• 한국유체기계학회 논문집
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• 제17권2호
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• pp.35-40
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• 2014

The optimal removal efficiency to develop wastewater treatment system using the magnetic ion exchange resin. The secondary sedimentation effluent of wastewater in W wastewater treatment plant located in Gyeong-gi Province was used as the influent. To compare the sedimentation effluent reacted with the magnetic ion exchange resin to the influent, the concentrations of CODmm, TN, $NO{_3}^-$-N and TP were measured. The flux of the influent and HRT were set to 250 mL/min, 10 min, respectively, and BVTR has adjusted to 200, 150, 100. The removal efficiency of CODmn, TN, $NO{_3}^-$-N and TP in the 200 BVTR from 71%, 40.37%, 46.34%, 42.03%, 150 BVTR from 55.22%, 37.83%, 50.38% 41.6% and 100 BVTR from 74%, 59.15%, 79.94%, 79.16%, respectively. The results on 200 BVTR, 150 BVTR, 100 BVTR tests show that 100 BVTR is the optimal factor capable of the highest rate of rejection of the organic material.

• 한국환경과학회지
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• 제22권8호
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• pp.1009-1017
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• 2013

Perfluorooctanoic acid (PFOA) and perfluorooctyl sulfonate (PFOS) is a new persistent organic pollutants of substantial environmental concern. This study investigated the potential of magnetic ion exchange resin (MIEX$^{(R)}$) as the adsorbent for the removal of PFOA and PFOS from Nakdong River water. In our batch experiments, we studied the effect of some parameters (pH, temperature, sulfate concentration) on the removal of PFOA and PFOS. The results of sorption kinetics on MIEX$^{(R)}$ show that it takes 90 min to reach equilibrium but the economical contact time and dosage were 30 min and 10 mL/L. An increase in pH (pH 6~10) leads to a decrease in PFOA (2.0%) and PFOS (3.6%) sorption on MIEX$^{(R)}$. The sorption of both PFOA and PFOS decreases with an increase in ionic strength for sulfate ion (${SO_4}^{2-}$), due to the competition phenomenon. An increase in water temperature ($8^{\circ}C{\sim}28^{\circ}C$) in water leads to a increase in PFOA (2.8%) and PFOS (4.3%) sorption on MIEX$^{(R)}$. Based on the sorption behaviors and characteristics of the adsorbents and adsorbates, ion exchange and hydrophobic interaction were deduced to be involved in the sorption, and hemi-micelles possibly formed in the intraparticle pores.

• 품질경영학회지
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• 제17권2호
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• pp.64-69
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• 1989

This paper aims at analyzing the process capability and at determining an optimal condition by experimental designs using the 2-way classification with repitition in order to maintain lower Nacl content and to refine both of a very small quantity of fatty acid and various magnetic ions in the glycerin to use ion exchange resin treatment process. An optimal condition of each level combination in both of passing temperature of cation exchange resin($A_1$, $A_2$, $A_3$) and of anion exchange resin($B_1$, $B_2$, $B_3$) is $A_3B_3$. The process capability index is improved from 0.63 to 1.40 and is interpreted as a desirable state. This analysis of process capability by experimental designs will contribute to improving productivity and quality of products.

• 약학회지
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• 제28권1호
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• pp.21-23
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• 1984

High performance amino acid analyzing method has been developed for the routine analysis of taurine in preparations. Ion-exchange resin #2619 Hitachi Custom Ion-Exchange Resin, $2.6(I.D.){\times}150$(length)mm was used as column, buffer I, pH 3.3 as mobile phase. The retention time of taurine was 7 minutes. Calibration curve by peak height for standard taurine was linear from 2.5ppm to 25ppm. The reproducibility showed relative standard deviation $\pm$1.9% when analyzed 10 times for standard solution. The samples could be continuously analyzed without regenerating the resin between samples. Five samples were applied to column every 12 min. and then the resin was regenerated for 30 min. during one analyzing cycle time, 90 min. The automatic amino acid analyzer has made it possible to assay multiple samples in a relatively short period of time using the analytical magnetic program card. The high sensitivity and specificity of the analytical column of the automatic amino acid analyzer permits the routine analysis of taurine in preparations.

• 상하수도학회지
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• 제22권1호
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• pp.131-140
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• 2008

The application of magnetic ion exchange resin($MIEX^{(R)}$) is effective for natural organic matter(NOM) removal and for control of the formation of disinfection byproducts(DBPs). NOM removal is also enhanced by adding $MIEX^{(R)}$ with coagulant such as polyaluminium chloride(PACl) in conventional drinking water treatment systems. In the application of $MIEX^{(R)}$, it is important to understand changes of NOM characteristics such as hydrophobicity and molecular weight distributions with $MIEX^{(R)}$ or $MIEX^{(R)}$+coagulant treatment.To observe characteristics of NOM by treatment with $MIEX^{(R)}$ or $MIEX^{(R)}$+coagulant, four major drinking water sources were employed. Results showed that the addition of $MIEX^{(R)}$ to coagulation significantly reduced the amount of coagulant required for the optimum removal of dissolved organic matter(DOC) and turbidity in the all four waters. The DOC removal was also increased approximately 20%, compared to coagulant treatment alone. The process with $MIEX^{(R)}$ and coagulant showed that complementary removal of hydrophobic and hydrophilic fraction of DOC. The combined processes preferentially removed the fractions of intermediate (3,000-10,000 Da) and low (< 500 Da) molecular weight. The microfiltration test showed that membrane cake resistance was decreased for waters with flocs from $MIEX^{(R)}$+coagulant. A porous layer was formed to $MIEX^{(R)}$ on the membrane surface and the layer consequently inhibited settling of coagulant flocs, which could act on a foulant.

• 한국세라믹학회지
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• 제39권6호
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• pp.576-581
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• 2002

원자력발전소에서 발생하는 이온교환수지와 잡고체를 동시에 처리하기 위하여 유도 가열식 저온용융로를 이용한 유리화 실증시험을 수행하였다. 유리 고화체의 화학적 내구성을 평가하기 위하여 최종 유리에 대해 수행한 PCT 침출 시험결과 기준유리 보다 내 침출성이 우수한 것으로 나타났다. 최종 유리 고화체에 대해 열처리 실험 결과 액상온도는 1048K (775$^{\circ}C$)로 측정되었다 유리 고화체에 대한 압축강도 측정 결과 규제치인 34kg/$\textrm{cm}^2$ 보다 약 90배 높은 값을 나타내었다. 저온용융로(CCM)의 하부, 중앙, 상부 유리 고화체의 미세구조 관찰 결과 이차상 없는 균질한 상태였다. 환원성 유기물을 함유한 이온교환수지에 잡고체를 동시 투입하여 자성 금속상 침전을 방지할 수 있었다. 유리화 실증시험을 통하여 감용비 74를 달성하였다.