• Journal of the Mineralogical Society of Korea
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• v.25 no.4
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• pp.271-282
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• 2012

We explore the effect of removal of organic ligand on the atomic configurations around oxygen in hydroxyl groups in amorphous silica gel (synthesized through hydrolysis of $SiCl_4$ in diethyl-ether) using high resolution $^{17}O$ solid state NMR spectroscopy. $^1H$ and $^{29}Si$ MAS NMR spectra for amorphous silica gel showed diverse hydrogen environments including water, hydroxyl groups (e.g., hydrogen bonded silanol, isolated silanol), and organic ligands (e.g., alkyl chain) that may interact with surface hydroxyls in the amorphous silica gel, for instance, forming silica-organic ligand complex (e.g., Si-$O{\cdots}R$). These physically and chemically adsorbed organic ligands were partly removed by ultrasonic cleaning under ethanol and distilled water for 1 hour. Whereas $^{17}O$ MAS NMR spectra with short pulse length ($0.175{\mu}s$) at 9.4 T and 14.1 T for as-synthesized amorphous silica gel showed the unresolved peak for Si-O-Si and Si-OH structures, the $^{17}O$ MAS NMR spectra with long pulse length ($2{\mu}s$) showed the additional peak at ~0 ppm. The peak at ~0 ppm may be due to Si-OH structure with very fast relaxation rate as coupled to liquid water molecules or organic ligands on the surface of amorphous silica gel. The observation of the peak at ~0 ppm in $^{17}O$ MAS NMR spectra for amorphous silica gel became more significant as the organic ligands were removed. These results indicate that the organic ligands on the surface of amorphous silica gel interact with oxygen atoms in Si-OH and provide the information about atomic structure of silanol and siloxane in amorphous silica gel. The current results could enhance the understanding of dehydration mechanism of diverse silicates, which is known as atomic scale origins of intermediate depth (approximately, 70~300 km) earthquakes in subduction zone.

• KOREAN JOURNAL OF CROP SCIENCE
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• v.60 no.3
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• pp.293-299
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• 2015

High temperature is one of major environmental stress. Heat tolerance managing is difficult through the phenotypic selection, so marker assistant selection (MAS) using molecular markers like as RAPD, SSR etc. was tried to select useful traits for heat tolerance. Fourteen SSR markers reported by previous research were selected for this research. We tried to evaluate 14 SSR markers for MAS using 31 useful wheat resources including 24 crossing line from Turkey, six Korean wheat cultivars and Chinese spring. The average of the number of alleles and PIC values in this study were 6.14 and 0.64, respectively. Two major clades and four sub clades were grouped by phylogenetic tree using UPGMA. Four Korean wheat cultivars were distinct from other Turkey resources in the phylogenetic dendrogram. From the results, we expected that these markers were able to adapt to screening wheat genotyping for heat tolerance.

• Journal of the Mineralogical Society of Korea
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• v.22 no.4
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• pp.343-352
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• 2009

High-resolution Solid-state NMR provides element specific and quantitative information and also resolves, otherwise overlapping atomic configurations in multi-component non-crystalline silicates. Here we report the preliminary results on the effect of composition on the structure of CMAS (CaO-MgO-$Al_2O_3-SiO_2$) silicate glasses, as a model system for basaltic magmas, using the high-resolution 1D and 2D solid-state NMR. The $^{27}Al$ MAS NMR spectra for the CMAS silicate glasses show that four-coordinated Al is predominant, demonstrating that $Al^{3+}$ is network forming cation. The peak position moves toward lower frequency about 4.7 ppm with increasing $X_{MgO}$ due to an increase in $Q^4$(4Si) fraction with increasing Si content, indicating that Al are surrounded only by bridging oxygen. $^{17}O$ MAS NMR spectra for $CaAl_2SiO_6$ and $CaMgSi_2O_6$ glasses qualitatively suggest that NBO fraction in the former is smaller than that in $CaMgSi_2O_6$ glasses. As $^{17}O$ 3QMAS NMR spectrum of model quaternary aluminosilicate glass resolved distinct bridging and non-bridging oxygen environments, atomic structure for natural magmas can also be potentially probed using high-resolution 3QMAS NMR.

• Korean Journal of Breeding Science
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• v.41 no.4
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• pp.568-573
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• 2009

A new soybean variety, "Singang", was released by NICS, RDA in 2008. It is resistant to soybean mosic virus (SMV), which is one of the most serious diseases in soybean production. "Singang" had been developed for seven years by molecular marker-assisted selection (MAS) breeding method using recurrent parent, "Sowon", and donor parent, "L29" which has the SMV-resistance gene, Rsv3. Selected promising breeding line, Suwon 242, was evaluated in yield trials for 2 years from 2005 to 2006 at NICS. Regional yield trials were performed for 3 years from 2006 to 2008 in five locations including Jeju. Agronomic characteristics of "Singang" is a determinate growth habit, purple flower color, grey pubescence, yellow testa, light brown hilum and lanceolate leaflet shape. "Singang" showed the similar performance to "Sowon" cultivar. This variety showed 3 days shorter in days to maturity than the check variety (Pungsannamul). The average yield under regional yield trials in five location was 2.78t/ha. It is adaptable to the whole country except for Gangwon province.

• Journal of the Korean Magnetic Resonance Society
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• v.18 no.1
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• pp.41-46
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• 2014

In order to obtain information on the structural geometry of $NH_4HSeO_4$ near the phase transition temperature, the spectrum and spin-lattice relaxation time in the rotating frame $T_{1{\rho}}$ for the ammonium and hydrogen-bond protons were investigated through $^1H$ MAS NMR. $T_{1{\rho}}$ for the hydrogen-bond protons abruptly decreased at high temperature and it is associated with the change in the structural geometry in $O-H{\cdots}O$ bonds. This mobility of the hydrogen-bond protons may be the main reason for the high conductivity.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.5 no.5
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• pp.480-483
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• 2004

Butylene carbonate(4-ethyl-l,3-dioxolan-2-one), one of the cyclic carbonate was synthesized by the thermal degradation of poly(butylene carbonate). The poly(butylene carbonate) was made from 1,2-Epoxybutane and carbon dioxide which is one of the main green house gas. The prepared cyclic carbonate was identified by GC-Mass. This synthetic method is an alternative way to prepare cyclic carbonates.

• The Bulletin of The Korean Astronomical Society
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• v.40 no.2
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• pp.52.2-52.2
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• 2015

SgrA* located in the center of the Milky Way is of great interest to understand the physics of supermassive black hole(SMBH) and the interaction of the G2 cloud around SgrA* with the accretion flow which was expected since 2013. In order to seize this rare opportunity, KVN and VERA Array (so called, KaVA) has started an intensive monitoring program of SgrA* at 22/43 GHz where scatter broadening is reduced compared to lower frequency VLBI observations. We present the results of KaVA SgrA* observation together with Takahagi (32m) and Yamaguchi (32m) telescopes at 22 GHz on March 24, 2013. We have tested both a standard amplitude calibration methods using the Tsys and antenna gain information and a template amplitude calibration method which uses a peak of H2O maser line of nearby maser source (SgrB2), and found that the latter method is useful when an accuracy of Tsys measurement or antenna gain of a telescope is poor. In our comparison, the difference between the two methods is around 20% (~5% for the KVN and ~15% for the VERA when the elevation is above $20^{\circ}$). We also imaged SgrA* with a total flux of ~0.7 Jy at 22GHz, and fitted an elliptical Gaussian model which has a size of ~2.5mas for major axis and ~1.7mas for minor axis, respectively.

• The Bulletin of The Korean Astronomical Society
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• v.40 no.2
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• pp.36.3-37
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• 2015

4C39.25 (0923+392) is a distant radio loud AGN placed at redshift 0.695. The motivation of our work is peculiar properties 4C39.25. Firstly, it has a conspicuous distinction of jet direction between kilo-parsec scale observation made by VLA (Kollgaard et al. 1990) and the parsec scale observation by VLBA (Kellermann et al. 1998). This might indicate episodic-jet activity which recently turned on. This object currently shows two stationary compact parsec-scale components which are bright jet component on east and less luminous core on west. Also, it is known that there have been superluminal jet components which are flowing from the core toward east, and then merging with the bright jet component (Marscher et al. 1991, Alberdi et al. 2000, Lister et al. 2013). Although 4C39.25 seems to be a blazar-like source having broad emission lines (SDSS) and superluminal motion, its property that jet component is brighter than the core is different from ordinary blazars. Furthermore, it has young radio galaxy-like properties such as non-variation in total flux (Alberdi et al. 1997, 2000, MOJAVE database) and high frequency peak at spectral energy distribution (Orienti et al 2007). Such complex properties led us to make recent observations to reveal precise properties and new changes of the source. We used Korean VLBI Network (KVN) and VLBI Exploration of Radio Astronomy (VERA) Array (KaVA) which provide high-frequency (23GHz and 43GHz) and high spatial resolution (1.2mas and 0.6mas). Therefore, this system is suitable for morphological and physical research on parsec scale structure. We present results for several epochs observed during 2013 to 2014, mainly focusing on morphological changes of 4C39.25 using KaVA images.

• Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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• v.27 no.1
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• pp.693-700
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• 2009

For real-time precise GPS data processing such as a long baseline network RTK (Real-Time Kinematic) survey, PPP (Precise Point Positioning) and monitoring of ionospheric/tropospheric delays, it is necessary to guarantee accuracy comparable to IGS (International GNSS Service) precise orbit with no latency. As a preliminary study for determining near real-time satellite orbits, the general procedures of satellite orbit determination, especially the dynamic approach, were studied. In addition, the transformation between terrestrial and inertial reference frames was tested to integrate acceleration. The IAU 1976/1980 precession/nutation model showed a consistency of 0.05 mas with IAU 2000A model. Since the IAU 2000A model has a large number of nutation components, it took more time to compute the transformation matrix. The classical method with IAU 2000A model was two times faster than the NRO (non-rotating origin) approach, while there is no practical difference between two transformation matrices.

• Korean Journal of Biological Psychiatry
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• v.15 no.2
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• pp.92-100
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• 2008

Objectives : The purpose of this study was to investigate 1) the neuropsychological deficits with major depressive disorder(MDD) in depressed state and 2) the changes of neuropsychological dysfunctions during depressed episodes and remitted periods in the MDD group. Methods : 12 patients with MDD and 70 normal controls who were diagnosed and classified by DSM-IV and SCID-IV interview participated in this study. The psychopathology was measured using the Hamilton rating scale for depression(HAM-D) and Brief Psychiatric Rating Scale(BPRS). The memory function, executive function, and sustained attention were measured by a trained psychologist using the Korean version of Memory Assessment Scale(K-MAS), Wisconsin Card Sorting Test(WCST), and Vigilance(VIG) and Cognitrone (COG) in Vienna Test System. After 6 weeks of treatment, we retested the cognitive tests in order to measure the cognitive functions in remitted states. Results : Patients with MDD achieved significantly lower score in sentence immediately recall, verbal memory score and total memory score of the K-MAS, total errors of the WCST, response time of Vigilance and response time at "Yes" response of Cognitrone than normal controls at baseline. After 6 weeks of medication, the psychiatric symptoms in the patient group were attenuated, and most of the neuropsychological functions including attention, memory, and frontal/executive function were improved except for response time of Cognitrone. Conclusions : This study provides evidence for distinct neuropsychological deficits in patients with MDD on their depressed states and remitted periods. The impairment on response time remains after remission, and this would be a trait marker of major depressive disorder.