• 신재생에너지
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• 제4권4호
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• pp.56-64
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• 2008

Anaerobic biodegradability (AB), which can be determined with the ultimate methane yield by the decomposition of organic materials, is one of the important parameters for the design and the operation of anaerobic digestion plant. In this study, Biochemical methane potential (BMP) test has been carried out to evaluate the methane yields of animal manures such as pig and cattle slurries, and different forage crops cultivated at the reclaimed tideland such as maize, sorghum, barley, rye, Italian ryegrass (IRG), rape, rush, and waste sludge produced from slaughterhouse wastewater treatment plant (SSWTP). In the ultimate methane yield and biodegradability of animal manure, those of pig slurry were 345 $mlCH_4/gVS_{fed}$ and 44.7% higher than 247 $mlCH_4/gVS_{fed}$ and 46.4% of cattle slurry (Cat. 2). The ultimate methane yield and biodegradability of spike-crop rye (Rye 1) were 442.36 $mlCH_4/gVS_{fed}$ and 86.5% the highest among different forage crops, those of the other forage crops ranged from 306.6 to 379 $mlCH_4/gVS_{fed}$ of methane yield with the AB having the range of about 60 to 77%. Therefore the forage crops could be used as a good substrate to increase the methane production and to improve the biodegradability in anaerobic co-digestion together with animal manure.

• 한국작물학회:학술대회논문집
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• 한국작물학회 2017년도 9th Asian Crop Science Association conference
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• pp.137-137
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• 2017

Rice has important role as a primary food resource in especially the Asia, Korea, China, India, Indonesia and Japan. After development and increasingly using artificial chemical fertilizer, rice is getting high quality and quantity to satisfy ever-increasing people. On the other hand, the earth environment is more polluted each day. Nowadays consumers are looking for the organic crops or foods that were grown with eco-friendly method and in pure farmland. With the immergence of this trend, it is time to development environmentally-friendly agriculture. One of the methods is growing green manure crops in winter or spring on the fields. For this reasons, growing rye and Italian ryegrass are useful to use green manure to enhance rice production without chemical fertilizers and make the property of the soil eco-friendly. To know how improve the quality and quantity of rice with green manures, rye and Italian ryegrass, first the characteristics of green manure corps were measured. Dry matter yields of the rye and Italian ryegrass were 2.21 and $1.81t\;Ha^{-1}$. And the percentages of the dry matter were 28 and 32%. And, analyzed mineral components in rye and Italian ryegrass were nitrogen, organic matter, $P_2O_5$, CaO, $C_2O$ and MgO. Specially, the percentages of the organic matter and the CaO between rye and Italian ryegrass have difference appreciably. the height of the rice on the Italian ryegrass-fertilized field was the highest among the variant fields. The height of the rice on the non-fertilized field was the lowest. Yield of the Italian ryegrass-, rye- and non-fertilized rice are 805.2, 639.9 and $415.3kg\;10a^{-1}$. At the result, Italian ryegrass is the most effective green manure among the 3 treated-fertilized.

• 한국유기농업학회지
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• 제19권4호
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• pp.543-551
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• 2011

This study was conducted to evaluate nutrient production of both orchardgrass and several clovers as a green manure in a 'Niitaka' pear (Pyrus pyriforia) orchard. The experiment was conducted at diligent farmer in Boseong in Chonnam on March 26 of 2010, and the treatments included; 1) orchard grass (2.0kg/$1,000m^2$), 2) orchard grass (1.0kg/$1,000m^2$)+ladino clover (1.0 kg/$1,000m^2$), 3) orchard grass (1.0kg/$1,000m^2$)+red clover (1.0kg/$1,000m^2$), and 4) orchard grass (1.0kg/$1,000m^2$) +white clover (1.0kg/$1,000m^2$). Lengths of orchardgrass and clovers were greater in July than those of June and September. Seeding of orchardgrass without clovers in June and July increased dry weight of green manure crops compared with the seeding of orchardgrass with clovers, resulting in greater annual total dry weight. Various green manure treatments produced different amounts of total N and $P_2O_5$ from each raw materials and did not satisfy amounts of those nutrients for proper annual growth of ten- to twelve-year-old pear tree. Amounts of $K_2O$ producing from green manures, however, satisfied for proper growth of the pear trees.

• 한국물환경학회지
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• 제32권6호
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• pp.670-699
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• 2016

In this study, 16 antibiotics were selected from among the top 30 veterinary antibiotics sold in South Korea in 2014, as well as from among the pharmaceuticals targeted by EPA method 1694, in order to review analytical methods for the detection of trace levels of antibiotics in environmental samples: surface water, soils, animal origin foods, and manures. LC-MS/MS was heavily used. In the chromatography for the detection of the selected antibiotics, the $C_{18}$ column was mostly used at the temperature of $30{\sim}40^{\circ}C$. Water and methanol/acetonitrile were commonly chosen as a nonpolar and a polar mobile phase, respectively. Gradient elution was applied to separate multiclass antibiotics. Volatile additives, such as formic acid, acetic acid, and ammonium acetate were mixed with the mobile phase to improve the ionization efficiency of analytes and the sensitivity in MS detection. Electrospray ionization (ESI) was widely used in the LC-MS/MS and positive ionization was preferred to determine the selected antibiotics. A protonated $[M+H]^+$ molecule was selected as a precursor ion, and its two transitions were analyzed, one for quantitative measurement and the other for confirmation. This study reviewed linearity of the calibration curve, recovery, repeatability, method detection limits (MDLs), and method quantification limits (MQLs) for each target compound used to validate the developed analytical methods.

• Asian-Australasian Journal of Animal Sciences
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• 제26권6호
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• pp.864-873
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• 2013

In developing countries, biogas energy production is seen as a technology that can provide clean energy in poor regions and reduce pollution caused by animal manure. Laboratories in these countries have little access to advanced gas measuring equipment, which may limit research aimed at improving local adapted biogas production. They may also be unable to produce valid estimates of an international standard that can be used for articles published in international peer-reviewed science journals. This study tested and validated methods for measuring total biogas and methane ($CH_4$) production using batch fermentation and for characterizing the biomass. The biochemical methane potential (BMP) ($CH_4$ NL $kg^{-1}$ VS) of pig manure, cow manure and cellulose determined with the Moller and VDI methods was not significantly different in this test (p>0.05). The biodegradability using a ratio of BMP and theoretical BMP (TBMP) was slightly higher using the Hansen method, but differences were not significant. Degradation rate assessed by methane formation rate showed wide variation within the batch method tested. The first-order kinetics constant k for the cumulative methane production curve was highest when two animal manures were fermented using the VDI 4630 method, indicating that this method was able to reach steady conditions in a shorter time, reducing fermentation duration. In precision tests, the repeatability of the relative standard deviation (RSDr) for all batch methods was very low (4.8 to 8.1%), while the reproducibility of the relative standard deviation (RSDR) varied widely, from 7.3 to 19.8%. In determination of biomethane concentration, the values obtained using the liquid replacement method (LRM) were comparable to those obtained using gas chromatography (GC). This indicates that the LRM method could be used to determine biomethane concentration in biogas in laboratories with limited access to GC.

• 한국산업보건학회지
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• 제26권2호
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• pp.170-177
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• 2016

Objectives: This study was conducted to evaluate the total heavy metals contents and chemical forms in the animal manure compost. Materials and methods: A total of 109 compost samples were collected throughout the country and classified into three groups in accordance with the raw materials; pig manure, poultry manure and mixed(pig+poultry+cattle) manure. The compost samples were analyzed for total metal content and sequential chemical extraction to estimate the quantities of metals. Results: Concentrations of Zn and Cu in several compost samples were higher than the maximum acceptable limits by the Korea Compost Quality Standards. Concentrations of Zn, Cu, and Cd in compost samples were 257~5,102, 68~1,243, and 0.02~2.54 mg/kg respectively, while Cr, Ni, As, and Pb were < 20 mg/kg. The concentrations of heavy metals in pig manure compost were higher than those of both the poultry and the mixed manure compost. The predominant forms for extracted metals were Cr, Ni, Zn, As, and Pb, residual; Cu, organic; and Cd, carbonate. Conclusions: Results indicate that the Zn and Cu contents in compost were higher than other heavy metals and the heavy metal contents were greater in pig manure compost followed by mixed and poultry manure compost. To prevent the accumulation of heavy metals in soil where animal manure compost is applied, strategy for reducing heavy metal concentrations in animal manure and compost must be considered.

• 한국축산시설환경학회지
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• 제1권1호
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• pp.65-75
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• 1995

This experiment was carried out to the effects of population density and C/N ratios of feed on the growth, reproductive effciency and cast producation of the earthworm(Eisenia foetida). The population densities of 50, 100, 150, 200 and 250 individuals of the earthworm fed with different C/N ratios of 25, 35, 45 and 55 cow manures were studied in rearing box($6,400cm^3$), and at the fertility stage during a period of 60 days. The results were summarized as follows; The survial rate(SR), increasing rate(IR), reproductive efficiency(RE) and cast production of the earthworms showed highest values in C/N ratio of 25. These results may indicate that C/N ratio of 25 is a very favourable feed for the growth of the earthworms. The survial rate(SR) indicated significant positive correlation with reproductive efficiency(RE) in different C/N ratios of feeds. The survial rate(SR) showed highest values in population densities of $50{\sim}100$ worms/$6,400cm^3(64.0{\sim}128.0cm^3/worm$). On the contrary, increasing rate(IR) tended to decreased with the increased population densities. The survival rate(SR) indicated significant negative correlation with reproductive efficiency(RE) in different population densities of the earthworms. The cast production estimated were $31.6mg{\sim}67.4mg/day/worm$ grown in optimum population densities($50{\sim}100\;worms/6,400cm^3$). The earthworm casting are an excellent soil conditioning material or organic fertilizer sources with a high chemical composition and their physical properties.

• 한국초지조사료학회지
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• 제20권1호
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• pp.41-48
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• 2000

This study was conducted to investigate the effects of the application rate of fermented swine manure and additional mineral fertilizer on productivity and nutritive value of corn(Zea mays L.) for silage. Swine manures used in this study were the compost of swine manure fermented with sawdust(SMFWS) and swine sluny(SS). This study was arranged in split-split plot design. Main plots were the types of swine manure, subplots were the application rate of swine manure, such as 100, 200 and 400kgN/ha, and sub-subplots were the application rate of mineral fertilizer, such as 50 and 100kgNiha. Corn DM(dry matter) and TDN(tota1 digestible nutrient) yields increased as application rate of SMFWS and SS increased. DM and TDN yields in SS treatments were higher than those in SMFWS treatments. The effect of fermented swine manure improved positively as application rate of urea increased. Net energy for lactation(NE1) and TDN content in corn decreased as application rate of SMFWS and SS increased, but crude protein(CP) content increased by the application of SMFWS and SS. NE, and TDN contents in SMFWS treatments were lower than those in SS treatments, but CP content in SMFWS was higher than that in SS. The growth and nutritive value of corn were improved by the application of mineral fertilizer. (Key words : Swine manure, Swine sluury, Compost, Zea may, TDN, Net energy)

• 한국초지조사료학회지
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• 제35권3호
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• pp.212-216
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• 2015

This study was conducted to assess the efficacy of slurry acidification in reducing ammonia emission from manure storage and application. The non-fermented cattle manure (NFC) and swine slurry (SS) were acidified by sulfuric acid and stored in an acryl chamber for 168 and 96 hours, respectively. Ammonia emitted from the chamber was collected using an acid trap system. The amount of ammonia emission was significantly reduced when the livestock manures were treated with sulfuric acid. The absolute amount of ammonia in NFC increased rapidly starting from 48 h and 72 h in the control (pH 8.6) and acidified NFC (pH 6.5), respectively. The absolute amount of ammonia was the highest at 96 h ($3.65g\;kg^{-1}h^{-1}$) in the control and at 144 h ($2.34g\;kg^{-1}h^{-1}$) in pH 6.5 NFC. The cumulative ammonia content in the control continuously increased until 96 h and was maintained until 168 h, whereas the increase rate of emission gas accumulation in acidified NFC was much less throughout the experimental period. Acidification of SS mitigated ammonia emission as proven in NFC. The cumulative amount of ammonia emission was decreased by 49.4% and 92.3% in the acidified SS at pH 6.5 and pH 5.5, respectively, compared to the control at 96 h after treatment. These results indicate that ammonia emission can be significantly reduced by sulfuric acid treatment of livestock manure during processing and the subsequent land application.

• 한국물환경학회지
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• 제33권5호
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• pp.546-555
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• 2017

The Nutrient budget is one of the agricultural-environment indicators of OECD. A nutrient budget measures the surplus as the differential between the inputs and the outputs of within a certain boundary and within a specified period of time (i.e. one year). According to OECD, the annual nitrogen budget for Korea was $245kg\;N\;ha^{-1}$ in 2014, which corresponds to the first position among OECD countries. In Korea in 2014, about 90 % of livestock excreta was composted as solid and liquid manure, which are usually and customarily spread on agricultural land. The objectives of this study are intended to suggest methodology of the regional nitrogen budget as a nitrogen management tool, which considers conversion from raw excreta to composted manures based on the methodology of OECD/Eurostat, and application of the new method in an agricultural region of Korea. As a result, the calculated excess rate of hydrospheric nitrogen surplus was $251kg\;N\;ha^{-1}$ (in the region in 2014), which indicates the presence of potential risks emanating from excessive nitrogen, with regard to both export water and soil environments. The findings also assert that this was shown to be one of the most important elements in the nitrogen budget, which translates to the actual amounts of nitrogen lost during the solid composting process. To better understand the process and the reliability of the method, it is necessary to analyze the sensitivity of the relevant co-efficients used in the method in the near future.