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Analysis on the Heat Exchange Efficiency of Kraft Recovery Boiler by Nose Arch Structure Using CFD (CFD를 활용한 크래프트 회수보일러 내부 노즈 아치 구조에 따른 열교환 효율 분석)

  • Jang, Yongho;Park, Hyundo;Lim, Kyung pil;Park, Hansin;Kim, Junghwan;Cho, Hyungtae
    • Applied Chemistry for Engineering
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    • v.32 no.2
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    • pp.149-156
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    • 2021
  • A kraft recovery boiler produces steam for power generation by the combustion of black liquor from the kraft pulping process. Since saturated steam became superheated in a superheater above the furnace, it is important to increase the heat exchange efficiency for the superheated steam production and power generation. A nose arch at the bottom of the superheater is important for blocking radiation from the furnace which causes corrosion of the superheater. But the nose arch is the main reason for creating a recirculation region and then decreasing the heat exchange efficiency by holding cold flue gas after the heat transfer to saturated steam. In this study, the size of recirculation region and the temperature of flue gas at the outlet were analyzed by the nose arch structure using computational fluid dynamics (CFD). As a result, when the nose arch angle changed from 106.5° (case 1) to 150° (case4), the recirculation region of flue gas decreased and the heat exchange efficiency between the flue gas and the steam increased by 10.3%.

Anti-Aspergillus Activities of the Ligusticum chuanxiong Essential Oil Alone and in Combination with Antibiotics

  • Sim, Youn;Shin, Seung-Won
    • Natural Product Sciences
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    • v.16 no.3
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    • pp.175-179
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    • 2010
  • The present study aimed to assess the antifungal properties of the essential oil fraction from Ligusticum chuanxiong (Umbelliferae) and its components against five clinically important Aspergillus species. The essential oil fraction was extracted from the underground parts of the plant by steam distillation, and its main components, namely, Z-ligustilide, butylidene phthalide, and p-cresol were isolated by column chromatography. The antifungal activities of the essential oils were evaluated by the broth dilution method. Both the total essential oil fraction of L. chuanxiong and its components showed significant anti-Aspergillus activity against all five tested strains with MICs between 62.5 and 250 ${\mu}g$/ml, respectively. In a checkerboard microtiter assay, the combination of antibiotics, itraconazole with the essential oil fraction of L. chuanxiong or its main components exhibited synergistic or additive, and in some cases indifferent, effects against the tested Aspergillus species, resulting in FICIs (fractional inhibiting concentration indices) ranging from 0.12 to 2, while the combination of antibiotics, amphothericin B with L. chuanxiong essential oils mostly showed antagonistic effects.

A Fundamental Study on Supercritical CO2 Curing of Resource-Recycling Concrete Containing Concrete Sludge Waste as Main Materials (레미콘 슬러지 고형분을 주재료로 한 자원순환형 콘크리트의 초임계 CO2 양생에 관한 기초적 연구)

  • Sim, Sang-Rak;Lee, Young-Do;Ryu, Dong-Woo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2022.11a
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    • pp.27-28
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    • 2022
  • In this study, the mechanical properties of resource-recycling concrete containing concrete sludge waste as main materials was compared depending on whether supercritical CO2 curing was applied for the realization of CCU technology. After supercritical CO2 curing, the compressive strength of the steam-cured specimen was lowered, but it was confirmed that the compressive strength of the underwater-cured specimen was improved.

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Preparation of 27Ni6Zr4O143M(M=Mg, Ca, Sr, or Ba)O/70 Zeolite Y Catalysts and Hydrogen-rich Gas Production by Ethanol Steam Reforming

  • Kim, Dongjin;Lee, Jun Su;Lee, Gayoung;Choi, Byung-Hyun;Ji, Mi-Jung;Park, Sun-Min;Kang, Misook
    • Bulletin of the Korean Chemical Society
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    • v.34 no.7
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    • pp.2073-2080
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    • 2013
  • In this study the effects of adding alkaline-earth (IIA) metal oxides to NiZr-loaded Zeolite Y catalysts were investigated on hydrogen rich production by ethanol steam reforming (ESR). Four kinds of alkaline-earth metal (Mg, Ca, Sr, or Ba) oxides of 3.0% by weight were loaded between the $Ni_6Zr_4O_{14}$ main catalytic species and the microporous Zeolite Y support. The characterizations of these catalysts were examined by XRD, TEM, $H_2$-TPR, $NH_3$-TPD, and XPS. Catalytic performances during ESR were found to depend on the basicity of the added alkaline-earth metal oxides and $H_2$ production and ethanol conversion were maximized to 82% and 98% respectively in 27($Ni_6Zr_4O_{14}$)3MgO/70Zeolite Y catalyst at $600^{\circ}C$. Many carbon deposits and carbon nano fibers were seen on the surface of $30Ni_6Zr_4O_{14}$/70Zeolite Y catalyst but lesser amounts were observed on alkaline-earth metal oxide-loaded 27($Ni_6Zr_4O_{14}$)3MO/70Zeolite Y catalysts in TEM photos after ESR. This study demonstrates that hydrogen yields from ESR are closely related to the acidities of catalysts and that alkaline-earth metal oxides reduce the acidities of 27($Ni_6Zr_4O_{14}$)3MO/70Zeolite Y catalysts and promote hydrogen evolution by preventing progression to hydrocarbons.

Physical Properties of Carbon Prepared from a Coconut Shell by Steam Activation and Chemical Activation and the Influence of Prepared and Activated Carbon on the Delivery of Mainstream Smoke

  • Ko, Dong-Kyun;Shin, Chang-Ho;Jang, Hang-Hyun;Lee, Young-Taeg;Rhee, Moon-Soo
    • Journal of the Korean Society of Tobacco Science
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    • v.30 no.1
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    • pp.8-13
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    • 2008
  • Several activated carbon in different specific surface area was prepared by steam and chemical activation of coconut shell. Products were characterized by BET ($N_2$) at 77K, and probed to be highly specific surface area of $1580m^2/g$ and pore volume that had increased with activating conditions. And also we have analyzed the adsorption efficiency of vapor phase components in cigarette mainstream smoke in order to evaluate the relationship between thesmoke components and the physicochemical properties of activated carbons. As a result of this study, the delivery of mainstream smoke was directly affected by the specific surface area and the pore size of activated carbon. The activated carbon prepared by steam activation exhibited better adsorption efficiency on the vapor phase components in mainstream smoke compared with activated carbon prepared by $ZnCl_2$, due to the higher micro-pore area of 66%. But the adsorption efficiency of semi-volatile matters such as phenolic components in a main stream smoke by the activated mesoporous carbon prepared by $ZnCl_2$ is more effective. From the these results, we can conclude that specific surface area by the micropore area increased the adsorption efficiency of activated carbon on vapour phase components, but semi-volatiles or particulate matter was affected by the ratio of mesopore area in total specific surface area.

Hydrogen Production from Ethanol Steam Reforming over SnO2-K2O/Zeolite Y Catalyst

  • Lee, Jun-Sung;Kim, Ji-Eun;Kang, Mi-Sook
    • Bulletin of the Korean Chemical Society
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    • v.32 no.6
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    • pp.1912-1920
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    • 2011
  • The $SnO_2$ with a particle size of about 300 nm instead of Ni is used in this study to overcome rapid catalytic deactivation by the formation of a $NiAl_2O_4$ spinal structure on the conventional Ni/${\gamma}$-$Al_2O_3$ catalyst and simultaneously impregnated the catalyst with potassium (K). The $SnO_2-K_2O$ impregnated Zeolite Y catalyst ($SnO_2-K_2O$/ZY) exhibited significantly higher ethanol reforming reactivity that that achieved with $SnO_2$ 100 and $SnO_2$ 30 wt %/ZY catalysts. The main products from ethanol steam reforming (ESR) over the $SnO_2$-$K_2O$/ZY catalyst were $H_2$, $CO_2$, and $CH_4$, with no evidence of any CO molecule formation. The $H_2$ production and ethanol conversion were maximized at 89% and 100%, respectively, over $SnO_2$ 30 wt %-$K_2O$ 3.0 wt %/ZY at 600 $^{\circ}C$ for 1 h at a $CH_3CH_2OH:H_2O$ ratio of 1:1 and a gas hourly space velocity (GHSV) of 12,700 $h^{-1}$. No catalytic deactivation occurred for up to 73 h. This result is attributable to the easier and weaker of reduction of Sn components and acidities over $SnO_2-K_2O$/ZY catalyst, respectively, than those of Ni/${\gamma}$-$Al_2O_3$ catalysts.

Elementary Teachers' Perception on Policies related to ICT for Future Education (미래교육을 대비한 정보관련 정책들에 대한 초등교사의 인식)

  • Lim, Sanghoon;Jo, Miheon
    • Journal of The Korean Association of Information Education
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    • v.20 no.2
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    • pp.121-130
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    • 2016
  • A variety of educational policies have been implemented to educate outstanding individuals who will lead the future and to adopt supporting systems. For the successful implementation of educational policies, it is crucial to identify the perception of teachers as main agents of education. This study conducted a survey with elementary teachers in Chungcheongbuk-do. The purpose of this study was to investigate teachers' perception on the major policies related to ICT(i.e., STEAM, Smart Education, Software Education, e-textbook, and EdudataSystem). This study also compared the distribution of teachers' perception on the policies. The results of the study indicated that teachers had relatively positive perception on the importance and the necessity of the policies. On the other hand, it was found that the levels of teachers' training experiences and readiness for teaching related to ICT were relatively low. In addition, the patterns of teachers' perception on STEAM, Smart Education and Software Education were similar. Based on the results, the study suggested that appropriate support and educational strategies for effective implementation of policies should be established.

Prediction of Loop Seal Formation and Clearing During Small Break Loss of Coolant Accident (소형냉각재 상실사고시 루프밀봉 형성 및 제거에 대한 예측)

  • Lee, Sukho;Kim, Hho-Jung
    • Nuclear Engineering and Technology
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    • v.24 no.3
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    • pp.243-251
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    • 1992
  • Behavior of loop seal formation and clearing during small break loss of coolant accident is investigated using the RELAP5/MOD 2 and /MOD3 codes with the test of SB-CL-18 of the LSIF (Large Scale Test Facility). The present study examines the thermal-hydraulic mechanisms responsible for early core uncovery including the manometric effect due to an asymmetric coolant holdup in the steam generator upflow and downflow side. The analysis with the RELAP5/MOD2 demonstrates the main phenomena occuring in the depressurization transient including the loop seal formation and clearing with sufficient accuracy. Nevertheless, several differences regarding the evolution of phenomena and their timing have been pointed out in かe base calculations. The RELAP5/MOD3 predicts overall phenomena, particularly the steam generator liquid holdup better than the RELAP5/MOD2. The nodalization study in the components of the steam generator U-tubes and the cross-over legs wiか the RELAP5/MOD3 results in good prediction of the loop seal clearing phenomena and their timing.

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EFFECTS OF SUPPORT STRUCTURE CHANGES ON FLOW-INDUCED VIBRATION CHARACTERISTICS OF STEAM GENERATOR TUBES

  • Ryu, Ki-Wahn;Park, Chi-Yong;Rhee, Hui-Nam
    • Nuclear Engineering and Technology
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    • v.42 no.1
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    • pp.97-108
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    • 2010
  • Fluid-elastic instability and turbulence-induced vibration of steam generator U-tubes of a nuclear power plant are studied numerically to investigate the effect of design changes of support structures in the upper region of the tubes. Two steam generator models, Model A and Model B, are considered in this study. The main design features of both models are identical except for the conditions of vertical and horizontal support bars. The location and number of vertical and horizontal support bars at the middle of the U-bend region in Model A differs from that of Model B. The stability ratio and the amplitude of turbulence-induced vibration are calculated by a computer program based on the ASME code. The mode shape with a large modal displacement at the upper region of the U-tube is the key parameter related to the fretting wear between the tube and its support structures, such as vertical, horizontal, and diagonal support bars. Therefore, the location and the number of vertical and horizontal support bars have a great influence on the fretting wear mechanism. The variation in the stability ratios for each vibrational mode is compared with respect to Model A and Model B. Even though both models satisfy the design criteria, Model A shows substantial improvements over Model B, particularly in terms of having greater amplitude margins in the turbulence-excited vibration (especially at the inner region of the tube bundle) and better stability ratios for the fluid-elastic instability.

A Study on the Leakage Evaluation for Power Plant Valve Using Infrared Thermography Method (적외선열화상에 의한 발전용 밸브 누설명가 연구)

  • Lee, Sang-Guk
    • Journal of the Korean Society for Nondestructive Testing
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    • v.30 no.2
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    • pp.110-115
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    • 2010
  • This study was conducted to estimate the feasibility using thermal image measurement that is applicable to internal leak diagnosis for the power plant valve. Abnormal heating of valve surface associated with high temperature steam f10w toward valve outlet side in the condition of low temperature is a primary indicator of leakage problems in high temperature and pressure valves. Thermal imaging enables to see the invisible thermal radiation that may portend impending damage before their condition becomes critical. When steam flow in valve outlet side in the condition of low temperature is converted into heat transmitted through the valve body due to the internal leakage in valve. The existence of abnormally increasable leakage rate in the valve will result in abnormally high levels of heat to be generated that can be quickly identified with a thermal image avoiding energy loss or damage of valve component. From the experimental results, it was suggested that the thermal image measurement could be an effective way to precisely diagnose and evaluate internal leak situation of valve.