• 제목/요약/키워드: Magnetic orbital

검색결과 124건 처리시간 0.035초

Strain induced magnetic stripe domains in $La_{0.7}Sr_{0.3}MnO_3$ thin films

  • Joonghoe Dho;Kim, Y. N.;Y. S. Hwang;E. O. Chi;Kim, J. C.;Lee, E. K.;N. H. Hur
    • 한국자기학회:학술대회 개요집
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    • 한국자기학회 2002년도 동계연구발표회 논문개요집
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    • pp.84-85
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    • 2002
  • Recently doped perovskite manganites have renewed interest because they exhibit a variety of unique magnetic and electronic behaviors such as colossal magnetoresistance (CMR), percolative phase separation, spin/charge/orbital ordering, and so on. For this reason, fabrication of thin films with the best surface morphology and controlling their magneto transport properties is essential for making magneto-resistive devices. (omitted)

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절반금속 Fe_2TX 화합물의 전자구조 연구 (T = 3d 전이금속; X = Al, Si) (Electronic Structures of half-metallic phase of ternary Fe_2TX (T = 3d transition metal and X = Al, Si))

  • Park, Jin-Ho;Kwon, Se-Kyun;Byung ll Min
    • 한국자기학회:학술대회 개요집
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    • 한국자기학회 2000년도 International Symposium on Magnetics The 2000 Fall Conference
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    • pp.584-584
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    • 2000
  • Electronic structures of ordered Fe$_3X (X = Al, Si), and their derivative ternary alloys of Fe_2TX (T = 3d transition metal) have been investigated by using the linearized muffin-tin orbital (LMTO) band method. The role of the coupling between substituted transition metal and its neighbors is investigated by calculating the magnetic moments and local density of states (LDOS). It is shown that it is essential to include the coupling beyond nearest neighbors in obtaining the magnetic moment of Fe alloy. The preferential sites of T impurities in Fe_3X are determined from the total energy calculations. The derivative ternary alloys of Fe_2TX have characteristic electronic structures of semi-metal for Fe_2VAI and (nearly) half-metal for Fe_2TAI (T = Cr, Mn) and Fe_2TSi (T = V, Cr, Mn)

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Structural Analysis and Single-Crystal EPR Study of Dimeric Cu(I) Complex with TTF Derivative

  • Kwon, Sun-Young;Seo, Young-Joo;Lee, Yang-Joo;Noh, Dong-Youn;Lee, Hong-In
    • 한국자기공명학회논문지
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    • 제8권2호
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    • pp.86-95
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    • 2004
  • A Cu(I) complex with an asymmetric TTF derivative (CET-EDTTTF) is prepared from the slow-diffusion method using CET-EDTTTF and Cu(I)Br solutions and characterized by X-ray crystallography and EPR spectroscopy. Structural analysis shows Cu(I) ions are tetrahedrally coordinated to two bridging bromides, one terminal bromide, and one S atom from CET-EDTTTF. Detailed geometrical and EPR analysis identified that the dimmer molecule contains [Cu$_2Br_4]^{2-}$ anion between two [CET-EDTTTF]$^+$ radical cations. Single-crystal EPR investigation of the complex reveals that the ganisotropy is unusually big, compared to those of the previously reported TTF+ cation radicals, implying that there is significant contribution of the Cu d-orbital to the HOMO of the complex.

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A First-principles Study on Magnetism of Al Impurity in bcc Fe

  • Rahman, Gul;Kim, In-Gee
    • Journal of Magnetics
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    • 제16권1호
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    • pp.1-5
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    • 2011
  • The magnetism and electronic structure of bcc $Al_1Fe_{26}$ was investigated by means of first-principles calculations with and without spin-orbit coupling (SOC). From the calculated total energy, the SOC corrected system is shown to be approximately 5 meV per atom lower than the SOC uncorrected system. The induced spin magnetic moment at the Al site was -0.125 ${\mu}_B$ without SOC and -0.124 ${\mu}_B$ with SOC. The orbital magnetic moments were calculated to be 0.002 ${\mu}_B$ in [$\overline{1}$00] direction for Al. The electronic structures showed the nearest neighbor antiferromagnetic interaction between Fe and Al to be essential for determining the magnetism of the $Al_1Fe_{26}$ system.

강자성 초전도체의 연구동향과 전망 (Research Trend and Prospect in Ferromagnetic Superconductor)

  • 한상욱
    • 한국자기학회지
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    • 제22권2호
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    • pp.66-72
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    • 2012
  • 강자성 초전도체의 발견은 상극으로 알려진 강자성과 초전도성이 어떻게 상호작용하여 조화롭게 공존하는지에 대한 학문적인 연구뿐만 아니라 새로운 기술적인 응용을 위한 광범위한 탐구를 이끌고 있다. 본 해설논문에서는 강자성 초전도체에 대한 이해를 돕기 위하여, 먼저 초전도체의 쿠퍼쌍을 깨뜨리는 강한 자기장의 궤도 효과와 상자성 효과에 대하여 설명한다. 자기장의 이러한 효과 이외에도 초전도체/강자성체 복합 구조의 계면에서 발생하는 근접 효과에 의해 단일상 쿠퍼쌍은 강자성체를 지나가는 동안 불안정하여 아주 짧은 침투깊이를 가진다. 그러나 쿠퍼쌍이 홀-진동수 삼중상인 경우 안정되고 긴 유효길이를 가지게 되는데, 새로운 스핀 전자소자로서의 개발을 위해 그 연구의 중요성이 높아지고 있다. 마지막으로 다양한 강자성 초전도체와 양자구속효과에 의해 두 성질이 공존하는 저차원의 물질들을 소개한다.

TWO-COLOR VR CCD PHOTOMETRY OF THE INTERMEDIATE POLAR `RXS J062518.2+733433

  • Kim, Yong-Gi;Andronov Ivan L.;Park, Sung-Su;Chinarova Lidia L.;Baklanov Alexey V.;Jeon, Young-Beom
    • Journal of Astronomy and Space Sciences
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    • 제22권3호
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    • pp.197-210
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    • 2005
  • Results of 7 nights of CCD VR photometry of the intermediate polar 1RXS J062518.2+733433 obtained at the Korean 1.8m telescope are reported. The corrected ephemeris for the orbital minimum is BJD (Orb.min) = 2453023.6159(42)+0.1966431(33) (E-1735). The corrected ephemeris for the spin maximum is BJD (spin max) = 2452893 78477 (10)+0.01374116815 (17) (E-15382) (cycle numbering corresponds to that of Staude et al.2003). The variations of the shape of the individual spin variations are highly correlated in V and R. The phase of the spin maximum is found to be dependent on the orbital phase. The corresponding semi-amplitude of sinusoidal variations of phase is $0.11{\pm}0.03.$ This new phenomenon is explained by the changing viewing conditions of the accreting magnetic white dwarf, and should be checked in further observations this star and for other intermediate polars. To avoid influence of this effect on the analysis of the long-term spin period variations, the runs of at least one orbital period are recommended. Results of time series analysis are presented in tables.

Hydration Effect on the Intrinsic Magnetism of Natural Deoxyribonucleic Acid as Studied by EMR Spectroscopy and SQUID Measurements

  • Kwon, Young-Wan;Lee, Chang-Hoon;Do, Eui-Doo;Choi, Dong-Hoon;Jin, Jung-Il;Kang, Jun-Sung;Koh, Eui-Kwan
    • Bulletin of the Korean Chemical Society
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    • 제29권6호
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    • pp.1233-1242
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    • 2008
  • The hydration effect on the intrinsic magnetism of natural salmon double-strand DNA was explored using electron magnetic resonance (EMR) spectroscopy and superconducting quantum interference device (SQUID) magnetic measurements. We learned from this study that the magnetic properties of DNA are roughly classified into two distinct groups depending on their water content: One group is of higher water content in the range of 2.6-24 water molecules per nucleotide (wpn), where all the EMR parameters and SQUID susceptibilities are dominated by spin species experiencing quasi one-dimensional diffusive motion and are independent of the water content. The other group is of lower water content in the range of 1.4-0.5 wpn. In this group, the magnetic properties are most probably dominated by cyclotron motion of spin species along the helical π -way, which is possible when the momentum scattering time (${\tau}_k$) is long enough not only to satisfy the cyclotron resonance condition (${\omega}_c{\tau}_k$ > 1) but also to induce a constructive interference between the neighboring double helices. The same effect is reflected in the S-shaped magnetization-magnetic field strength (M-H) curves superimposed with the linear background obtained by SQUID measurements, which leads to larger susceptibilities at 1000 G when compared with the values at 10,000 G. In particular, we propose that the spin-orbital coupling and Faraday's mutual inductive effect can be utilized to interpret the dimensional crossover of spin motions from quasi 1D in the hydrate state to 3D in the dry state of dsDNA.

TEMPORAL VARIATIONS OF IO'S MAGNETIC FOOTPRINT BRIGHTNESS

  • WANNAWICHIAN, SUWICHA;PROMFU, TATPHICHA
    • 천문학논총
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    • 제30권2호
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    • pp.61-64
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    • 2015
  • The brightness of Io's magnetic footprint, an indicator of electromagnetic interaction at the satellite, appears to be strongly connected to the satellite's distance from the plasma equator. As a result, the brightest footprints were detected when Io is near the interception location between the satellite's orbital plane and the plasma equator. However, volcanic activities on Io show strong correlation with the equatorward shift of Jupiter's main auroral oval, consequently causing the disappearance of Io's footprint. The same conclusion was suggested via the observation of Jupiter's hectometric radio emission, called HOM, which closely corresponds to Jupiter's auroral activity. The plasma environment near the Jovian satellites was found to vary significantly at different observational epochs. The electron density increased by approximately a factor of three from the Voyager epoch (1979) to the Galileo epoch (1995), while the electron density was found to be significantly higher (~ 5 times) in the Cassini epoch (2001). In this current study, the magnetic footprints were clearly brighter ten years ago (from peak brightness in 1998-2001) than the footprints detected in 2007. For volcanic activities on Io in 2007, there are two clear activities in February and late May. The magnetic footprint appeared to be dimmer in March 2007, expected to be the result of volcano activities in Feb 2007. However, the magnetic footprint brightness in June appeared to be slightly brighter than the footprints observed in May. The reason could be the time delay between the brightening of the sodium nebula on approximately May 31st and, a while later, the enhancement of flux tube content peaking on approximately June 5th. On the other hand, Io's magnetic footprints were observed during June 1st - 10th when they may not yet have been affected by the increase in mass outflow due to the increase of plasma density.

Mechanical and thermodynamic stability, structural, electronics and magnetic properties of new ternary thorium-phosphide silicides ThSixP1-x: First-principles investigation and prospects for clean nuclear energy applications

  • Siddique, Muhammad;Iqbal, Azmat;Rahman, Amin Ur;Azam, Sikander;Zada, Zeshan;Talat, Nazia
    • Nuclear Engineering and Technology
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    • 제53권2호
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    • pp.592-602
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    • 2021
  • Thorium compounds have attracted immense scientific and technological attention with regard to both fundamental and practical implications, owing to unique chemical and physical properties like high melting point, high density and thermal conductivity. Hereby, we investigate the mechanical and thermodynamic stability and report on the structural, electronic and magnetic properties of new silicon-doped cubic ternary thorium phosphides ThSixP1-x (x = 0, 0.25, 0.5, 0.75 and 1). The first-principles density functional theory procedure was adopted within full-potential linearized augmented plane wave (FP-LAPW) method. The exchange and correlation potential terms were treated within Generalized-Gradient-Approximation functional modified by Perdew-Burke-Ernzerrhof parameterizations. The proposed compounds showed mechanical and thermodynamic stable structure and hence can be synthesized experimentally. The calculated lattice parameters, bulk modulus, total energy, density of states, electronic band structure and spin magnetic moments of the compounds revealed considerable correlation to the Si substitution for P and the relative Si/P doping concentration. The electronic and magnetic properties of the doped compounds rendered them non-magnetic but metallic in nature. The main orbital contribution to the Fermi level arises from the hybridization of Th(6d+5f) and (Si+P)3p states. Reported results may have potential implications with regard to both fundamental point of view and technological prospects such as fuel materials for clean nuclear energy.

Geosynchronous Magnetic Field Response to Solar Wind Dynamic Pressure

  • Park, Jong-Sun;Kim, Khan-Hyuk;Lee, Dong-Hun;Lee, En-Sang;Jin, Ho
    • Journal of Astronomy and Space Sciences
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    • 제28권1호
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    • pp.27-36
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    • 2011
  • The present study examines the morning-afternoon asymmetry of the geosynchronous magnetic field strength on the dayside (magnetic local time [MLT] = 06:00~18:00) using observations by the Geostationary Operational Environmental Satellites (GOES) over a period of 9 years from February 1998 to January 2007. During geomagnetically quiet time (Kp < 3), we observed that a peak of the magnetic field strength is skewed toward the earlier local times (11:07~11:37 MLT) with respect to local noon and that the geosynchronous field strength is larger in the morning sector than in the afternoon sector. That is, there is the morning-afternoon asymmetry of the geosynchronous magnetic field strength. Using solar wind data, it is confirmed that the morning-afternoon asymmetry is not associated with the aberration effect due to the orbital motion of the Earth about the Sun. We found that the peak location of the magnetic field strength is shifted toward the earlier local times as the ratio of the magnetic field strength at MLT = 18 (B-dusk) to the magnetic field strength at MLT = 06 (B-dawn) is decreasing. It is also found that the dawn-dusk magnetic field median ratio, B-dusk/B-dawn, is decreasing as the solar wind dynamic pressure is increasing. The morning-afternoon asymmetry of the magnetic field strength appears in Tsyganenko geomagnetic field model (TS-04 model) when the partial ring current is included in TS-04 model. Unlike our observations, however, TS-04 model shows that the peak location of the magnetic field strength is shifted toward local noon as the solar wind dynamic pressure grows in magnitude. This may be due to that the symmetric magnetic field associated with the magnetopause current, strongly affected by the solar wind dynamic pressure, increases. However, the partial ring current is not affected as much as the magnetopause current by the solar wind dynamic pressure in TS-04 model. Thus, our observations suggest that the contribution of the partial ring current at geosynchronous orbit is much larger than that expected from TS-04 model as the solar wind dynamic pressure increases.