• Title/Summary/Keyword: Magnetic composite

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The Characterizations of Tape Casting for Low Temperature Sintered Microwave Ceramics Composite (저온소성 마이크로파 유전체 세라믹스 복합체의 Tape Casting특성)

  • Lee, Woo-Suk;Kim, Chang-Hwan;Ha, Mun-Su;Jeong, Soon-Jong;Song, Jae-Sung;Ryu, Bong-Ki
    • Journal of the Korean Ceramic Society
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    • v.42 no.2 s.273
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    • pp.132-139
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    • 2005
  • Sintering behavior of $BaO-Nd_{2}O_3-TiO_2$ with a Pb-based glassceramics frit were investigated in order to understand an effect of glassceramics as a low temperature sintering agent on dielectric ceramics. A green sheet form was fabricated through tape casting method with the glassceramic fut added $BaO-Nd_{2}O_3-TiO_2$. The dispersion properties, rheological properties and final density of dielectric composit slurry as a function of amount and composition of organic additives was examined. The dispersants' addition was effective in controlling dispersion of the ceramics in solution. The addition of excessive dispersant showed adverse effect on dispersion. The prepared slurries, containing ceramic : powders, glass-ceramics and various kinds of organic viechles, exhibited typical shear thinning behavior. The best properties of tape casting appeared powder to solvent ratio 65 : 35 and amount of the binder 6 wt$\%$ and plasticizer 3 wt$\%$. The viscosity of the slurry was 677 cps and green/sintered density in the tape was $3.3 g/cm^3,\;5.56 g/cm^3$ respectively.

Fabrication of Lightweight Microwave Absorbers with Co-coated Hollow Silica Microspheres (저밀도 실리카 중공미세구 표면에 Co 박막의 코팅에 의한 경량 전파흡수체 제조)

  • Kim, Sun-Tae;Kim, Sung-Soo;Ahn, Jun-Mo;Kim, Keun-Hong
    • Journal of the Korean Magnetics Society
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    • v.15 no.2
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    • pp.67-75
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    • 2005
  • For th aim of lightweight microwave absorbers, conductive and magnetic microspheres are fabricated by plating of Co films on hollow ceramic microspheres of low density. Metal plating was carried out in a two-step electroless plating process (pre-treatment of activation and plating). Uniform coating of the film with about $2{\~}3{\cal}um$ thickness was identified by SEM. High-frequency magnetic and microwave absorbing properties were determined in the rubber composites containing the Co-coated microspheres. Due to conductive and ferromagnetic behavior of the Co thin films, high dielectric constant and magnetic loss can be obtained in the microwave frequencies. Due to those electromagnetic properties, high absorption rate (25 dB) and thin matching thickness ($2.0{\~}2.5{\cal}mm$) are predicted in the composite layers containing the metal-coated microspheres of low density (about 0.84 g/cc) for the electromagnetic radiation in microwave frequencies.

Magnetic Parameters as Indicators of Late-Quaternary Environments on Fort Riley Kansas (암석 자기 변수들을 이용한 제4기 고환경 복원-Fort Riley 캔사스)

  • Park, kyeong
    • The Korean Journal of Quaternary Research
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    • v.11 no.1
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    • pp.57-68
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    • 1997
  • Climatic change of the late-Quaternary period has been record-ed in the loess deposits of the central Great plains and the record of such change is extractable using a number of approaches and parameters. The stratigraphy of loess deposits which have been investigated on Fort Riley exhibits the same sequence of loess units and intercalated buried soils as is found elsewhere in the re-gion but adds detail unique to the reservation Upland late-Qua-ternary composite stratigraphy preserved on the reservation con-sists of the basal Sangamon soil of the Last interglacial(c. 120-110ka), Gilman Canyon Formation(c. >40 -20ka), Peoria loess(c. 20 -10ka) Brady soil(c. 11 -10ka) Bignell loess(c. 9-\ulcornerka). and mod-ern surface soil. Application of magnetic analyses has provided proxy data sets that represent a time series of climatically regulated pedogenesis/weathering and botanical composition. magetic data have yielded an impression of the variation in climate from Sangamon time to the late Holocene through a reconstruction of the history of pedogenesis/weathering. Sangamon soil formation dominated the reservation durin the Last interglacial as indicated by magnetic parameters. During Gil-man Canyon time loess influx was usually sufficiently slow as to permit pedogenesis which appears to have been at a maximum twice during that time. Warm season grasses were important dur-ing soil formation but diminished in importance during the peri-ods of more rapid loess fall which were cooler and perhaps wet-ter. Peoria loess fall a function of the deterioration of climate during the last Glacial Maximum thinly blanketed the reservation with thickest accumulations occurring to the north-west(Bala Cemetery site)proximal to the source region. Long-term surface stability did not apparently occur within Peoria time but short-term stability may be indicaed by the presence of thin weathering zones(incipient soils) in the Peoria loess. Re-gional landscape stability prevailed during the environmental shift at the Pleistocene/Holocene transition resulting in forma-tion of the well expressed Brady soil. One or more weak soils developed in the Bignell loess as it ac-cumulated. A notable feature of the Bignell loess is the appear-ance of the Altithermal dry period: the loess experienced little weathering and was dominated by warm season grasses until the latter of the Holocene.

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Single-layered Microwave Absorbers containing Carbon nanofibers and NiFe particles (탄소나노섬유와 NiFe 분말을 함유한 단층형 전자기파 흡수체)

  • Park, Ki-Yeon;Han, Jae-Hung;Lee, Sang-Bok;Kim, Jin-Bong;Yi, Jin-Woo;Lee, Sang-Kwan
    • Composites Research
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    • v.21 no.5
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    • pp.9-14
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    • 2008
  • Carbon nanofibers (CNFs) were used as dielectric lossy materials and NiFe particles were used as magnetic lossy materials. Total twelve specimens for the three types such as dielectric, magnetic and mixed radar absorbing materials (RAMs) were fabricated. Their complex permittivities and permeabilities in the range of $2{\sim}18$ GHz were measured using the transmission line technique. The parametric studios for reflection loss characteristics of each specimen to design the single-layered RAMs were performed. The mixed RAMs generally showed the improved absorbing characteristics with thinner matching thickness. One of the mixed RAMs, MD3with the thickness of 2.00 mm had the 10 dB absorbing bandwidth of 4.0 GHz in the X-band ($8.2{\sim}12.4$ GHz). It also showed very broad 10 dB absorbing bandwidth as wide as 6.0 GHz in the Ku-band ($12.0{\sim}18.0$ GHz) with the thickness tuning to 1.49 mm. The experimental results for selected several specimens were in very good agreements with simulation ones in terms of the overall reflection loss characteristics and 10 dB absorbing bandwidth.

Consolidation and magnetic properties of ferromagnetic Fe-MgO powders prepared by ball milling process (볼밀링법으로 제조된 강자성 Fe-MgO 분말의 벌크화 및 자기적 특성)

  • Chung-Hyo Lee
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.34 no.4
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    • pp.125-130
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    • 2024
  • Preparation of ferromagnetic powders for the mixture of hematite and pure Mg powders by ball milling has been investigated. Also, consolidation of the ball-milled powders was performed in a spark plasma sintering machine at 800-1,000℃. It is found that a ferromagnetic Fe-MgO composite powders are obtained by ball milling of hematite and pure Mg powders before 1 hour. The magnetization and coercivity of ball-milled samples change at the results of the solid state reaction of hematite by pure Mg during ball milling. The saturation magnetization of ball-milled samples increases with increasing ball milling time and reaches to a maximum value of 93.4 emu/g after 5 hours of ball milling. Shrinkage change after sintering of ball-milled sample for 5 hours was significant above 300℃ and gradually increased with increasing temperature up to 800℃. X-ray diffraction result shows that the average grain size of Fe in Fe-MgO bulk sample sintered at 900℃ is 50 nm. It can be also seen that the coercivity of bulk sample sintered at 900℃ is still high value of 90 Oe, indicating that the grain growth of magnetic Fe phase during sintering process tend to be suppressed.

Sorptive Removal of Radionuclides (Cobalt, Strontium and Cesium) using AMP/IO-PAN Composites (AMP/IO-PAN 복합체를 이용한 방사성 핵종(코발트, 스트론튬, 세슘)의 흡착 제거)

  • Park, Younjin;Kim, Chorong;Shin, Won Sik;Choi, Sang-June
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.11 no.4
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    • pp.259-269
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    • 2013
  • Applicability of ammonium molybdophosphate/iron oxides-polyacrylonitrile (AMP/IO-PAN) composites on the removal of radionuclides in the radioactive wastewater generated from nuclear power plants was investigated. The composites were characterized using the following analytical techniques: X-ray diffraction (XRD), Fourior transform-infrared (FT-IR) spectroscopy, scanning electron microscopy (SEM), particle size analyzer (PSA), nitrogen adsorption-desorption and magnetic property measurement system (MPMS). 10wt% of AMP/IO-PAN composite has a saturation magnetization of 2.038 emu/g. Single-solute sorptions of Co, Sr and Cs onto 10wt% of AMP/IO-PAN composite were investigated. The maximum sorption capacities ($Q^0$) predicted by the Langmuir model on 10wt% of AMP/IO-PAN composite were 0.097, 0.086 and 0.66 mmol/g for Co, Sr and Cs, respectively. The maximum sorption capacities ($Q^0$) of Cs predicted by Langmuir model on 0, 10, 20 and 30wt% of AMP/IO-PAN composites were 0.702, 0.655, 0.602 and 0.559 mmol/g, respectively. The maximum sorption capacities ($Q^0$) of Cs decreased with increasing the iron oxide content in the AMP/IO-PAN composites.

A Study on Multi-Layered EM Wave Absorber Using Natural Lacquer as a Binder

  • Choi, Dong-Han;Kim, Dong-Il;Choi, Chang-Mook;Li, Rui
    • Journal of Navigation and Port Research
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    • v.30 no.9
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    • pp.767-772
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    • 2006
  • Generally, a silicone rubber and a chlorinated polyethylene(CPE) have been used as a binder for the development of high-performance composite EM(Electro Magnetic) wave absorbers. In this paper, the EM wave absorption performance of natural lacquer, which is newly proposed as a binder was investigated. The prepared MnZn ferrite EM wave absorbers are mixed with natural lacquer showed excellent EM wave absorption characteristics compared with MnZn ferrite EM wave absorbers which are mixed with the conventional binders. MnZn ferrite EM wave absorbers mixed with natural lacquer were prepared and their absorption ability was also investigated The EM wave absorbers are fabricated in different proportions of MnZn, or NiZn ferrite and natural lacquer, and their reflection coefficients are measured. The permittivity and permeability are calculated by using the measured reflection coefficients. The EM wave absorption abilities are calculated according to different thicknesses of the EM wave absorbers.

Immobilization of oxidative enzymes onto Cu-activated zeolite to catalyze 4-chlorophenol decomposition

  • Zol, Muhamad Najmi Bin;Shuhaimi, Muhammad Firdaus Bin;Yu, Jimin;Lim, Yejee;Choe, Jae Wan;Bae, Sungjun;Kim, Han S.
    • Membrane and Water Treatment
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    • v.11 no.3
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    • pp.195-200
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    • 2020
  • In this study, a biocatalyst composite was prepared by immobilizing oxidoreductases onto Cu-activated zeolite to facilitate biochemical decomposition of 4-chlorophenol (4-CP). 4-CP monooxygenase (CphC-I) was cloned from a 4-CP degrading bacterium, Pseudarthrobacter chlorophenolicus A6, and then overexpressed and purified. Type X zeolite was synthesized from non-magnetic coal fly ash using acetic acid treatment, and its surfaces were coated with copper ions via impregnation (Cu-zeolite). Then, the recombinant oxidative and reductive enzymes were immobilized onto Cu-zeolite. The enzymes were effectively immobilized onto the Cu-zeolite (79% of immobilization yield). The retained catalytic activity of CphC-I after immobilization was 0.3423 U/g-Cu-zeolite, which was 63.3% of the value of free enzymes. The results of this study suggest that copper can be used as an effective enzyme immobilization binder because it provides favorable metalhistidine binding between the enzyme and Cu-zeolite.

A study on vector modeling using Preisach and Stoner-Wholfarth Model (Preisach 모델과 Stoner-Wholfarth 모델을 결합한 벡터 모델링 기법에 관한 연구)

  • Lee, Jung-Woo;Park, Gwan-Soo;Hahn, Song-Yop
    • Proceedings of the KIEE Conference
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    • 1996.07a
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    • pp.62-64
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    • 1996
  • Two current approaches for modeling the vector magnetic hysteretic process are the vector Preisach models and those models based on a system of noninteracting pseudo-particles. The pseudo-particles are intended to mimic the average behavior of real media particles. The simplest switching mechanisms of pseudoparticles is the Stoner-Wholfarth model. The Preisach models are quite precise in specifying the experimental input to the models. The vector properties of the Preisach models are, however, inadequate. This is partly because of the questionable assumptions used in coupling the various vector hysteresis components. Also these models do not include reversible magnetization changes. Unlike Preisach counterpart, the Stoner-Wholfarth model is inherently vector in nature. This is because spatial distribution and switching mechanisms are imposed on the system of pseudo-particles, so they come closer to representing the physical reality. The lack of interaction between pseudo-particles exclude the usefulness of the Stoner-Wholfarth model for small fields when the medium is traversing minor loops. The present work is an attempt at combining the advantages of above two models into one composite model, including the effect of particle interaction.

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Non-linear free and forced vibration analysis of sandwich nano-beam with FG-CNTRC face-sheets based on nonlocal strain gradient theory

  • Arani, Ali Ghorbanpour;Pourjamshidian, Mahmoud;Arefi, Mohammad
    • Smart Structures and Systems
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    • v.22 no.1
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    • pp.105-120
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    • 2018
  • In this paper, the nonlinear free and forced vibration responses of sandwich nano-beams with three various functionally graded (FG) patterns of reinforced carbon nanotubes (CNTs) face-sheets are investigated. The sandwich nano-beam is resting on nonlinear Visco-elastic foundation and is subjected to thermal and electrical loads. The nonlinear governing equations of motion are derived for an Euler-Bernoulli beam based on Hamilton principle and von Karman nonlinear relation. To analyze nonlinear vibration, Galerkin's decomposition technique is employed to convert the governing partial differential equation (PDE) to a nonlinear ordinary differential equation (ODE). Furthermore, the Multiple Times Scale (MTS) method is employed to find approximate solution for the nonlinear time, frequency and forced responses of the sandwich nano-beam. Comparison between results of this paper and previous published paper shows that our numerical results are in good agreement with literature. In addition, the nonlinear frequency, force response and nonlinear damping time response is carefully studied. The influences of important parameters such as nonlocal parameter, volume fraction of the CNTs, different patterns of CNTs, length scale parameter, Visco-Pasternak foundation parameter, applied voltage, longitudinal magnetic field and temperature change are investigated on the various responses. One can conclude that frequency of FG-AV pattern is greater than other used patterns.