• 제목/요약/키워드: Mass Distribution

검색결과 2,347건 처리시간 0.041초

The Influence of Mixed Solvents Volatility on Charge State Distribution of Peptides During Positive Electrospray Ionization Mass Spectrometry

  • Nielsen, Birthe V.;Abaye, Daniel A.;Nguyen, Minh T.L.
    • Mass Spectrometry Letters
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    • 제8권2호
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    • pp.29-33
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    • 2017
  • Understanding the mechanisms that control and concentrate the observed electrospray ionisation (ESI) response from peptides is important. Controlling these mechanisms can improve signal-to-noise ratio in the mass spectrum, and enhances the generation of intact ions, and thus, improves the detection of peptides when analysing mixtures. The effects of different mixtures of aqueous: organic solvents (25, 50, 75%; v/v): formic acid solution (at pH 3.26) compositions on the ESI response and charge-state distribution (CSD) during mass spectrometry (MS) were determined in a group of biologically active peptides (molecular wt range 1.3 - 3.3 kDa). The ESI response is dependent on type of organic solvent in the mobile phase mixture and therefore, solvent choice affects optimal ion intensities. As expected, intact peptide ions gave a more intense ESI signal in polar protic solvent mixtures than in the low polarity solvent. However, for four out of the five analysed peptides, neither the ESI response nor the CSD were affected by the volatility of the solvent mixture. Therefore, in solvent mixtures, as the composition changes during the evaporation processes, the $pK_b$ of the amino acid composition is a better predictor of multiple charging of the peptides.

비동질 3중 충돌형 인젝터의 기체-액체 라인 선택에 따른 분무특성 (Mass Distribution and Spray Characteristics to Liquid-Gas Line Selection of Unlike Triplet Impinging Injector)

  • 이인철;이창진;구자예
    • 한국분무공학회지
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    • 제11권4호
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    • pp.205-211
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    • 2006
  • Impinging angle, impinging distance, length eve. diameter and injection pressure of a triplet injector were tested to evaluate the spray characteristics injected by liquid/gas combinations. Two different kinds of unlike triplet sprays were produced by changing the gas and liquid feed lines. One was the G-L-G(Gas-Liquid-Gas) type, and the other was L-G-L(Liquid-Gas-Liquid) type. Spray angles were wider with the G-L-G type than with L-G-L type. Mass distributions in spray were obtained with a, mechanical patternator. Mass distributions were not circular but elliptical distributions. When the range of mechanical patternator to injector decreased, mass distributions were more concentrated in the center region.

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Influence of interaction between coal and rock on the stability of strip coal pillar

  • Gao, W.
    • Geomechanics and Engineering
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    • 제16권2호
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    • pp.151-157
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    • 2018
  • The constrained conditions of roof and floor for the coal pillar affect the strength of coal pillar very seriously. To analyze the influence of rock mass for the roof and floor on the stability of coal pillar comprehensively, one method based on the mechanical method for the composite rock mass was proposed. In this method, the three rock layers of roof, floor and coal pillar are taken as the bedded composite rock mass. And the influence of rock mass for the roof and floor on the elastic core of coal pillar has been analyzed. This method can obtain not only the derived stress by the cohesive constraining forces for the coal pillar, but also the derived stress for the rock mass of the roof and floor. Moreover, the effect of different mechanical parameters for the roof and floor on the stability of coal pillar have been analyzed systematically. This method can not only analyze the stability of strip coal pillar, but also analyze the stability of other mining pillars whose stress distribution is similar with that of the strip coal pillar.

Analysis of nonionic surfactants and silicone polymers in cosmetic products using Matrix - assisted Laser Desorption/Ionization Time-of- flight Mass Spectrometry

  • Lee, Myoung-Hee;Lee, Gae-Ho;Yoo, Jong-Shin
    • 대한화장품학회:학술대회논문집
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    • 대한화장품학회 2003년도 IFSCC Conference Proceeding Book II
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    • pp.480-507
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    • 2003
  • A rapid and efficient method for analyzing the nonionic surfactants and silicone polymers, which control the shape and characteristics of cosmetic products and give influence on product quality, has been developed using Matrix-Assisted Laser Desorption Ionization Time of Flight Mass Spectrometry (MALDI- TOF IMS). The MALDI-TOF/MS could easily and effectively determine the molecular weight distribution and monomer units of nonionic surfactants. As a result, creating a library of mass spectrum data of surfactants used in cosmetic products using MALDI-TOF/MS and analyzing surfactants extracted from the products may become a useful method for detailed structural characterization of the surfactants. Furthermore, the MALDI-TOF/MS analysis was effective in obtaining the spectrum of silicone polymers from which the molecular weight distribution could be determined. The repetition units and structural data could also be obtained through molecular mass peaks. Additionally, the monomer ratio and terminal groups as properties of silicone copolymers could be determined

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Physical Parameters of Late Type Spiral Galaxies - III. Mass and Mass to Luminosity Ratio of NGC 7793

  • Kim, Chang-Ha;Chun, Mun-Suk
    • Journal of Astronomy and Space Sciences
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    • 제3권2호
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    • pp.103-116
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    • 1986
  • The mass distribution and other related quantities were calculated by fitting the observed rotation curve(Davoust and de Vaucouleur 1980) to Brandt and Belton's mass distribution model. One of n values for mass model is determined as 1.5(Vm=95 $kms^{-1}$) and two pairs of them are determined as 0.8(Vm = 95$kms^{-1}$) and 2.0 and 0.8 (Vm = 55$kms^{-1}$) and 2.0 because of the hump in observed rotation curve. Total masses and integrated mass to luminosity ration are $1.8\times10^{10}M_\odot,\;1.5\times10^{10}M_\odot,\;1.4\times10^{10}M_\odot$, and 6.57, 5.33, 5.26 for three cases according to n values. Integrated mass to luminosity ratio in Holmberg radius is 3.44, 3.26, 3.00 in god agreement with the typical value of Sd type suggested by Faber and Gallagher(1979). Presented halo masses which are fifty percent of total masses and halo mass to luminosity ratios given as 75.83, 53.50, 58.75 are values less than Turner's(1976).

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초전도기기를 적용한 미래 저압대용량 신 배전계통 (Future New Distribution System with Low voltage and Mass Capacity using HTS equipments)

  • 윤재영;김종율;이승렬
    • 한국초전도ㆍ저온공학회논문지
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    • 제7권1호
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    • pp.37-41
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    • 2005
  • This paper describes the construction scheme of new distribution system using HTS(High Temperature Superconducting) power equipments such as cable, transformer and FCL(fault current limiter). At present, one of the most serious problems in distribution power system, especially for metropolitan complex city, is to obtain the ROW for cable line routes, space for downtown substations and satisfy the environmental protection caused by NIMBY phenomena. Unfortunately, it is expected that this situation will get more and more worse. As the HTS technology to apply in power system Is developed, HTS cable utilizing mass-capacity characteristic can be a useful countermeasure to overcome this problem. This paper describes the application methodology of 22.9kV HTS cable with low-voltage, mass-capacity characteristics replacing the 154kV conventional cable. By applying 22.9kV HTS cable, the HTS transformer with higher capacity for the reduction of space and transformer numbers of downtown substation is necessary. Also, if the leakage Impedance of HTS transformer is same as or lower than that of conventional transformer, the fault current of 22.9kV bus will increase because the HTS transformer capacity is larger than that of the conventional transformer. This means the parallel application of HTS-FCL to reduce the fault current in addition to the HTS cable and transformer can be necessary. With the basic construction scheme of new distribution system, this paper describes the future study points to realize this new distribution system using HTS equipments.

제주시 도로변에서의 에어로졸의 입경별 분포 특성 (Roadside Aerosols Size Distribution Characteristics in Jeju City)

  • 이기호;김수미;허철구
    • 한국환경과학회지
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    • 제30권9호
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    • pp.727-739
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    • 2021
  • Measurements on mass size distribution of roadside aerosols were obtained in downtown Jeju City from July 2018 to May 2020 using an 8-stage cascade impactor sampler and the compositions of aerosols were analyzed. The mass size distribution of total aerosols was bimodal with aerosols existing in both the fine and coarse modes. The mass size distributions of Na+, Mg2+, Ca2+, Cl-, NH4+ and SO42- were unimodal, whereas that of K+ was bimodal. For NO3-, the size distribution in winter and spring was bimodal with the peaks in both fine and coarse modes, whereas for summer and autumn the distribution was unimodal with a peak in the coarse mode. NH4+ was found to co-exist with SO42- in the fine mode with an average molar ratio of [NH4+]/[SO42-] equal to 2.05. Good correlation was observed between NO3- and NH4+ in the fine mode particles in spring and winter. Based on the value of the marine enrichment factor for Cl-, Mg2+, K+, Ca2+ and SO42-, it may be inferred that a major part of the roadside aerosols in downtown Jeju City was largely contributed by terrigenous sources, although the influence of sea salt was normally present.

A Method of Squeegee pressure Optimization for Mass Production Thick Film Heaters Using SPC and Neural Network

  • Luckchonlatee, Chayut;Chaisawat, Ake
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 2002년도 ITC-CSCC -1
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    • pp.22-25
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    • 2002
  • The Mass production of ceramic heater has encountered with the estimation for the proper parameters of the printing conditions. This paper presents a method to estimate the squeegee pressure. It uses resistance distribution from the trial run with approximate squeegee pressure which comes from statistical process control (SPC). Then, the resistance distribution and its total resistance are input to the backpropagation neural networks that can recognize resistance's distribution patterns. The value of output network derived from the input value can identify to the appropriate squeegee pressure. The experimental results are demonstrated In ensure the efficiency and the reliability of this method with the accuracy 96.75 percent. Indeed, embedded on this method will aid us to reduce the loss from the normal mass production.

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대향류형 보텍스 튜브에서의 형상 변화에 따른 온도 분리에 관한 실험적 연구(I) (An Experimental Study on the Characteristics of Temperature Separation for the Formal Change of Counterflow Type Vortex Tube)

  • 황승식;전운학;김종철;이희상
    • 한국자동차공학회논문집
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    • 제9권1호
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    • pp.84-93
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    • 2001
  • The aim of this study is to provide fundamental informations that make it possible to use a cool stream and a hot stream simultaneously. We changed the pressure of compressed air that flows into a tube, the inner diameter of orifice that a cold stream exits, and the mass flow rate ratio. And in each case, we measured the temperature of a cold stream and a hot stream in each exit of a tube. Also we measured the axial temperature distribution and the radial temperature distribution in internal space of a tube. From the study, following conclusive remarks can be made. Average flow rate that flows into a tube is in proportion to square root of inlet pressure. As inlet pressure increases axial and radial temperature distribution in the inner space of vortex-tube increase. As mass flow rate ratio change, separation point moves.

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초음파 연료분사장치의 분무특성에 관한 연구 (A Study on the Spray Characteristics with Ultrasonic added Fuel Injection System)

  • 윤면근;류정인
    • 한국분무공학회지
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    • 제1권1호
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    • pp.85-91
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    • 1996
  • This experiment was undertaken to investigate spray characteristics of the conventional inject ion system and the ultrasonic energy added inject ion system. Sauter mean diameter was mesured under the variation of inject ion pressure and the spray distance. To measure the droplet size we used the Malvern system 2600C. The spray angle and mass distribution was analyzed to the CCD camera and the patternater. After experiment, it was found that the ultrasonic energy added injection system had smaller sauter men diameter of droplet, wider mass distribution and wider spray angle than the conventional inject ion system had.

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