• Title/Summary/Keyword: Magnetic Saturation

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Impact of Amino-Acid Coating on the Synthesis and Characteristics of Iron-Oxide Nanoparticles (IONs)

  • Ebrahiminezhad, Alireza;Ghasemi, Younes;Rasoul-Amini, Sara;Barar, Jaleh;Davaran, Soodabeh
    • Bulletin of the Korean Chemical Society
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    • v.33 no.12
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    • pp.3957-3962
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    • 2012
  • Iron-oxide nanoparticles (IONs) with biocompatible coatings are the only nanostructural materials which have been approved by the FDA for clinical use. Common biocompatible coatings such as hydrocarbons, polymers, and silica have profound influences on critical characteristics of IONs. Recently, amino acids were introduced as a novel biocompatible coating. In the present study, the effects of amino acids on IONs synthesis and characteristics have been evaluated. Magnetite nanoparticles with L-arginine and L-lysine coatings were synthesised by a coprecipitation reaction in aqueous solvent and their characteristics were compared with naked magnetite nanoparticles. The results showed that amino acids can be a perfect coating for IONs and would increase particle stability without any significant effects on the critical properties of nanoparticles such as particle size and magnetization saturation value.

Spectrum analysis of acoustic Barkhausen noise on neutron irradiated material

  • Sim Cheul-Muu;Park Seung-Sik;Park Duck-Gum;Lee Chang-Hee
    • Proceedings of the Acoustical Society of Korea Conference
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    • autumn
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    • pp.231-234
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    • 2000
  • In relation to a non-destructive evaluation of irradiation damage of micro-structure of interstitial, void and dislocation, the changes in the hysteresis loop and Barkhausen noise amplitude and the harmonics frequency due to neutron irradiation were measured and evaluated. The Mn-Mo-Ni low alloy steel of reactor pressure vessel was irradiated to a neutron fluence of $2.3\times10^{19}n/cm^2$ $(E\ge1MeV)$ at $288^{\circ}C.$The saturation magnetization of neutron irradiated metal did not change. Neutron irradiation caused the coercivity to increase, whereas susceptibility to decrease. The amplitude of Barkhausen noise parameters associated with the domain wall motion were decreased by neutron irradiation. The spectrum of Barkhausen noise was analyzed with an applied frequency of 4Hz and 8Hz, and a sampling time of 50 $\mu$ sec and 20 $\mu$ sec. The harmonic frequency of Joule effect shows 4Hz, 8Hz, 12Hz and 16Hz reflected from an unirradiated specimen. On the contrary, the harmonic frequency disappeared for the irradiated specimen. Harmonic frequency of induced voltage of sinusoidal magnetic field And Spectrum of Barkhausen noise on material is determined.

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Synthesis, Structure and Magnetization Behaviors of MnBi/Fe3B/Nd2Fe14B Nanocomposite alloy

  • Yang, Y.;Wu, Q.;Hu, Y.C.;Zhang, P.Y.;Ge, H.L.
    • Journal of Magnetics
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    • v.21 no.2
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    • pp.235-238
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    • 2016
  • Microstructure and magnetization behaviors of $MnBi/Fe_3B/Nd2_Fe_{14}B$ nanocomposite alloy have been investigated. It was found that the coercivity increased firstly and then decreased, and saturation magnetization decreased with the additon of MnBi alloy. The addition of 40 wt.% MnBi powder enhanced the coercivity from 192.8 kA/m to 311.2 kA/m. The ${\delta}M$ and D(H)-H plots suggested the occurrence of a stronger exchange-coupling occurring between the hard and soft magnetic phase for this sample. The dependence of coercivity with temperature was discussed in 40 wt.% $Mn_{55}Bi_{45}$/ 60 wt.% $Nd_{4.5}Fe_{76.5}Nb_{0.5}B_{18.5}$ alloy powder, and a positive temperature coefficient was founded from 298 K to 350 K.

Control of Material Properties and Magnetism of Electroplated Nickel-iron Thin Films (전기도금법을 이용한 니켈-철 박막의 물성과 자성 조절)

  • Seo, Ho-Young;Nam, Kyung-Ho;Hong, Ki-Min
    • Journal of the Korean Magnetics Society
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    • v.22 no.2
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    • pp.42-44
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    • 2012
  • We have studied a means to control the composition of nickel-iron thin films. By changing current and voltage applied to a electroplating electrolyte we could manipulate the relative concentration of nickel and iron in the thin films, which caused variations of coercivity, squareness, and saturation magnetic field. As we increase the content of iron in the thin films by using potentiostatic and galvanostatic plating, the grain size was increased and the coercivity was reduced.

Preparation of Li-ferrite Powders by Hyrtothermal Method (수열합성법에 의한 Li-ferrite 분말 제조)

  • Lee, Jong-Hyeon;Kang, Yong;Won, Chang-Whan;Chun, Byong-Sun
    • Journal of the Korean Ceramic Society
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    • v.32 no.5
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    • pp.543-548
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    • 1995
  • Li-ferrite powders were prepared from mixture of Fe and Li salts using a hydrothermal method. Their crystal structure, microstructure and magnetic property were investigated with X-ray diffraction analysis, chemical analysis, SEM, and VSM. In the case of using FeCl3 as a precursor, Li-ferrite powders were synthesized. However, Fe3O4 was formed when the precursor was a divalented Fe2SO4 or FeCl2. The precipitation rate of Li-ferrite was increased as the reaction temperature increased. The optimum conditions of synthesis were the mole ratio of Fe+++/Li+=2, pH 13, the reaction temperature of 25$0^{\circ}C$ and the reaction time of 120min. With this condition, the spherical particles with good dispersion were obtained with average particle size of 0.4${\mu}{\textrm}{m}$ and saturation magnetization of 65 emu/g.

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Sliding Mode Control for Improving Performance of Mount with MR(Magneto-Rheological) Fluid (MR마운트 진동제어 성능 향상을 위한 슬라이딩 모드 제어)

  • Ahn, Young Kong;Kim, Sung-Ha;Jeong, Seok-Kwon
    • Journal of Power System Engineering
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    • v.21 no.4
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    • pp.18-25
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    • 2017
  • This paper deals with vibration control of a small mount with MR(Magneto-Rheological) fluid as a functional fluid mount for precision equipment of automobiles. Damping and stiffness coefficients of the mount with MR fluid are changed by variations of the applied magnetic field strength. We present the robust control scheme, based on a conventional sliding mode control theory, for the design of a stable controller that is capable of vibration control due to various disturbances such as impact and periodic excitations, and is insensitive to dynamic properties of the mount. We got stable controller by using Lyapunov stability theory. The controller is then realized by using a semi-active control condition in simulations. Chattering problem of the sliding mode control is eliminated by saturation function instead of signum function. The sliding mode control with Lyapunov stability theory is superior to passive and Sky-Hook control in performance.

Study on the Condensation Heat Transfer Characteristics in Small Diameter Tubes (세관 내 응축 열전달 특성에 관한 연구)

  • 박기원;노건상;홍진우;오후규
    • Journal of Advanced Marine Engineering and Technology
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    • v.28 no.1
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    • pp.29-38
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    • 2004
  • The Condensation heat transfer coefficients of R-22 and R-l34a were measured in smooth horizontal copper tubes with inner diameters of 1.77. 3.36 and 5.35 mm. respectively. The experiments were conducted in a closed loop. which was driven by a magnetic gear pump. They were Performed for the following ranges of variables: mass flux (200 to $500\;kg/\textrm{m}^2{\cdot}s$) saturation temperature $30^{\circ}C$ and quality (0 to 1.0). The main results obtained are as follows Condensation heat transfer coefficients in the small diameter tubes (ID < 7 mm) were observed to be strongly affected by inner diameter change and to differ from those in the large diameter tubes. The heat transfer coefficients in the small diameter tubes were 20 ~ 40 % higher than those in the large diameter tubes as the inner diameter of the tube was reduced. Also. it was very difficult to apply some well-known previous predictions (Cavallini-Zecchin's. Haraguchi's and Dobson's correlation) to small diameter tubes. Based on an analogy between heat and mass transfer the new correlation is Proposed to predict the experimental data more accurately.

Evaporative Heat Transfer Characteristics of Carbon Dioxide in a Horizontal Tube (수평관내 이산화탄소의 증발 열전달 특성)

  • Son Chang-Hyo;Lee Dong-Gun;Kim Young-Lyoul;Oh Hoo-Kyu
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.16 no.12
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    • pp.1134-1139
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    • 2004
  • The evaporative heat transfer coefficient of $CO_2$ (R-744) in a horizontal tube was investigated experimentally. The experiments were conducted without oil in a closed refrigerant loop which was driven by a magnetic gear pump. The main components of the refrigerant loop are a receiver, a variable-speed pump, a mass flow meter, a pre-heater and evaporator (test section). The test section consists of a smooth, horizontal stainless steel tube of inner diameter of 7.75 mm. The experiments were conducted at mass flux of 200 to 500 kg/m$^2$s, saturation temperature of -5 to 5$^{\circ}C$, and heat flux of 10 to 40kW/m$^2$. The test results showed the heat transfer of $CO_2$ has a greater effect on nucleate boiling more than convective boiling. Mass flux of $CO_2$ does not affect nucleate boiling too much, and the effect of mass flux on evaporative heat transfer of $CO_2$ is much smaller than that of refrigerant R-22 and R-134a. In comparison with test results and existing correlations, correlations failed to predict the evaporative heat transfer coefficient of $CO_2$, therefore, it is necessary to develope reliable and accurate predictions determining the evaporative heat transfer coefficient of $CO_2$ in a horizontal tube.

THE LOW TEMPERATURE DEPENDENCE OF MAGNETIZATION AND AC SUSCEPTIBILITY OF GLASSY $Fe_{91-x}Zr_{7}B_{2}Ni_{x}$ (x=0,5,10,15) ALLOYS

  • Strom, V.;Kim, K.S.;Jonsson, B.J.;Yu, S.C.;Inoue, A.;Rao, K.V.
    • Journal of the Korean Magnetics Society
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    • v.5 no.5
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    • pp.515-518
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    • 1995
  • We have studied the magnetization in fields up to 1T at 5K, the saturation magnetization dependence on temperature and the temperature dependence of AC-susceptibility at very low fields (5mOe to 50mOe) of glassy $Fe_{91-x}Zr_{7}B_{2}Ni_{x}$ (x = 0, 5, 10, 15) alloys. The temperature dependence of the magnetization follows the predictions of spin wave excitations with long wavelengths. At zero Ni concentration there is a clear competition between ferromagnetic and antiferromagnetic interactions giving rise to spin-glass behaviour. The addition of Ni drastically modifies the magnetic properties: the antiferromagnetic exchange coupling is reduced and finally disappears, the spin wave stiffness increases from 39.5 to $87.3\;meV{\AA}^{2}$ and To increases from 230 K to 478 K. We develop a simple model to quantify the competing interactions and to relate the antiferromagnetically coupled Fe moments to the Ni concentration. We find that the initial susceptibility increases with increasing Ni content along with a decrease of the temperature dependence.

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THE EFFECT OF NITROGEN ON THE MICROSTRUCTURE AND THE CORROSION RESISTANCE OF Fe-Hf-C-N THIN FILMS

  • Choi, J.O.;Han, S.H.;Kim, H.J.;Kang, I.K.
    • Journal of the Korean Magnetics Society
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    • v.5 no.5
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    • pp.641-644
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    • 1995
  • We have studied the effect of the nitrogen on the microstructure, thermomagnetic properties and corrosion resistance of Fe-Hf-C-N nanocrystalline thin films with high permeability and high saturation magnetization. These films were fabricated by reactive sputtering in $Ar+N_{2}$ plasma using an rf magnetron sputtering apparatus. As $P_{N2}$ increases, the microstructure changes from amorphous to crystalline $\alpha$-Fe phase and again returns to amorphous one. Spin wave stiffness constant increases with $P_{N2}$ until 5% $P_{N2}$, and then decreases with the further increase. This trend corresponds well with that of the microstructure with increasing $P_{N2}$. The Fe-Hf-C-N films with over 3% $P_{N2}$ show higher corrosion resistance than the N-free Fe-Hf-C films. The Fe-Hf-C-N films are considered to have high potentials for the head core materials suitable for high density recording systems, owing to their excellent soft magnetic properties and corrosion resistance.

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