• Title/Summary/Keyword: Mass changes

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Improved Cycle Performance of High-Capacity SiOx Negative Electrodes with Carbon Nanotube Conducting Agents for Lithium-Ion Batteries (탄소나노튜브 도전재 적용을 통한 리튬이온 이차전지용 고용량 SiOx 음극의 사이클 성능개선)

  • Hyang Sun Jeon;Ji Heon Ryu
    • Journal of the Korean Electrochemical Society
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    • v.26 no.3
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    • pp.35-41
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    • 2023
  • The carbon-coated silicon monoxide (c-SiOx), which is a negative electrode active material for lithium-ion batteries (LIBs), has a limited cycle performance due to severe volume changes during cycles, despite its high specific capacity. In particular, the significant volume change of the active material can deform the electrode structure and easily damage the electron transfer pathway. To improve performance and mitigate electrode damage caused by volume changes, we replaced parts of the carbon black conducting agent with carbon nanotubes (CNTs) having a linear shape. The content of the entire conductive material in the electrode was fixed at 10% by mass, and the relative content of CNTs ranged from 0% to 25% by mass to prepare electrodes and evaluate electrochemical performance. As the CNT content in the electrode increased, both cycle life and rate capability improved. Even a small amount of CNT can significantly improve the electrochemical performance of a c-SiOx negative electrode with large volume changes. Furthermore, dispersing CNTs effectively can lead to achieving the equivalent performance with a reduced quantity of CNTs.

Effects of Changes in Accelerated Degradation Conditions for Catalyst Supports in Polymer Electrolyte Fuel Cell (고분자전해질 연료전지(PEMFC)에서 촉매 지지체 가속 열화 조건 변화의 영향)

  • Sohyeong Oh;Yuhan Han;Donggeun Yoo;Myoung Hwan Kim;Ji Young Park;Youngjin Choi;Kwonpil Park
    • Korean Chemical Engineering Research
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    • v.62 no.1
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    • pp.7-12
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    • 2024
  • The durability of the catalyst support has a significant effect on the durability of proton exchange membrane fuel cells (PEMFC). The accelerated durability evaluation of the catalyst support is performed at a high voltage (1.0 to 1.5 V), and the catalyst and ionomer binder in the catalyst layer are also deteriorated, hindering the evaluation of the durability of the support. The existing protocol (DOE protocol) was improved to find conditions in which the support, which is a durability evaluation target, deteriorates further. A protocol (MDOE) was developed in which the relative humidity was lowered by 35% and the number of voltage changes was reduced. After repeating the 1.0 ↔ 1.5 V voltage change cycle, the catalyst mass activitiy (MA), electrochemical active area (ECSA), electrical double layer capacity (DLC), Pt dissolution and particle growth were analyzed. Reaching 40% reduction in mass activity, the MDOE protocol took only 500 cycles, reducing the number of voltage changes compared to the DOE method and increasing the degradation of the carbon support by 50% compared to the DOE protocol.

Gender Identity Expression in Contemporary Men's Fashion - Focus on Judith Butler's Gender Identity Theory - (현대 남성복에 나타난 젠더 정체성 - 주디스 버틀러의 정체성 이론을 중심으로 -)

  • Kim, Hyun Jung;Yim, Eun Hyuk
    • Journal of the Korean Society of Costume
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    • v.65 no.3
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    • pp.47-61
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    • 2015
  • Dress functions as a clear boundary between gender differences In the past. However dress in the 21st century, due to movement of feminism during the 1960's, advance of mass media and the influence of postmodernism, the boundary of gender differences has been blurred. Especially in men's fashion, where there was no little changes in traditional menswear, it is noteworthy that there appears some changes. The research about gender has developed to queer theory, subjected on gender itself, founded on the gender diversity. The purpose of the study is to conduct the implied meanings of dress in contemporary society, when gender diversity has been expressed in men's fashion, and to review the characteristics of contemporary men's fashion through the collections and advertisements of post 2000's as well as internet sites. This research is based on theory of Judith Butler, which is on the center of feminism and queer theory. Homosexual expressions which are presented in male clothing and advertisement produce rejection of the dichotomous view of gender concept and allowing of individual gender identity expression.

Influence of Panax ginseng on obesity and gut microbiota in obese middle-aged Korean women

  • Song, Mi-Young;Kim, Bong-Soo;Kim, Hojun
    • Journal of Ginseng Research
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    • v.38 no.2
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    • pp.106-115
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    • 2014
  • Background: Gut microbiota is regarded as one of the major factors involved in the control of body weight. The antiobesity effects of ginseng and its main constituents have been demonstrated, but the effects on gut microbiota are still unknown. Methods: To investigate the effect of ginseng on gut microbiota, 10 obese middle-aged Korean women took Panax ginseng extracts for 8 wk and assessment of body composition parameters, metabolic biomarkers, and gut microbiota composition was performed using 16S rRNA gene-based pyrosequencing at baseline and at 8 wk. Significant changes were observed in body weight and body mass index; however, slight changes were observed in gut microbiota. We divided the participants into two groups, the effective and the ineffective weight loss groups, depending on weight loss effect, in order to determine whether the antiobesity effect was influenced by the composition of gut microbiota, and the composition of gut microbiota was compared between the two groups. Results: Prior to ginseng intake, significant differences of gut microbiota were observed between both at phyla and genera and the gut microbiota of the effective and ineffective weight loss groups was segregated on a principal coordinate analysis plot. Conclusion: Results of this study indicate that ginseng exerted a weight loss effect and slight effects on gut microbiota in all participants. In addition, its antiobesity effects differed depending on the composition of gut microbiota prior to ginseng intake.

A study on Architectural Characters of well-designed middle and high school buildings in 2000's - On Winning Works of 'The Excellent Facility School Award' by Ministry of Education, Science and Technology - (2000년 이후 중.고등학교 시설의 건축 특성 연구 - 교육과학기술부 선정 '우수시설학교' 수상작을 중심으로 -)

  • Seong, Eun-Young;Yang, Sang-Hyun
    • Journal of the Korean Institute of Educational Facilities
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    • v.19 no.1
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    • pp.25-35
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    • 2012
  • The function and the role of school are changing according to various future-oriented education models such as open-ended learning cycle, community learning center, re-schooling, network system and de-schooling, which reflect recent social demands related to discussions on sustainability, low birth rate and ageing. what changes to our school buildings have been there? This study is aimed that shows the architectural change of school buildings and environments in 2000's. It reveals the architectural tendancy through some school buildings, 'the excellent facility school award' winner which Ministry of Education, Science and Technology have chosen annually since 1998. In the past decade, it is outstanding change that mass composition, window patterns and exterior wall materials are diversified greatly. The most of them have a opened main hall and multi-purpose spaces which give effective educational environment to students. Although visual changes are outstanding, we still need qualitative educational space program and improved school building design according to future-educational demands.

Study on Transient Response of a Unit Proton Exchange Membrane Fuel Cell with an Aged Gas Diffusion Layer (내구성능저하된 기체확산층이 고분자전해질 연료전지의 과도응답성능에 미치는 영향 연구)

  • Cho, Junhyun;Ha, Tahun;Park, Jaeman;Oh, Hwanyeong;Min, Kyoungdoug;Jyoung, Jy-Young;Lee, Eunsook
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.76.2-76.2
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    • 2010
  • The gas diffusion layer is the key component of the proton exchange membrane fuel cell because it directly affect to the mass transport mechanism and dynamic behavior of the cell. In this study, the effects of GDL aging on the transient response of the PEM fuel cell is systematically investigated using current step transient response analysis under different stoichiometric ratios and humidity conditions. With GDLs aged by the accelerated stress test, the effects of hydrophobicity and structural changes due to carbon loss in the GDL on the transient response of PEM fuel cells are determined. The degraded GDLs that had uneven hydrophobicity distributions cause local water flooding inside the GDL and induce lower and unstable voltage responses after load changes.

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A Morphological Study on the Titanium-Oxide Foams Processed Using Freeze-Casting (동결 주조법으로 제조된 티타늄 옥사이드 폼의 구조 연구)

  • Yoon, Hyunjung;Choe, Heeman;Choi, Hyelim
    • Journal of the Korean Ceramic Society
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    • v.49 no.5
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    • pp.427-431
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    • 2012
  • The $TiO_2$ foam synthesized using freeze-casting is a promising photocatalyst and photovoltaic electrode for a variety of energy applications, because the freeze-casting technique is easy to use, cheap, and suitable for mass-production. Despite its several advantages, little scientific information is available on the processing and morphology of the $TiO_2$ foams processed by freeze-casting. In particular, no systematic study has been performed on the microstructural evolution and morphological change of the rutile-phase $TiO_2$ foams during sintering. Therefore, in the present study, several $TiO_2$ foam samples were produced using the freeze-casting technique, which were then sintered at a relatively high temperature of $1200^{\circ}C$ for 1, 2, and 4 h to compare the morphological changes in the microstructure and to understand the effects of processing parameters of the rutile-phase $TiO_2$ foams. The foam ligament size increased near linearly with increasing sintering time whereas the average pore size decreased only slightly with increasing sintering time, with changes in particle morphology from sphere to rod and complete phase transformation from anatase to rutile.

Development of Methods for Protein Extraction from Three Major Korean Fermented Soy Foods for 2-Dimensional Gel and Mass Spectrometric Analyses

  • Lim, Jin-Kyu
    • Journal of Applied Biological Chemistry
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    • v.51 no.3
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    • pp.88-94
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    • 2008
  • Three different protein extraction methods-phenol extraction, trichloroacetic acid (TCA) precipitation, and desalting/TCA precipitation-were compared to determine the optimal reproducible high resolution 2-dimensional (2-D) electrophoresis for each chungkugjang, doenjang, and kochujang samples. The soluble proteins from Chungkugjang extracted by phenol were separated with high reproducibility and resolution, and gained 1.75- to 3-fold more protein spots on 2-D gel than those from the other methods. On the contrary, the extracted proteins from doenjang and kochujang treated by desalting/TCA precipitation method showed about 1.5- to 3.3-fold more protein spots on 2-D gel. Using the established methods, the changes in the protein profiles of the fermented soy foods were monitored during the fermentation period by 2-DE. One of the major proteins in soy, $\beta$-conglycinin $\alpha$-subuint, and some proteins with unknown functions were localized on 2-D gel as the protease-resistant proteins throughout the fermentation period of doenjang. Changes in the protein profile monitored by the established methods can provide basic information on unfolding the mechanisms of the generation of biofunctional activity in the fermented soy foods.

Numerical Simulation of the Liquid Flow in the Lower Part of the Blast Furnace - A Cold Flow Case (고로하부 액체유동에 대한 수치해석 사례 - 냉간유동)

  • Jin, Hong-Jong;Choi, Sang-Min;Jung, Jin-Kyung
    • Journal of the Korean Society of Combustion
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    • v.13 no.2
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    • pp.33-41
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    • 2008
  • The high permeability of the gas in the molten iron of the dripping zone of the blast furnace is a major factor in achieving the stable operation of a furnace with high productivity. Basic studies of the liquid flow behavior in a packed bed are necessary to grasp the effect of various operational changes on conditions in the dropping zone. Molten iron and slag together playa critical role in the lower zone, transporting mass and energy, while impairing and redistributing the gas flow. In turn, molten iron and slag undergo physical and chemical changes, and are redistributed radially as they descend to the hearth. In this research, mathematical formulations are derived for the gas and the liquid. The solid phase is fixed with constant porosity. The information for the molten iron and slag includes the hold-up, velocity, pressure, and information related to the areas of interaction between the gas and the liquid, and the solid and the liquid. Predictable results include the velocity, pressure and temperature distribution. Additional parameters include the packed particle size and the air blast rate.

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A Study of Multi-scenario in Visual Novel (비주얼 노블 멀티 시나리오 분석)

  • Lee, So-Hee
    • Journal of Korea Game Society
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    • v.18 no.2
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    • pp.59-68
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    • 2018
  • A visual novel, a type of digital content combining novel and game, was designed as hypermedia which includes various media, for instance, image, sound, and video. The narrative of visual novel contains multimedia elements and highlights multi-scenario structures based on hypertext. Prior to creating visual novel scenario, a writer should thoroughly consider two main points. First of all, the scenario should cover the multimedia features of visual novel. Secondly, the scenario should be structured as a multi-scenario providing with performativity to players for interaction with readers. This study examines the influence of changes in platforms on visual novel scenario adjusted to mobile environment. It would provide an opportunity to understand how storytelling changes and adapts to rapid transformation of digital media contents.