• Title/Summary/Keyword: Magnetic Saturation

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Crystallographic and Magnetic Properties of Nickel Substituted Manganese Ferrites Synthesized by Sol-gel Method

  • Chae, Kwang Pyo;Choi, Won Oak;Lee, Jae-Gwang;Kang, Byung-Sub;Choi, Seung Han
    • Journal of Magnetics
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    • v.18 no.1
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    • pp.21-25
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    • 2013
  • Nickel substituted manganese ferrites, $Mn_{1-x}Ni_xFe_2O_4$ ($0.0{\leq}x{\leq}0.6$), were fabricated by sol-gel method. The effects of sintering and substitution on their crystallographic and magnetic properties were studied. X-ray diffractometry of $Mn_{0.6}Ni_{0.4}Fe_2O_4$ ferrite sintered above 523 K indicated a spinel structure; particles increased in size with hotter sintering. The M$\ddot{o}$ssbauer spectrum of this ferrite sintered at 523 K could be fitted as a single quadrupole doublet, indicative of a superparamagnetic phase. Sintering at 573 K led to spectrum fitted as the superposition of two Zeeman sextets and a single quadrupole doublet, indicating both ferrimagnetic and paramagnetic phase. Sintering at 673 K and at 773 K led to spectra fitted as two Zeeman sextets due to a ferrimagnetic phase. The saturation magnetization and the coercivity of $Mn_{0.6}Ni_{0.4}Fe_2O_4$ ferrite sintered at 773 K were 53.05 emu/g and 142.08 Oe. In $Mn_{1-x}Ni_xFe_2O_4$ ($0.0{\leq}x{\leq}0.6$) ferrites, sintering of any composition at 773 K led to a single spinel structure. Increased Ni substitution decreased the ferrites' lattice constants and increased their particle sizes. The M$\ddot{o}$ssbauer spectra could be fitted as the superposition of two Zeeman sextets due to the tetrahedral and the octahedral sites of the $Fe^{3+}$ ions. The variations of saturation magnetization and coercivity with changing Ni content could be explained using the changes of particle size.

Core loss Calculation of a Permanent Magnetic Motor Considering Mechanical Stress (영구자석 전동기 철심의 기계적 응력을 고려한 철손 해석)

  • Kim, Ji-Hyun;Ha, Kyung-Ho;Kwon, Oh-Yeoul;Kim, Jae-Kwan;La, Min-Soo;Lee, Sun-Kwon
    • Proceedings of the KIEE Conference
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    • 2009.07a
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    • pp.851_852
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    • 2009
  • Shrink fitting which is assembling process to fix stator core on the motor frame is widely used at the mass production line of motors because of cost and productivity. This process produces compressive stress on a stator core, which causes negative effect for example, core and copper losses on motor performance. Magnetic properties of electrical steel are effected by both compressive and tensile and thermal stresses. Electromagnetic field analysis is considered one of the effective process since one can predict motor performance including core loss precisely. This method can consider non linear magnetic property with magnetic saturation which is typical electrical steel behavior. However this method is strongly depended on non linear magnetic data, one may have different calculation result whether considering mechanical stress or not. This study describes magnetic field analysis of a motor considering mechanical stress from shrink fitting. Analysis results are compared with each stress-free and stressed condition.

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Permeability of CoZrNb film with thickness (CoZrNb막의 두께에 따른 투자율의 변화)

  • Hoe, J.;Kim, Y.H.;Shin, K.H.;Sa-Gong, G.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.443-446
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    • 2001
  • MI(Magneto-Impedance) sensor which is made by thin films has significantly high detecting sensitivity in weak magnetic field. It also has a merit to be able to build in low power system. Its structure is simple, which makes it easier to prepare a miniature. In this study, its magnetic permeability and anisotropy field(H$\sub$k/) as a function of a thickness of sputtered amorphous CoZrNb thin film with high saturation magnetostriction and excellent soft magnetic property are investigated. In order to make a uniaxial anisotropy, thin film was subjected to post annealing with a static magnetic field with 1KOe intensity at 250, 300, and 320$^{\circ}C$ for 2 hour. Anisotropy field(H$\sub$k/)of thin film is measured by using MH loop tracer. Its magnetic permeability of thin film is measured over the frequency range from 1 MHz to 750MHz. It has shown that the magnetic permeability of amorphous CoZrNb thin film is decreased due to the skin effect with increasing a thickness of CoZrNb thin film, and hence its driving frequency is lowered.

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Degradation of Soft Magnetic Properties of Fe-Hf-N/Cr/SiO2 Thin Films Reacted with Bonding Glass (접합유리와 반응된 Fe-Hf-N/Cr/SiO2 박막의 연자기 특성 열화)

  • Je Hae-June;Kim Byung-Kook
    • Korean Journal of Materials Research
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    • v.14 no.11
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    • pp.780-785
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    • 2004
  • The degradation mechanism of soft magnetic properties of $Fe-Hf-N/Cr/SiO_2$ thin films reacted with a bonding glass was investigated. When $Fe-Hf-N/Cr/SiO_2$ films were annealed under $600^{\circ}C$ without the bonding glass, the compositions and the soft magnetic properties of Fe-Hf-N layers were not changed. However, after reaction with the bonding glass at $550^{\circ}C$, the soft magnetic properties of the film were degraded. At $600^{\circ}C$, the saturation magnetization of the reacted film decreased to 13.5 kG, and its coercivity increased to 4 Oe, and its effective permeability decreased to 700. It was founded that O diffused from the glass into the Fe-Hf-N layers during the reaction and generated $HfO_2$ phases. It was considered that the soft magnetic properties of the $Fe-Hf-N/Cr/SiO_2$ films reacted with the bonding glass were primarily degraded by the formation of the Fe-Hf-O-N layer of which the Fe content was below 60 $at\%$, and secondarily degraded by the Fe-Hf-O-N layer above 70 $at\%$.

Analysis for Magnetic field generated in the Flux-Lock Type Reactor using HTSC during a fault time (고온초전도체를 이용한 자속구속 리액터의 사고시 발생되는 자계 분석)

  • Lim, Sung-Hun;Choi, Hyo-Sang;Kang, Hyeong-Gon;Ko, Seok-Cheol;Lee, Jong-Hwa;Choi, Myung-Ho;Song, Jae-Joo;Han, Byoung-Sung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07a
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    • pp.601-604
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    • 2003
  • The magnetic field generated in the iron core, which is required for the magnetic field to link each coil of the flux-lock type reactor, affects the fault current limiting characteristics of the flux-lock type high-Tc superconducting fault current limiter(SFCL). By applying numerical analysis for equivalent circuit of flux-lock type SFCL, the magnetic field induced in the iron core including currents of each coil was investigated. Through the analysis of magnetic field, we have analyzed that the magnetic field linked the 3rd coil, which is wound in the iron core, prevents the saturation of the iron core, but decreases the impedance of the flux-lock type SFCL.

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Composition and magnetic ProPerties of CoFecu alloys according to electrolysis conditions (전해조건에 따른 CoFeCu 함금박막의 조성, 우선방위 및 자기적 특성)

  • 예길촌
    • Journal of the Korean institute of surface engineering
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    • v.30 no.1
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    • pp.3-12
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    • 1997
  • The composition, the preferred orientation and the magnetic properties of the CoFeCu alloys electrodepositen under various electrolysis conditions in sulfate baths ware investigated. As the D.C. current density increased, the Co content in alloy electrodeposits increased, while the Cu content decreased and Fe content remained content. The effect of magnetic field up to 300 Oe on the composition of alloys was negligible. The Cu content of the alloys deposited in pulse current increased noticeably with increasing off-time, while the Co and Fe content decreased. The coercivity of the alloys with 3.5 to 7.0wt.% Cu was 1.0 to 2.0 Oe, but increased noticeably above and below that composition. The application of magnetic field during deposition decreased the coercivity of alloys. The saturation flux density of the alloys with 3.5 to 5.0wt.% Cu was relatively high in the range from 16 to 20.7Gauss. The anisotropy field(HK) of the alloys deposited under the magnetic field(50∼300 Oe) ranged from 18 to 22 Oe. The alloys had fcc structure with (111) preferred orientation, whose distribution increased a little with increasing magnetic field.

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Properties of Fe-based Soft magnetic Thin Film with Hybrid Structures (Hybrid 구조의 Fe계 연자성 박막의 특성)

  • 송재성;이원재;허정섭;김현식;오영우
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.11
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    • pp.963-968
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    • 2000
  • Magnetic properties and microstructures of Fe$\_$93-x/Zr$_3$B$_4$Ag$\_$x/ thin films were investigated as a function of addition of element Ag, (X$\_$Ag/=0 to 6 at.%) and annealing temperature, T$\_$a/=300$\^{C}$ to 600$\^{C}$. In the case of adding Ag, magnetic properties of Fe$\_$93-x/Zr$_3$B$_4$Ag$\_$x/ thin films were improved than those of Ag-free Fe$\_$93/Zr$_3$B$_4$thin films. The prominent soft magnetic properties with coercivity of 1.1 Oe, saturation magnetization of 2.2 T and permeability of 5400 at 50㎒ were obtained from Fe$\_$88/Zr$_3$B$_4$Ag$\_$5/ thin film annealed was lower than that of Fe-base or Co-base thin films reported previously. Such enhanced magnetic properties are presumably attributed to the format in ultra fine grains. Also, the reduced eddy current loss in the annealed sample is due to refined micro magnetic domains with increasing the amount of Ag in Fe$\_$93-x/Zr$_3$B$_4$Ag$\_$x/ thin films.

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Effects of B Addition and Heat Treatment on the Magnetic and Magnetostrictive Properties of Amorphous $SmEe_2$ thin Films (비정질 $SmFe_2 $합금의 자기적 및 자기변형 특성에 미치는 B 첨가와 열처리 영향)

  • Choi, K.G.;Jang, Ho;Han, S.H.;Kim, H.J.;Lim, S.H.
    • Journal of the Korean Magnetics Society
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    • v.10 no.5
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    • pp.237-245
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    • 2000
  • Effects of B addition and heat treatment on the magnetic and magnetostrictive properties of amorphous SmFe$_2$ thin films are investigated. A significant improvement in the magnetostrictive properties at low magnetic fields is observed with the addition of B. This improvement, however, is achieved at a heavy cost of intrinsic properties such as saturation magnetostriction. For example, at a magnetic field of 30 Oe, magnetostriction of a thin film with a B content of 9.9 at.% is increased from 190 to 333 ppm, but saturation magnetostriction is decreased by more than 50 %. This result is in accord with the deterioration (reduction) of saturation magnetization and the improvement (reduction) of coercive force at this B content. The magnetostrictive properties are also improved by annealing and optimum annealing temperature is found to be in the range 300-400 $^{\circ}C$. The main reason for the improvement is mainly considered to be due to the reduction of coercive force caused by stress relief, not due to the ultrafine SmFe$_2$ precipitates which were originally expected to form by annealing.

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The clinical usefulness of fat suppression by chemical shift selective(CHESS) pulse in MRI (MRI에서 화학적 이동 선택(CHESS) pulse에 의한 지방소거의 임상적 유용성)

  • Han, Man-Seok;Yang, Hae-Sool;Jin, Kyung-Soo;Eo, Ik-Soo;Cho, Dong-Heon
    • The KIPS Transactions:PartB
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    • v.14B no.6
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    • pp.431-436
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    • 2007
  • Magnetic Resonance Imaging(MRI) has chemical shift phenomenon between fat and water, and the phenomenon has influence on structure enclosed by fat. Strong signals emitted from fat often generate false artefact, which reflects the importance of fat suppression techniques. There have been a number of researches on fat suppression techniques, but using fat suppression method alone in MRI can cause difficultproblems in diagnosis. This paper aims to study a fat suppression method by Chemical Shift Selective saturation(CHESS). This research describes the theoretical background and the experiment on water and fat phantom with MR instruments. In the experiment, CHESS pulse was designed by utilising Matlap program, and the pulse diagram was generated for the Pre-saturation process. The experiment using water and fat phantom was applied to C-spine, L-spine and Breast, and produced successful fat suppression results. This experiment has proved that the CHESSpulse fat suppression is a very helpful technique in diagnosing medical imaging. This method is a robust and useful technique for both clinical and basic investigators..(Experiment with Chungnam national university hospital G.E 1.5T MR)

Ferromagnetism of thin films deposited from paramagnetic stainless steel targets by Facing Targets Sputtering

  • Matsushita, N.;Ono, N.;Naoe, M.
    • Proceedings of the Korean Magnestics Society Conference
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    • 1991.05a
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    • pp.73-74
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    • 1991
  • The films with ferromagnetic fine particles dispersed in nonmagnetic matrix, such as $Fe-Al_2O_3$ and Fe-Cu have been studied for use of magnetic recording medium, optically device and sensor. Their magnetic properties depend strongly on structural parameter such as size and volume fraction of ferromagnetic particles. Fe-Cr-Ni alloy sputtered films also have microstructure with ferromagnetic -- b.c.c phase and nonmagnetic f.c.c phase grains. Magnetic properties of these films depend strongly on such a unique structure. These are depend on the ratio in volume of ferromagnetic particles to nonmagnetic ones $V_F/V_N$, the saturation magnetization Ms increased with increase of $V_F/V_N$. The coercivity Hc of the as-deposited films took maximum value of about 200 Oe at adequate $V_F/V_N$ and then Ms and Squareness S were 500 emu/cc and 0.5, respectively.(omitted)

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