testing process and fiber breaking appeared later on mainly Load distribution factor of the matrix confirmed that increased according as increases of plate width ratio. The amplitude distribution of AE signal from a specimens is an aid to the determination of the different fracture mechanism such as matrix cracking, disbonding, interfacial delamination, fiber pull-out, fiber breaking, and etc. In the result of AE amplitude distribution analysis, matrix cracking, fiber disbonding or interfacial delamination, and fiber pull-out or fiber breaking signal correspond to <65dB, <75dB, and <90dB respectively, Also, changes of the slope of cumulative AE energy represented crazing phenomena or degradation of materials.

• Proceedings of the Korean Environmental Health Society Conference
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• 2003.06a
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• pp.123-127
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• 2003

This experiment was performed to investigate the characteristics of sonolytic reaction as the basic data for development of the ultrasonic AOP(Advanced Oxidation Process) process from which the refractory organic compounds in aqueous solution which are not readily removed by the existing conventional wastewater treatment processes can be destructed and removed. Trichloroethylene (TCE), benzene, and 2,4-dichlorophenol(DCP) were used as the samples, and their destruction efficiency were measured in terms of experimental parameters of the initial solution concentration, initial solution pH, reaction temperature, acoustic frequencies and intensities. Results showed that the destruction efficiencies of all of the sample materials were above 80% within 120 minutes of sonolytic reaction in all reaction condition. The reaction order of these three compounds was verified as Pseudo first order. From the fore-mentioned results, it can be concluded that the refractory organic compounds could be removed by the ultrasonic irradiation with radicals, such as H$.$and OH$.$causing the high increase of pressure and temperature. Finally, it appears that the new AOP technology using ultrasonic irradiation can be applied to the treatment of refractory substances which are difficult to be decomposed by the conventional methods.

• International Journal of Concrete Structures and Materials
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• v.2 no.2
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• pp.137-143
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• 2008

In recent years, much research work has been performed on durability design and long-term performance of concrete structures in marine environments. In particular, the development of new procedures for probability-based durability design has been shown to provide a more realistic basis for the analysis. This approach has been successfully applied to several new concrete structures, where requirements for a more controlled durability and service life have been specified. For reinforced concrete structures in a marine environment, it is commonly assumed that the dominant degradation mechanism is the corrosion of the reinforcement due to the presence of chlorides. The design approach is based on the verification of durability limit states, examples of which are: depassivation of reinforcement, cracking and spalling due to corrosion, and collapse due to cross section loss of reinforcement. With this design approach the probability of failure can be determined as a function of time. In the present paper, a probability-based durability performance analysis is used in order to demonstrate the importance of the durability design approach of concrete structures in marine environments. In addition, the sensitivity of the various durability parameters affecting and controlling the durability of concrete structures in a marine environment is studied. Results show that the potential of this approach to assist durability design decisions making process is great. Based the crucial information generated, it is possible to prolong the service life of structures while simultaneously optimizing the final design solution.

• Journal of the Korean Society for Heat Treatment
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• v.19 no.3
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• pp.163-169
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• 2006

Fretting is a kind of surface degradation mechanism observed in mechanical components and structures. The fretting damage decreases into 50-70% of the plain fatigue strength. The connecting rod for automobile has been used in special environments and various loading conditions. Failure of connecting rod in automotive engine may cause catastrophic situation. In this study, we investigated the fatigue characteristic of connecting rod material for an automobile. Fatigue life is defined as the number of cyclic stress to failure by regular cyclic stress. Fatigue life of C70S6 specimen was obtained from 134,000 to 147,000 cycles. Fatigue limit showed 432MPa by normal fatigue test. The other hands, it was 96MPa in the case of fretting fatigue test. It was extremely lower than that of a normal fatigue test. From observation of fracture surface, it was confirmed that the fatigue crack was initiated at the boundary of a specimen and bridge pad.

• Corrosion Science and Technology
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• v.16 no.4
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• pp.209-225
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• 2017

Development of high strength steel requires proper understanding of hydrogen behavior since the higher the steel strength the greater the susceptibility of hydrogen assisted cracking. This paper provides a brief but broad overview on hydrogen entry and transport behavior of high-strength ferritic steels. First of all, hydrogen absorption, diffusion and trapping mechanism of the steels are briefly introduced. Secondly, several experimental methods for analyzing the physical/chemical nature of hydrogen uptake and transport in the steels are reviewed. Among the methods, electrochemical permeation technique utilized widely for evaluating the hydrogen diffusion and trapping behavior in metals and alloys is mainly discussed. Moreover, a modified permeation technique accommodating the externally applied load and its application to a variety of steels are intensively explored. Indeed, successful utilization of the modified permeation technique equipped with a constant load testing device leads to significant academic progress on the hydrogen assisted cracking (HAC) phenomenon of the steels. In order to show how the external and/or residual stress affects mechanical instability of steel due to hydrogen ingress, the relationship among the microstructure, hydrogen permeation, and HAC susceptibility is briefly introduced.

• Earthquakes and Structures
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• v.16 no.5
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• pp.589-599
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• 2019

Conventional buckling restrained braces used in concentrically braced frames are expected to yield in both tension and compression without major degradation of capacity under severe seismic ground motions. One of the weakness points of a standard buckling restrained braced frame is the low post-yield stiffness and thus large residual deformation under moderate to severe ground motions. This phenomenon can be attributed to low post-yield stiffness of core member in a BRB. This paper introduces a multi-core buckling restrained brace. The multi-core term arises from the use of more than one core component with different steel materials, including high-performance steel (HPS-70W) and stainless steel (304L) with high strain hardening properties. Nonlinear dynamic time history analyses were conducted on variety of diagonally braced frames with different heights, in order to compare the seismic performance of regular and multi-core buckling restrained braced frames. The results exhibited that the proposed multi-core buckling restrained braces reduce inter-story and especially residual drift demands in BRBFs. In addition, the results of seismic fragility analysis designated that the probability of exceedance of residual drifts in multi-core buckling restrained braced frames is significantly lower in comparison to standard BRBFs.