• Title/Summary/Keyword: Mass Efficiency

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LIMITED OXIDATION OF IRRADIATED GRAPHITE WASTE TO REMOVE SURFACE CARBON-14

  • Smith, Tara E.;Mccrory, Shilo;Dunzik-Gougar, Mary Lou
    • Nuclear Engineering and Technology
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    • v.45 no.2
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    • pp.211-218
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    • 2013
  • Large quantities of irradiated graphite waste from graphite-moderated nuclear reactors exist and are expected to increase in the case of High Temperature Reactor (HTR) deployment [1,2]. This situation indicates the need for a graphite waste management strategy. Of greatest concern for long-term disposal of irradiated graphite is carbon-14 ($^{14}C$), with a half-life of 5730 years. Fachinger et al. [2] have demonstrated that thermal treatment of irradiated graphite removes a significant fraction of the $^{14}C$, which tends to be concentrated on the graphite surface. During thermal treatment, graphite surface carbon atoms interact with naturally adsorbed oxygen complexes to create $CO_x$ gases, i.e. "gasify" graphite. The effectiveness of this process is highly dependent on the availability of adsorbed oxygen compounds. The quantity and form of adsorbed oxygen complexes in pre- and post-irradiated graphite were studied using Time of Flight Secondary Ion Mass Spectrometry (ToF-SIMS) and Xray Photoelectron Spectroscopy (XPS) in an effort to better understand the gasification process and to apply that understanding to process optimization. Adsorbed oxygen fragments were detected on both irradiated and unirradiated graphite; however, carbon-oxygen bonds were identified only on the irradiated material. This difference is likely due to a large number of carbon active sites associated with the higher lattice disorder resulting from irradiation. Results of XPS analysis also indicated the potential bonding structures of the oxygen fragments removed during surface impingement. Ester- and carboxyl-like structures were predominant among the identified oxygen-containing fragments. The indicated structures are consistent with those characterized by Fanning and Vannice [3] and later incorporated into an oxidation kinetics model by El-Genk and Tournier [4]. Based on the predicted desorption mechanisms of carbon oxides from the identified compounds, it is expected that a majority of the graphite should gasify as carbon monoxide (CO) rather than carbon dioxide ($CO_2$). Therefore, to optimize the efficiency of thermal treatment the graphite should be heated to temperatures above the surface decomposition temperature increasing the evolution of CO [4].

Development of MURCC code for the efficient multi-unit level 3 probabilistic safety assessment

  • Jung, Woo Sik;Lee, Hye Rin;Kim, Jae-Ryang;Lee, Gee Man
    • Nuclear Engineering and Technology
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    • v.52 no.10
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    • pp.2221-2229
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    • 2020
  • After the Fukushima Daiichi nuclear power plant (NPP) accident, level 3 probabilistic safety assessment (PSA) has emerged as an important task in order to assess the risk level of the multi-unit NPPs in a single nuclear site. Accurate calculation of the radionuclide concentrations and exposure doses to the public is required if a nuclear site has multi-unit NPPs and large number of people live near NPPs. So, there has been a great need to develop a new method or procedure for the fast and accurate offsite consequence calculation for the multi-unit NPP accident analysis. Since the multi-unit level 3 PSA is being currently performed assuming that all the NPPs are located at the same position such as a center of mass (COM) or base NPP position, radionuclide concentrations or exposure doses near NPPs can be drastically distorted depending on the locations, multi-unit NPP alignment, and the wind direction. In order to overcome this disadvantage of the COM method, the idea of a new multiple location (ML) method was proposed and implemented into a new tool MURCC (multi-unit radiological consequence calculator). Furthermore, the MURCC code was further improved for the multi-unit level 3 PSA that has the arbitrary number of multi-unit NPPs. The objectives of this study are to (1) qualitatively and quantitatively compare COM and ML methods, and (2) demonstrate the strength and efficiency of the ML method. The strength of the ML method was demonstrated by the applications to the multi-unit long-term station blackout (LTSBO) accidents at the four-unit Vogtle NPPs. Thus, it is strongly recommended that this ML method be employed for the offsite consequence analysis of the multi-unit NPP accidents.

Salting-out extraction of ginsenosides from the enzymatic hydrolysates of Panax quinquefolium based on ethanol/sodium carbonate system

  • Wei, Yingqin;Hou, Baojuan;Fang, Haiyan;Sun, Xinjie;Ma, Feng
    • Journal of Ginseng Research
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    • v.44 no.1
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    • pp.44-49
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    • 2020
  • Background: Salting-out extraction (SOE) had been developed as a special branch of aqueous two-phase system recently. So far as we know, few reports involved in extracting ginsenosides with SOE because of the lower recovery caused by the unique solubility and surface activity of ginsenosides. A new SOE method for rapid pretreatment of ginsenosides from the enzymatic hydrolysates of Panax quinquefolium was established in this article. Methods: The SOE system comprising ethanol and sodium carbonate was selected to extract ginsenosides from the enzymatic hydrolysates of Panax quinquefolium, and HPLC was applied to analyze the ginsenosides. Results: The optimized extraction conditions were as follows: the aqueous two-phase extraction system comprising ethanol, sodium carbonate, ethanol concentration of 41.51%, and the mass percent of sodium carbonate of 7.9% in the extraction system under the experimental condition. Extraction time had minor influence on extraction efficiency of ginsenosides. The results also showed that the extraction efficiencies of three ginsenosides were all more than 90.0% only in a single step. Conclusion: The proposed method had been successfully applied to determine ginsenosides in enzymatic hydrolysate and demonstrated as a powerful technique for separating and purifying ginsenosides in complex samples.

Hydro-elastic analysis of marine propellers based on a BEM-FEM coupled FSI algorithm

  • Lee, Hyoungsuk;Song, Min-Churl;Suh, Jung-Chun;Chang, Bong-Jun
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.6 no.3
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    • pp.562-577
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    • 2014
  • A reliable steady/transient hydro-elastic analysis is developed for flexible (composite) marine propeller blade design which deforms according to its environmental load (ship speed, revolution speed, wake distribution, etc.) Hydro-elastic analysis based on CFD and FEM has been widely used in the engineering field because of its accurate results however it takes large computation time to apply early propeller design stage. Therefore the analysis based on a boundary element method-Finite Element Method (BEM-FEM) Fluid-Structure Interaction (FSI) is introduced for computational efficiency and accuracy. The steady FSI analysis, and its application to reverse engineering, is designed for use regarding optimum geometry and ply stack design. A time domain two-way coupled transient FSI analysis is developed by considering the hydrodynamic damping ffects of added mass due to fluid around the propeller blade. The analysis makes possible to evaluate blade strength and also enable to do risk assessment by estimating the change in performance and the deformation depending on blade position in the ship's wake. To validate this hydro-elastic analysis methodology, published model test results of P5479 and P5475 are applied to verify the steady and the transient FSI analysis, respectively. As the results, the proposed steady and unsteady analysis methodology gives sufficient accuracy to apply flexible marine propeller design.

A Study on the Legal Application for Sport Pilot Certificate in Korea (스포츠조종사 자격증명의 국내 적용에 대한 연구)

  • Noh, Yo-Sup;Kim, Young-Hoon
    • Journal of the Korean Society for Aviation and Aeronautics
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    • v.13 no.3
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    • pp.43-60
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    • 2005
  • In september 2004, a new pilot certificate scheme referred to as Sport Pilot Certificate was declared official and standardized in the US. The designation of Light-sport aircraft and the details of the relevant pilot certificate policy was announced out of the perception that a new regulation is required to be applied whereby the limitations on the manufacturing process enhancements and current aviation rules are considered the triggering factors. US Federal Aviation Regulation retains a comprehensive range of airworthiness certificates and aircrafts are managed systematically in accordance with FAR 21, 103. The airworthiness are further segregated into sub categories, which allows differentiated management. Korean Aviation Law classify aircraft into five different categories and powered air vehicle that weighs more than 150kg(19liters fuel capacity) for one seat, 225kg for two seats(38liters fuel capacity) while the systems that fall under a specific mass threshold level are known as ultralight vehicle. The research discusses the policy of the sport pilot certificate and the light-sport aircraft ratings announced official by the Federal Aviation Administration in an intuitive fashion with the analysis of the operations providing the evidence as to the viability of adopting the policy in local grounds. Based on the findings, the report discusses the case for introducing the light-sport aircraft and make recommendation on a strategy of applying the policy in Korea with respect to the pilot certificates, safety agenda, and the written test for the pilot certificate, and operating efficiency.

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Information Sources and Knowledge on Infant Vaccination according to Online Communities (온라인 커뮤니티에 따른 영.유아 예방접종에 대한 정보습득 경로 및 지식수준 비교)

  • Choi, In-Young;Chung, Mi-Eun;Choy, Soon;Kim, Suk-Il
    • Journal of Preventive Medicine and Public Health
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    • v.40 no.4
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    • pp.291-296
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    • 2007
  • Objectives : To explore the information sources and knowledge on infant vaccinations of pro-vaccination community members and anti-vaccination community members on the internet. Methods : An online survey of 245 parents from three pro-vaccination communities and 92 parents from one anti-vaccination community was conducted from June 7 to June 23, 2006. Results : Parents from pro-vaccination communities usually gained the information regarding vaccination efficacy and risk mainly from healthcare providers (49.8%) and mass media (47.7%). Pro-vaccination community members considered healthcare providers as the most credible sources of information on vaccination, whereas the anti-vaccination community members usually gained their information regarding vaccine efficiency and risk from Internet child-care cafes and online vaccination communities. Parents of the anti-vaccination community considered the internet as the most credible information source (77.6% for efficacy, 94.8% for risk). In addition, the major reason why anti-vaccination community members didn't vaccinate and, will not vaccinate, was concern about possible side effects of the vaccine. The knowledge level on infant vaccination, education and economic status was higher in the anti-vaccination community. Conclusions : On-line communities concerned with vaccination are getting popular. The influence of anti-vaccination parents on the Internet is expected to be high. The government and healthcare providers need to increase their efforts to improve the credibility of information about vaccination. Our findings suggest that online communication regarding vaccinations needs to be considered as a means to increase vaccination rates.

A Time Lag Analysis of R & D Effect ell Total Factor Productivity in Information and Communication Industry (시차분석을 통한 정보통신산업 연군개발투자가 총요소생산성에 미치는 효과 연구)

  • Lee, Kyung-Suk;Park, Myeong-Cheol;Lee, Duk-Hee
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.31 no.2B
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    • pp.154-163
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    • 2006
  • The importance of R & D investment has dramatically been increased as industrial paradigm rapidly changes to knowledge-based economy. In order to preserve recent economic growth and reinforce competitive advantage, government policy and regulatory framework needs to be reshaped in ways that minimize the distorted use of limited resources and maximize the efficiency of R & D investment. In this regards, this paper aims to investigate the influence of R & D investment in national economic growth and to compare the effectiveness of IT R & D investment with other industries, in respect to the time lag.

Effect of High Pressure Carbon Dioxide on Inactivation of Leuconostoc sp. (고압 이산화탄소에 의한 Leuconostoc sp.의 살균 효과)

  • Hong, Seok-In;Park, Wan-Soo;Pyun, Yu-Ryang
    • Korean Journal of Food Science and Technology
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    • v.29 no.6
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    • pp.1202-1207
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    • 1997
  • Inactivation of Leuconostoc sp. isolated from kimchi using carbon dioxide under pressure was investigated in terms of operating parameters in order to evaluate its feasibility as a novel nonthermal process. Inactivation rates increased with increasing pressure, temperature and exposure time, but with decreasing working volume. Microbial reduction of 3 log cycles was achieved within 150 min under a $CO_2$ pressure of $60\;kg/cm^2$ at 30^{\circ}C$. It was confirmed that microbial inactivation by the high pressure $CO_2$ was governed essentially by the characteristic of $CO_2$ mass transfer and thus penetration of $CO_2$, into cells was a rate limiting step to determine efficiency of the inactivation process. The experimental results suggested that the high pressure $CO_2$ treatment could be used as one of the effective nonthermal methods for preserving foods.

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Effect of Initial Volume of Hard Water and Contact Time on the Reduction of Calcium Ion Concentration using High Voltage Impulse Technique (고전압 임펄스 기술을 활용한 경도 제거에서 경수의 초기부피와 인가시간이 칼슘이온 농도에 미치는 영향)

  • Cho, Seung-Yeon;Kim, Tae-Hui;Chang, In-Soung;Hong, Woong-ki;Lee, June-Ho
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.66 no.7
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    • pp.1066-1071
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    • 2017
  • Recently high voltage impulse (HVI) technique has been extensively studied for desalting processes to control the $CaCO_3$ scale formation in industrial water practices such as power plant, boiler, and heat exchange operations. Investigation of the operational parameters for the HVI is important, however, those had not been reported yet. In this study, the effect of initial feed volume and contact time on reduction of calcium ion concentration by the HVI technique was investigated. Initial feed volumes of artificial hard water which contained 100 mg/L of $Ca^{2+}$, were set to 1, 2, and 3 L respectively. After 24hr of HVI contact with 12kV, $Ca^{2+}$ ion was reduced to 50, 29 and 19 % of their initial concentration, indicating that calcium removal increased as initial feed volume decreased. This implies the applied HVI pulse energy per unit mass of calcium is important parameter determining overall desalting efficiency. A series of extended operations of HVI up to 30 days verified the long term stability of the HVI system. The calcium ion declined to 40 mg/L after 2~3 days, and further reduction of calcium was not achieved, indicating that optimum operation time could be 2~3 days under these experimental conditions. Consequently, it was confirmed that the important operational parameter of HVI technique is initial feed volume and contact time as well as the applied voltage that was already proven in the previous study.

A Low-latency L2 Handoff Scheme between WiBro and cdma2000 Mobile Networks (WiBro와 cdma2000 이동통신망간 적은 지연을 위한 L2 핸드오프 방안)

  • Lee, Geon-Baik;Cho, Jin-Sung
    • The KIPS Transactions:PartC
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    • v.13C no.7 s.110
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    • pp.873-880
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    • 2006
  • Since various networks are deployed and the most of users request higher mobility, there are many researches about the interworking between widely deployed 3G network and rapidly boarded WLAN. On the other side, WiBro is focused on as a next generation network, because many people expect that WiBro gives satisfaction about the enough mobility and mass data transmission. So the study of the integration between WiBro and cdma2000 will show better effects than the present study of the integration between WLAN and cdma2000. The L2 handoff proposed in this paper takes advantages over the existing L3 handoff scheme because it does not require the L3 procedure for the mobility unlike the L3 handoff. Through extensive computer simulations, the efficiency of the proposed scheme has been validated.