• 한국해양학회지
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• v.26 no.1
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• pp.1-12
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• 1991

A multi-disciplinary geophysical study including gravity, magnetic, and seismic reflection profiling was carried out in the area between the Clarion fracture zone and the Clippertone fracture zone o the northeastern equatorial Pacific basin. There are small free-air gravity anomalies of less than 20 mgal over seamounts and the east-west trending abyssal hills. The negative residual gravity anomalies over seamounts may indicate the existence of low density seamount roots compared to surrounding oceanic crust. Non-existence of magnetic lineations and the magnetic anomalies of small smplitude with no polarity change in the east-west direction support that the study area belongs to the Cretaceous magnetic quite zone. Positive magnetic anomalies over seamounts offset 100 km in the east-west direction in the southern part of the study area suggest a possibility of left-lateral movement of those seamounts along unknown fractures. The sedimentary section in the study area can be divided into three units (Unit I, unit IIA, and Unit IIB) n the basis of reflection characteristics. the total thickness of sedimentary section varies from 200 to 400 meters and the sedimentary section is thicker in the southern area of rough topography near the seamount belt than in the northern flat area. Manganese nodules are abundant in the southern part of the study area where the ridges are developed and the Unit I layer is thicker than 100 meters.

• Korean Journal of Soil Science and Fertilizer
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• v.32 no.4
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• pp.327-332
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• 1999

Manganese (Mn) oxides in soils have been a research subject since they react with nutrients and contaminants and Mn itself is an essential element for plant growth. Birnessite was synthesized in the presence of iron (Fe) in the precipitating solution. Influence of Fe, one of common elements in soils, on crytallinity, morphology, and chemical reactivity of birnessite was examined using X-ray diffraction (XRD), electron microscope, canon exchange capacity (CEC), and chromium (Cr) oxidation capacity. With increasing Fe concentration in the precipitating solution, crystallinity and crystal size decreased. Hexagonal plates of the birnessites formed at low Fe concentration were dominant and replaced more and more by aggregate of small particles with increasing the Fe concentration. There is no significant change in CEC with changing the Fe concentration. Chromium oxidation capacity of the birnessite increased with increasing the Fe concentration. Iron in the precipitating solution poisoned crystal growth by adsorption on the surface and increased nucleation. Since Fe is a common constituent under pedogenic environment and Fe and Mn oxides often coexist in Mn oxide nodules, the birnessite with small particle, low crystallinity, and high chemical reactivity is the form which is more likely to be formed in soils. The high CEC ($140cmol_ckg^{-1}$) and oxidation capacity of birnessite indicate that birnessite can be used in environment and agriculture.