• Title/Summary/Keyword: Material separation

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Separation and Purification of 2,6-Dimethylnaphthalene Present in the Fraction of Light Cycle Oil by Crystallization Operation (결정화조작에 의한 접촉분해경유 유분에 함유된 2,6-디메틸나프탈렌의 분리·정제)

  • Kim, Su Jin
    • Applied Chemistry for Engineering
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    • v.29 no.6
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    • pp.799-804
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    • 2018
  • The separation and purification of 2,6-dimethylnaphthalene (2,6-DMN) present in the light cycle oil (LCO) fraction was investigated by a crystallization operation. Solute crystallization (SC) was performed using LCO fraction and iso-propyl alcohol as a raw material and a SC solvent, respectively. Increasing the operation temperature and volume ratio of the solvent to the raw material (S/F) resulted in improving the purity of 2,6-DMN, whereas the yield decreased. As a result of the crystallization operation in three steps containing the SC using LCO fraction (13.9% 2,6-DMN) and isopropyl alcohol, the re-crystallization 1 (RC 1) using the crystals recovered by SC and methyl acetate, and RC 2 using the crystals recovered by RC 1 and methyl acetate, the crystal with 99.9% 2,6-DMN was recovered with 19.5% yield. Furthermore, the separation and purification process of 2,6-DMN present in the LCO fraction was reevaluated by using the experimental results obtained through each operations of SC, RC 1, and RC 2.

Experimental observation and numerical simulation of cement grout penetration in discrete joints

  • Lee, Jong-Won;Kim, Hyung-Mok;Yazdani, Mahmoud;Lee, Hangbok;Oh, Tae-Min;Park, Eui-Seob
    • Geomechanics and Engineering
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    • v.18 no.3
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    • pp.259-266
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    • 2019
  • This paper presents a comparison between experimental measurements and numerical estimations of penetration length of a cement grout injected in discrete joints. In the experiment, a joint was generated by planar acryl plates with a certain separation distance (; aperture) and was designed in such a way to vary the separation distances. Since a cement grout was used, the grout viscosity can be varied by controlling water-cement (W/C) ratios. Throughout these experiments, the influence of joint aperture, cement grout viscosity, and injection rate on a penetration length in a discrete joint was investigated. During the experiments, we also measured the time-dependent variation of grout viscosity due to a hardening process. The time-dependent viscosity was included in our numerical simulations as a function of elapsed time to demonstrate its impact on the estimation of penetration length. In the numerical simulations, Bingham fluid model that has been known to be applicable to a viscous cement material, was employed. We showed that the estimations by the current numerical approach were well comparable to the experimental measurements only in limited conditions of lower injection rates and smaller joint apertures. The difference between two approaches resulted from the facts that material separation (; bleeding) of cement grout, which was noticeable in higher injection rate and there could be a significant surface friction between the grout and joint planes, which are not included in the numerical simulations. Our numerical simulation, meanwhile, could well demonstrate that penetration length can be significantly over-estimated without considering a time-dependency of viscosity in a cement grout.

Cesium removal in water using magnetic materials ; A review (자성체 물질을 이용한 수중의 세슘제거 동향)

  • Yeo, Wooseok;Cho, Byungrae;Kim, Jong Kyu
    • Journal of the Korean Society of Industry Convergence
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    • v.21 no.6
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    • pp.395-408
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    • 2018
  • Even after the Fukushima nuclear accident in 2011, the rate of production of electric energy using nuclear energy is increasing, but there is a great danger such as the radioactive waste produced when using nuclear power, the catastrophic accident of nuclear power plant, and connection with nuclear weapons. In particular, Cs present in the ionic form of alkaline elements has a long half-life (30.17 years) because it is readily absorbed by the organism and emits intense gamma rays, thus presenting a serious radiation hazard. Therefore, it must be completely removed before it can be released into the natural ecosystem, because it can adversely affect not only humans but also natural ecosystems. Many adsorbents and ion exchangers which have high Cs removal efficiency have been used in recent years to completely separate and remove by self separation in water. Many adsorbents and ion exchangers which have high Cs removal efficiency have been used in recent years to completely separate and remove by self separation in water. In addition, researches have been doing to synthesize magnetic materials with adsorbents such as HCF and PB, and it shows a great effect in the removal rate of Cs present in wastewater or the maximum Cs adsorption amount. In particular, when a magnetic material was applied, excellent results were obtained in which only Cs was selectively removed from other cations. However, new problems such as applicability in the sea where Cs is directly released, applicability in various pH ranges, and failure to preserve the magnetizing force possessed by the magnetic body have been found. However, researches using ferromagnetic field with stronger magnetic properties than those of magnetic bodies is considered to be insufficient. Therefore, it is considered that if the researches combining the ferromagnetic field with the magnetization ability and functional adsorbents more actively, the radioactive material Cs which adversely affects the natural ecosystem can be effectively removed.

Investigation of continuous and discontinuous contact cases in the contact mechanics of graded materials using analytical method and FEM

  • Yaylaci, Murat;Adiyaman, Gokhan;Oner, Erdal;Birinci, Ahmet
    • Computers and Concrete
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    • v.27 no.3
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    • pp.199-210
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    • 2021
  • The aim of this paper was to examine the continuous and discontinuous contact problems between the functionally graded (FG) layer pressed with a uniformly distributed load and homogeneous half plane using an analytical method and FEM. The FG layer is made of non-homogeneous material with an isotropic stress-strain law with exponentially varying properties. It is assumed that the contact at the FG layer-half plane interface is frictionless, and only the normal tractions can be transmitted along the contacted regions. The body force of the FG layer is considered in the study. The FG layer was positioned on the homogeneous half plane without any bonds. Thus, if the external load was smaller than a certain critical value, the contact between the FG layer and half plane would be continuous. However, when the external load exceeded the critical value, there was a separation between the FG layer and half plane on the finite region, as discontinuous contact. Therefore, there have been some steps taken in this study. Firstly, an analytical solution for continuous and discontinuous contact cases of the problem has been realized using the theory of elasticity and Fourier integral transform techniques. Then, the problem modeled and two-dimensional analysis was carried out by using ANSYS package program based on FEM. Numerical results for initial separation distance and contact stress distributions between the FG layer and homogeneous half plane for continuous contact case; the start and end points of separation and contact stress distributions between the FG layer and homogeneous half plane for discontinuous contact case were provided for various dimensionless quantities including material inhomogeneity, distributed load width, the shear module ratio and load factor for both methods. The results obtained using FEM were compared with the results found using analytical formulation. It was found that the results obtained from analytical formulation were in perfect agreement with the FEM study.

Nanofood Materials and Approachable Development of Nanofunctional Dairy Products (나도 식품 소재와 나노 기능성 유제품 개발의 가능성)

  • Gwak, Hae-Su;Kim, Dong-Myeong
    • Journal of Dairy Science and Biotechnology
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    • v.22 no.1
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    • pp.1-12
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    • 2004
  • Nanofood is advanced functional food which food industry and food scientist try to develop process foods in near future. To be developed nanofood, nanofood materials are needed, such as biodegradable nanosphere material, biotechnical nanofood material, and protein and nanofood material. There are some food industrial applications with nanotechnology, such as nanoencapsulation, nanomolecule making, nanoparticle and powder making, nano separation, and nano extration. We can find several nanofoods and nanofood materials on the market. In addition, dairy industry is also in the first step for the development of nanofunctional food. However, nanoencapsulations of lactase, iron, vitamin C, isoflavone are developed for functional milk. Dairy industry needs various nanofood materials to be advanced functional dairy products.

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Structural Behavior of Worn Tire Attached to Carbon Fiber Steel Pile by Wave and Current Forces (파랑 및 조류력에 의한 탄섬유강 말뚝에 부착된 폐타이어의 구조거동)

  • 홍남식;이상화
    • Journal of Ocean Engineering and Technology
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    • v.18 no.3
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    • pp.13-19
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    • 2004
  • The structural behavior of a worn tire, attached to carbon fiber steel pile by current and wave forces, has been investigated through the numerical method. The finite element model has been developed, by considering that the composite material of rubber and cord is orthotropic, the rubber is isotropic, and that all the material behaves as linear elastic. The pressure distribution by wave and current, around the worn tire, has been estimated through the adjustment for the concept of flow separation. Also, the structural behavior of the worn tire has been examined, by comparing the situation wherein the space between the pile is reinforced, and tire as elastic and isotropic material, with the one left empty. Through this comparison, it is determined that the space between pile and tire has to be filled with elastic and isotropic material, in order to avoid the failure by wave and current action.

Hydrophobic Membrans of Tetrafluoroethylene and 2,2,4, Trifluoro 5 Trifluorometoxy 1,3 Dioxole

  • Gordano, A.;Clarizia, G.;Tocci, E.;Drioli, E.
    • Korean Membrane Journal
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    • v.1 no.1
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    • pp.50-58
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    • 1999
  • Symmetric asymmetric and composite perfluoropolymer membranes made with HYFLON AD have been prepared and evaluated. Porous and non porous symmetric membranes have been prepared by solvent evaporation with various processing conditions. Non-contact atomic force microscopy (AFM) was used to investigate the membrane morphology in air. Analysis of the images gave quantitative imformation on the surface pore strcture in particular on the pore size distributin. Possible useful uses of porous membranes are envisaged in the field of gas-liquid separations such as membrane contactors (MSc) Molecular Dynamics(MD) simulations structure of HYFLON AD 60X copolymer supporting these results are also reported. Amorphous perfluoropolymer membranes appears to be ideal other than in MCs when separation processes have to be performed in hostile environments i.e. high temperatures and aggressive non-aqueous media such as chemicals and solvents. In these cases HYFLON AD mem-branes can exploit the outstanding resistance of perfluoropolymers.

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A Case Study for Construction Method of drilled Shafts installed in Very Soft Soil (초연약지반에 시공된 현장타설말뚝의 시공방안 사례연구)

  • 최용규;이민희;백동진
    • Proceedings of the Korean Geotechical Society Conference
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    • 2002.06a
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    • pp.103-117
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    • 2002
  • During the installation of drilled shafts in very soft ground, to keep the pile shape and to central concrete quality, casing method (wrinkled pipe and embedded steel pipe) and non-casing method have been used. In the construction cost, non-casing method was the most economical. When the wrinkled pipe and the embedded steel pipe casing method are used, an increase of 133% and 123% in the construction cost could be seen. When concrete for drilled shaft was placed under groundwater, underwater unseparation concrete would be used to restrain the concretes's material separation and to control the concrete quality. On the condition of required unseparable and (lowing property was assured, use of less amount of mixed material and flowing material must be recommended.

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Feasibility Evaluation of Co-Incineration with MSW for Efficient Recycling of the Rejects after Separation Processes in MRF (재활용 기반시설에서 발생하는 선별 잔재물의 자원화를 위한 도시생활폐기물과의 혼합소각 가능성 평가)

  • Shin, Taek-Soo;Sung, Baek-Nam;Yeon, Ik-Jun;Cho, Byung-Yeol;Kim, Kwang-Yul
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.10
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    • pp.767-773
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    • 2011
  • The purpose of this study was to investigate the possibility of an alternative fuel resource by incinerating a mix of combustible MSW (municipal solid waste) and offals after separating recyclable material at the MRF (material recovery facilities) location. We analyzed the physical and chemical properties including the 3-contents, the calorific value, and chemical compositions of the separation rejects in MRF, and compared the results with combustible MSW. Moreover, we experimented the trend of combustible properties and the concentration change of air pollutants at mixed incineration in the MSW incinerator. According to the results of the experiment, the separation rejects showed higher heating value (5,865 kcal/kg), and lower moisture and ash content than combustible MSW. Since we have incinerated MSW in the MSW incinerator mixing the offals at 30% and 50% respectively, we know that the change of the concentration of dust, $SO_2$, $NO_2$, and CO did not appear significant, and not exceed the pollutants emission regulation. But, considering the enhancement of the HCl emission concentration (max. 33.7 ppm) at the co-incineration of the 50% offals, we believe that the proper mixing ratio of the separation rejects would become within 30%.

A Study on Classification of Limonite and Saprolite from Nickel Laterite Ores (뉴칼레도니아산 니켈라테라이트광의 분급 연구)

  • Seo, Joobeom;Kim, Kee-seok;Bae, In-kook;Lee, Jae-young;Kim, Hyung-seok
    • Resources Recycling
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    • v.25 no.1
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    • pp.40-47
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    • 2016
  • Nickel laterite ore is classified into two principal ore types: saprolite (silicate ore) and limonite (oxide ore). Saprolite-type ore characterized by high magnesia and silica contents is treated by pyrometallurgy process. On the other hand, limonite-type ore is subjected to hydrometallurgy process to produce nickel products. Hydrometallurgy process requires that a raw material to meet the demands that Si+Mg contents lower than 10% and Fe content over than 40%. It is therefore required that separation of saprilite-type ore to use nickel laterite ore as a raw material for hydrometallurgy process. In this study, separation of sparolite-type ore and limonite-type ore from nickel laterite ore from New Caledonia has been tried by dry classification. The results show that -5 mm size fraction and +5 mm size fraction of the nickel laterite ore contains mainly limonite-type ore and saprolite-type ore, respectively. To understand the moisture content of the raw ore on the dry classification, nickel laterite ore with different moisture contents of 23.0% and 9.1% were subjected to the dry classification. The results show that drying of the ore makes the separation more efficient as the amount of the fine product, that can be subjected to hydrometallurgy process without further separation or drying operations, was increased.