• Title/Summary/Keyword: Master-batch

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Evaluation on Dielectric Properties of Epoxy/Montmorillonite Nanocomposites (에폭시/몬모릴로나이트 나노복합재료의 유전특성 평가)

  • Jang, Yong-Kyun;Kim, Woo-Nyon;Kim, Jun-Kyung;Park, Min;Yoon, Ho-Gyu
    • Polymer(Korea)
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    • v.30 no.6
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    • pp.492-497
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    • 2006
  • The epoxy composites are prepared with mixing temperature of epoxy/montmorillonite (MMT) melt master batch and the dielectric properties of the composites are also compared with intercalation of MMT. The exfoliation mainly occurrs iii the low content of MMT composites, while in the composites with high content of MMT the interspacing distance increases as the mixing temperature of epoxy/MMT master batch is increased. Class transition temperature of the composite which the MMT are effectively exfoliated is increased with the appropriate postcuring condition. Since the orientation polarization of dipoles in the epoxy molecules is restricted by the clay nanolayers exfoliated, the dielectric constant and dielectric loss of the composites are reduced. Furthermore, the dielectric properties could be improved by controling the mixing temperature and time of epoxy/MMT master batch as well as postcuring condition.

New Engineering Techniques for Carbon Master Batch (탄소 마스터배치를 위한 새로운 엔지니어링 기술)

  • Pyo, Sang-Gil;Kang, Chang-Gi;Kim, Ki-Seok;Park, Soo-Jin
    • Elastomers and Composites
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    • v.48 no.2
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    • pp.125-132
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    • 2013
  • In this work, we have discussed new engineering systems for preparing carbon master batch composed by carbon black and various organic compounds. In general, polymer resin, which applied for automobile tire, household items, and various industry items, is used with the fillers including carbon black and silica to control the color or properties. Domestic part and material industry has been remarkably developed in that the development of materials including the compounding of raw materials. Meanwhile, the engineering technique for mass production has not reached to a requirement of industry due to slow technique development and high dependence on foreign. Thus, we will focus on the introduction of new engineering technique developed by domestic company for preparing carbon master batch.

Miscibility and Bleaching of Modified Polypropylene (개질 Polypropylene의 혼화성과 표백)

  • Cho, Kyu-Min;Cho, In-Sul;Chang, Du-Sang;Lee, Eun-Woo;Kim, Oh-Nyen
    • Textile Coloration and Finishing
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    • v.10 no.6
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    • pp.33-41
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    • 1998
  • 이 연구는 염색성이 열악한 polypropylene(PP) 섬유의 염색성을 개선하기 위해 추진한 것이다. 연구목적에 따라서 PP 섬유를 개질하기 위해 1차 cellulosic유도체를 추출하고 이 유도체와 PP를 9:1의 혼합비율로 섞어 master batch를 만든 다음 master batch 17%와 PP를 blending하여 개질 PP를 만들었다. 이렇게 제조된 개질 PP는 혼합된 변성 cellulosic polymer의 영향으로 착색이 심하게 되어 있으므로 이를 표백하는 것을 이 연구의 목적으로 하였다. 연구결과 blend한 개질 PP(Grand P)의 혼화성이 우수하였고, 아염소산나트륨에 표백적성을 가지며, 표백의 최적조건은 표백제의 농도가 0.1% $NaClO_2$, 표백온도 $70^\circ{C}$, 표백시간 30분이었다.

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Comparison Study of the Synthesized Silver Nano-particles using Liquid Phase Reduction Method and Alcohol Reduction Process (액상환원법과 알코올환원법으로 제조한 은나노입자특성 비교에 관한 연구)

  • Son, Eun-Jong;Hwang, Young-Gu;Shin, Yu-Shik;Jeong, Sung-Hoon
    • Textile Coloration and Finishing
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    • v.23 no.2
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    • pp.146-153
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    • 2011
  • Silver nano-particles have been synthesized by liquid phase reduction method and alcohol reduction process. Silver nano-particles of the size 30 ~ 40 nm were formed successfully by alcohol reduction process. The formation, structure, morphology and size of silver nano-particles have been studied using FE-SEM, TEM, XRD, UV-visible spectroscopy. In particular high dispersion stability of the synthesized silver nano-particles could be obtained by PVP binding. Antibacterial activity of Ag/PET master batch sample made from its nano-silver particles showed excellent antibacterial activity against S. aureus and E. coli.

Characterization and Evaluation of Porous Vermiculite Containing Polyethylene Composites Film

  • Lee, Hye Sun;Chang, Jeong Ho
    • Journal of the Korean Ceramic Society
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    • v.55 no.1
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    • pp.85-89
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    • 2018
  • This work reported the preparation and evaluation of a freshness-keeping film prepared by composite of a porous ceramic material such as vermiculite and polyethylene polymer. The ceramic material was pretreated physically and chemically to control the specific surface areas and particle size. A high content master-batch was prepared using the pretreated vermiculite. The master-batch, which contained 30% ceramic material, was mixed with a polymer material to prepare a film containing 3% vermiculite. The oxygen permeability and various physicochemical properties were evaluated for the prepared films. Compared to plain polyethylene film, the vermiculite loaded polyethylene film has a freshness maintenance property, indicating the creation of an improved film.

Effect of Master Batch and Compatibilizer on the Physical and Rheological Properties of PP/CNF Composite (PP/CNF 복합체의 물리적 성질 및 유변학적 특성에 대한 마스터배치와 상용화제의 영향)

  • San Kang;Yoo Jin Lee;Youn Cheol Kim
    • Applied Chemistry for Engineering
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    • v.35 no.5
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    • pp.418-422
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    • 2024
  • Polypropylene (PP)/CNF composites containing 3, 7, and 10 phr of cellulose nanofibers (CNF) were manufactured using a twin-screw extruder. CNF was introduced in the form of powder or master batch (MB) into ethylene-acrylic acid copolymer (EEA), and maleic anhydride grafted PP (PP-g-MAH) was used as a compatibilizer. The results of measuring the tensile strength and flexural strength showed that the degree of improvement in the mechanical properties of the PP/CNF composites applied with the compatibilizer was the greatest. This was confirmed by the morphological analysis of SEM, which was due to the increased compatibility between PP and CNF. It was confirmed that the complex viscosity of the PP/CNF composite in the low frequency range was higher than that of pure PP, but there was no significant difference in processing characteristics due to the increase in shear thinning phenomenon.

Recycling of Sound Insulation Headliner Waste Material (흡음재 폐기물의 재활용 방안)

  • Hong, Young-Ho
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.6
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    • pp.3089-3095
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    • 2013
  • The headliner was made of polyurethane(PU) and glass fiber(GF) composite materials are widely used as a sound insulation material. A large amount of waste materials occurs as a by-product in the headliner manufacturing process. In order to efficiently reuse the headliner waste materials, separation process of the components are very necessary. According to the results of thermal analysis, weight loss showed increase in the order polyurethane foam> non-foaming polyurethane> non-woven fabric> 1st layer> glass fiber in the range of up to $400^{\circ}C$. Analysis of the DSC characteristics, HDPE, LLDPE, PP, and Master Batch by adding additives the wasted scrap. As a result, except for the PP, there was no exothermic transition due to the crystallization.

Study on the talc dispersion and rheological properties of PP/talc compound (PP/talc 컴파운드의 talc 분산성 및 유변학적 특성 연구)

  • You, Young-Chul;Kim, Youn-Cheol
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.12 no.9
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    • pp.4261-4266
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    • 2011
  • Polypropylene (PP)/talc compounds with talc content of 20wt% were fabricated by master-batch (MB) and direct compounding method using injection molding. The MB was prepared by mini compounder at $200^{\circ}C$ and the content of talc was 50wt%. The talc dispersion of the PP/talc compound was investigated by SEM-EDS. The talc was well dispersed within PP matrix in case of the MB-PP compound using MB. The rheological properties of the PP/talc compounds were measured by dynamic Rheometer. The MB-PP compound indicates higher shear thinning and elastic property than direct compound. The disperion of talc was certified by G'-G" plot, and Van Gurp-Palmen analysis was applied in order to certify an increase in elasticity.

Determination of Optimum Batch Size and Fuel Enrichment for OPR1000 NPP Based on Nuclear Fuel Cycle Cost Analysis (OPR1000 발전소의 핵연료 주기비분석을 통한 최적 배취 크기와 핵연료 농축도 결정)

  • Cho, Sung Ju;Hah, Chang Joo
    • Journal of Energy Engineering
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    • v.23 no.4
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    • pp.256-262
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    • 2014
  • Cycle length of domestic nuclear power plants is determined by the demand-supply plan of utility company. The target cycle length is achieved by adjusting the number of feed fuel assembly and fuel enrichment. Traditionally, utility company first select the number of feed fuel assembly and then find out the fuel enrichment to achieve the special cycle length. But it is difficult to find out if this method is most economical than any other combinations of the enrichment and batch size satisfying the same cycle length. In this paper, core depletion calculation is performed to find out the optimum combination of the enrichment and batch size for given target cycle length in terms of fuel cycle cost using commercial core design code; CASMO/MASTER code. To minimize the uncertainty resulting from transition core analysis, levelized fuel cycle cost analysis was applied to the equilibrium cycle core in order to determine the optimum combination. The sensitivity study of discount rate was also carried out to analyze the levelized fuel cycle cost applicable to countries with different discount rates. From the levelized fuel cycle cost analysis results, the combination with smaller batch size and higher fuel enrichment becomes more economical as the discount rate becomes lower. On the other hand, the combination with higher batch size and lower fuel enrichment becomes more economical as the discount rate becomes higher.

Far-Infrared Emission Characteristics of Germanium Included Fabrics for Emotional Garment (게르마늄 함유 감성의류용 직물의 원적외선 방출 특성)

  • Kim, Hyun-Ah;Kim, Seung-Jin
    • Science of Emotion and Sensibility
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    • v.13 no.4
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    • pp.687-692
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    • 2010
  • This paper surveys emission characteristics of Far-infrared of the fabrics fabricated with germanium imbedded sheath-core conjugate composite filaments. For this purpose, master batch chip was prepared with PET semi-dull chip and nano sized germanium particles and sheath-core type conjugate composite filament was spun using this master batch chip and polyester semi dull. The emission power and emissivity of the germanium imbedded fabrics were measured and investigated using FT-IR spectrophotometer by KICM- FIR 1005 measurement method. In addition, the fabric mechanical properties were measured and discussed with the effects of the optimum texturing process conditions and fabric structural design conditions. The sheath/core type PET composite germanium imbedded filaments were manufactured by the optimum spinning condition, its tenacity and breaking strain showed the same level as the regular PET filament. The tenacity and breaking strain of the DTY showed good physical properties and no problem in the weaving process. Then, wet and dry shrinkages showed higher values than those of regular PET filament. The emission power of the germanium imbedded fabric was $3.53{\times}10^2W/m^2$ at the $5-20{\mu}m$ wave length range, and emissivity was 0.874. The fabric hand of germanium imbedded fabrics was inhanced by the optimum texturing process and fabric structural design with improved mechanical properties such as fabric bending and compressional properties.

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