• Journal of the Korean Magnetic Resonance Society
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• 제14권1호
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• pp.38-44
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• 2010

In liquids NMR, $^{1}H$ is the most widely observed nucleus, which is not the case in solids NMR. The reason is due to the strong homo-dipolar interactions between the hydrogen atoms which mask the useful chemical shift information. Therefore we must remove the strong homo-dipolar interactions in order to get structural information, which can be investigated by the isotropic chemical shift. There are two ways of obtaining it. One is the ultra-fast MAS of ca. 70 kHz spinning speed, which has become available only recently. The other way is devising a pulse sequence which can remove the strong homo-dipolar interaction. In the latter way, MAS with a moderate spinning rate of a few kHz, is enough to remove the chemical shift anisotropy. In this report, 1D-CRAMPS and 2D MASFSLG techniques are utilized and their results will be compared. This kind of highresolution $^{1}H$ NMR for solids, should become a valuable analytical tool in the understanding and the developing of a new class of hydrogen storage materials. Here ammonium borane $-NH_{3}BH_{3}$, whose hydrogen content is high, is used as a sample.

• Journal of the Korean Institute of Intelligent Systems
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• 제17권1호
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• pp.80-85
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• 2007

As home network system begins serving in earnest, the recent fruits of research in home service robot show that the new epoch that human and intelligent robots are living, communicating and interacting together at home, may come true in the near future. In the other hand, it is generally known that the multiagent system, performing distributed process together with other different devices in a home network system, is better than single robot or single home server for adapting themselves to home environment and completing their mission because the characteristic of home environment is 'open'. Therefore, in this paper we suggest the framework model to define agents, which is needed lot the home with a home network system, and the communication protocol architecture between agents. For this, we focus our attention on an agent comprising the set of many agent instances rather than the single intelligent or ability of a robot or home server, and also suggest the way of adaptation for agent systems to their environments and interaction with human in the manner of cooperation and negotiation among agents or agent instances in each agent.

• The Bulletin of The Korean Astronomical Society
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• 제42권1호
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• pp.28.3-29
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• 2017

We present the results of very long baseline interferometry (VLBI) observations of gamma-ray bright blazar S5 0716+714 using the Korean VLBI Network (KVN) at the 22, 43, 86, and 129 GHz bands, which are part of the KVN key science program known as the Interferometric Monitoring of Gamma-ray Bright AGNs (iMOGABA). Multi-frequency VLBI observations were conducted in 29 sessions from January 16, 2013 to March 1, 2016. The source was detected and imaged in all available frequency bands. For all observed epochs, the source is compact on the milliarcsecond (mas) scale, yielding a compact VLBI core dominating the synchrotron emission on the mas scale. Based on the multi-wavelength data at 15 and 230 GHz, we found that the source shows multiple prominent enhancements of the flux density at the centimeter (cm) and millimeter (mm) wavelengths, with mm enhancements leading cm enhancements with a time lag of $18{\pm}5$ days. Turnover frequency is found to vary over our observations between 22 to 69GHz. Taking into account the synchrotron self-absorption model of the relativistic jet in S5 0716+714, we estimated the magnetic field strength in the mas emission region to be 0.4-66 mG during the observing period, finding that the magnetic field strength is strongly correlated with the turnover frequency and the relatively strong magnetic field (e.g., B > 40 mG) is correlated with flux enhancements at mm wavelengths (e.g., 86 GHz).

• Analytical Science and Technology
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• 제17권2호
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• pp.173-179
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• 2004

The $BaTiO_3$ powders and thin films were prepared by an alkoxide modified sol-gel process (polymerization-complex route) using ethylene glycol. The stable starting (Ba-Ti)-mixed metal organic sol was made by addition of acetylacetone. The $BaTiO_3$ powders, which had a particle size of 40~77 nm, were crystallized from an amorphous to a tetragonal phase on annealing at 700 and $1100^{\circ}C$ for 1 h. From FT-IR, solid-state $^{13}C$ CP/MAS NMR spectroscopy and X-ray diffractometry, the trace of the Ba-Ti-oxycarbonate phase first appeared at $400^{\circ}C$. Hydrolyzed sol was spin coated on a quartz wafer at 3500 rpm for 60 s and pyrolyzed at $1100^{\circ}C$ for 1 h. After heat treatment, the coated layer became dense and smooth.

• Bulletin of the Korean Chemical Society
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• 제30권1호
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• pp.149-152
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• 2009

Hydrotalcites are anionic clays that are quite prevalent in nature and their importance is growing more and more because of their very wide range of potential applications and uses. Understanding the structural and compositional changes that occur on the molecular scale during the thermal decomposition of hydrotalcite compounds is essential for the basic prediction and comprehensive understanding of the behavior and technical application of these materials. In this study, several hydrotalcite compounds calcined at different temperatures for applications in a chlorine resistant textile were prepared and 27-Aluminm solid-state nuclear magnetic resonance (NMR) spectroscopy was used as a tool to study their local structure and behavior. The changes in the Al coordination of the hydrotalcite compounds were investigated with one dimensional (1D) solid-state magic angle spinning (MAS) NMR spectroscopy. The two broad resonances arising from the structurally different Al coordinations of these compounds were clearly resolved by two dimensional (2D) triple quantum magic angle spinning (3QMAS) NMR spectroscopy.

• Journal of Life Science
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• 제19권1호
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• pp.152-155
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• 2009

The old-gold-crimson ($og^c$) fruit color mutation produces deep red tomato fruit with high lycopene content. age is a null mutation allele of lycopene-${\beta}$-cyclase (Crt-b) gene (B locus) that converts lycopene to ${\beta}$-carotene in the cartenoid biosynthesis pathway in tomato. Breeding of high lycopene tomato cultivars can be accelerated by marker-assisted selection (MAS) for introgression of $og^c$ allele by using a gene-based DNA marker. In order to develop a marker, single nucleotide deletion of adenine(A) with. in a poly-A repeat that has been known to be responsible for frame-shift mutation of $og^c$ was confirmed by resequencing mutant allele and wild-type allele at B locus of several tomato lines. For allele discrimination and detection of $og^c$, derived CAPS (dCAPS) approach was used by designing a primer that artificially introduced restriction enzyme recognition site of Hin fI in PCR products from $og^c$ allele. This dCAPS marker is co-dominant gene-based PCR marker that can be efficiently used for MAS breeding program aiming the development of high lycopene tomato.

• Clean Technology
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• 제14권3호
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• pp.166-170
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• 2008

In this study, imidazolium salt ionic liquid on amorphous silica was prepared and its catalytic performance in the cycloaddition of $CO_2$ with allyl glycidyl ether (AGE) to produce heterocyclic carbonate was investigated. The ionic liquid was generated on chloropropyl functionalized silica through the immobilization of imidazole. The prepared catalyst was characterized using a number of instrumental analysis including XRD, BET, $^{29}Si$ MAS-NMR and SEM. $^{29}Si$ MAS-NMR showed that the ionic liquid formed adduct with the chloropropyl groups attached to the silica surface. The immobilized ionic liquid showed very good catalytic activity for the cycloaddition of $CO_2$ with AGE, showing 55-61% of AGE conversion with over 85% of the carbonate selectivity at $80-120^{\circ}C$. Its AGE conversion and selectivity to the carbonate were even higher than the homogeneous analog, 1-n-butyl-3-methyl imidazolium bromide (BMImBr).

• Journal of the Korean BIBLIA Society for library and Information Science
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• 제6권1호
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• pp.47-80
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• 1984

The aim of this paper is to study the classification and arrangement system, the original texts, and the bibliographic deseription of Dae-Jang-Mock-Lock. The results of this study can be summarized as followings; 1. The first carving of Dae-Jang-Mock-Lock was assumed to be completed at latest by 1087 (King Sun-Jong 4, Koryo) when the first carving of Dae-Jang-Kyong, the complete collection of Buddhist Sutra, mas finished. Henee, Dae-Jang-Mock-Lack is safely said to be the oldest catalog in Korea. 2. The major function of Dae-Jang-Mock-Lock mas to facilitate the job of printing, managing, or arranging the Sutra tablets, rather than to serve as its references. 3. Dae-Jang-Mock-Lock mas classified in accordance with the classification sys tern of Gae-Woon-Suck-Kyo-Lock, a chinese Buddhist catalog. This system classified the complete collection of Buddhist Sutra into the three categories of "Mah$\={a}$y$\={a}$na Tripitaka", "Hinayan$\={a}$ Tripitaha", and "collected Biographies of Samgha", at the first gradation. And then the Mah$\={a}$yan$\={a}$ Tripitaka mas divided into the three categories of "Mah$\={a}$y$\={a}$na Sutra", "Mah$\={a}$y$\={a}$na Uparaksa", and "Mah$\={a}$y$\={a}$na Upadesa", at the second gradation. In the same manner the "Hinayan$\={a}$ Tripitaka was divided into "Hinayan$\={a}$ Sutra", "Hinayan$\={a}$ Uparaksa", and "Hinayan$\={a}$ Upadesa". The "Collected Biographies of Samgha" was divided into Brahman Samgha and Chinese Samgha. For this reason we Can name this main classification system as a Tripitaka Classification. 4. The first carving tablets of the Buddhist Sutra from Choen Shelf (天函) to Young Shelf (英函) were the same Sutra that were included in Gae-Woen-Suck-Kyo-Lock (開元釋敎錄), except those 4 omitted sutras of 22 volumes. But the other 7 sutras of 24 volumes were included as an extra addition in "Dae-Jang-Mock-Lock." 5. The 40 shelves and 376 volumes of Buddhist Sutra from the Doo Shelf (杜函) to the Kyong Shelf (輕函) in Dae-Jang-Mock-Lock were copied from the texts of Guran Edition (契丹本) 6. The 36 shelves of Buddhist Sutras from the Bun shelf (磻函) to the Mil shelf (密函) in Dae-Jang-Mock-Lock were the same as those included in Sock-Jung-Woen-Suck-Kyo-Lock (續貞元釋敎錄), except the 3 omitted sutras.

• Proceedings of the KOR-BRONCHOESO Conference
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• 대한기관식도과학회 1982년도 제16차 학술대회연제순서 및 초록
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• pp.13.1-13
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• 1982

Cysticercosis is not likely to be the first diagnosis the otologist has in the head and neck area. The fact that this disease may present a diagnostic and therapeutic problem is illustrated by one case, appearing in the face of right side. The local finding of a soft nontender mass, the typical calcifications in the soft tissues visible on roentgenograms, and the histopathological findings are described and illustrated. Attention is drawn to the fact that cerebral cysticercosis, which is a very grave disease, may cause tinnitus, nystagmus, and hearing disturbances. Recently, the authors have experienced a case of cysticercosis on the face in a 24-year-old male patient. We present this case with a brief review of the literatures.

• Journal of Korean Physical Therapy Science
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• 제4권4호
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• pp.539-548
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• 1997

The purpose of this study was to determine the effects of FES on the clinical test patients who had disturbance gait due to cereberal vascular accident. The subjects for study were 16 hemiplegic patients (9 Male and 7 Female) who can gait with or without device. Their average age was 55 and they received average of 20.19 month of treatment collected data analysis was completed by using one-way analysis variable(ANOVA), Pearson ($-1{\leq}r{\geq}1$). The results were as follows : 1) There was difference in four variable (stride length,gait speed,gait cadence) between at the biginning and at the end of the treatment of FES (p<0.01). 2) There was relationship in capacity of activity between MAS and stride length (r = 0.751), gait speed (r = 0.689) but no relationship gait cadence (r = 0.236). 3) Age revealed relationship of stride length (r = -0.727), gait speed (r = -0.725), gait cadenc (r = -0.362). 4) There was no relationship in months post-CVA with MAS (r = 0.171), stride length (r = -0.110), gait speed (r = -0.096), gait cacedce (r = -0.154).