• Title/Summary/Keyword: Magnesium reduction

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EFFECT OF MAGNESIUM OXIDE CONTENTS ON THE PROPERTIES OF EXPERIMENTAL ALGINATES (산화마그네슘 함량이 실험적 알지네이트 인상재의 특성에 미치는 영향)

  • Bae Ill-Hwan;Woo Yi-Hyung;Choi Dae-Gyun
    • The Journal of Korean Academy of Prosthodontics
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    • v.41 no.5
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    • pp.551-564
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    • 2003
  • Statement of problem : Magnesium oxide may increase pH of alginate, and supply magnesium ions to the polymerization reaction of alginate. Purpose : This study was designed to evaluate the influence of incorporation of magnesium oxide to alginate composition. Material and Method : Seven kinds of experimental alginates were prepared and used for the experiments. Components with unchanging concentrations were sodium alginate 15%, calcium sulfate 14%, sodium phosphate 2%, and zinc fluoride 3%. Contents of magnesium oxide were varied as 0%, 1%, 2%, 3%, 4%, 5%, 6%. Diatomaceous earth were added to each experimental groups as balance to be 100%. Control group was a MgO 0% group. Working time, setting time, elastic recovery strain in compression, compressive strength and tear resistance were measured were measured. Sample size for each groups were 10. Arithmetic means were used as each groups representative values. Regression test between MgO contents and results, Duncan's multiple range test, and One-way ANOVA test were done between groups at level of 0.05. Results : 1 Magnesium oxide made the working time and setting time as longer(p<0.0001). 2 Magnesium oxide did not alter the elastic recovery(p>0.05). 3. Magnesium oxide contents between 2% and 4% exhibited the lowest strain in compression on alginates(p<0.0001). 4. Magnesium oxide made the compressive strength and the tear resistance stronger(p<0.0001). Conclusion : These results mean that setting time of alginate maybe controlled and that mechanical properties maybe improved by the incorporation of magnesium oxide into alginate, without any reduction of elasticity.

Intravenous Magnesium Infusion for the Prevention of Symptomatic Cerebral Vasospasm after Aneurysmal Subarachnoid Hemorrhage

  • Jeon, Jin-Sue;Sheen, Seung-Hun;Hwang, Gyo-Jun;Kang, Suk-Hyung;Heo, Dong-Hwa;Cho, Yong-Jun
    • Journal of Korean Neurosurgical Society
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    • v.52 no.2
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    • pp.75-79
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    • 2012
  • Objective : The study examined the difference in the incidence of symptomatic cerebral vasospasm with magnesium supplementation in aneurysmal subarachnoid hemorrhage (SAH) in a Korean population. Methods : This retrospective analysis was performed in 157 patients diagnosed with aneurysmal SAH from January 2007 to December 2011 at a single center. Seventy patients (44.6%) received a combination treatment of nimodipine with magnesium and 87 patients (55.4%) received only nimodipine. A matched case-control study using propensity scores was conducted and 41 subjects were selected from each group. A dosage of 64 mmol/day of magnesium was administrated. Results : The infusion of magnesium did not reduce the incidence of symptomatic cerebral vasospasm (n=7, 17.1%, p=0.29) compared with simple nimodipine injection (n=11, 26.8%). The ratios of good clinical outcome (modified Rankin scale 0-2) at 6 months were similar, being 78% in the combination treatment group and 80.5% in the nimodipine only group (p=0.79). The proportions of delayed cerebral infarction was not significantly lower in patients with combination treatment (n=2, 4.9% vs. n=3, 7.3%; p=0.64). There was no difference in the serum magnesium concentrations between the patients with symptomatic vasospasm and without vasospasm who had magnesium supplementation. No major complications associated with intravenous magnesium infusion were observed. Conclusion : Magnesium supplementation (64 mmol/day) may not be beneficial for the reduction of the incidence of symptomatic cerebral vasospasm in patients with aneurysmal SAH.

Magnesium Sulfate Induced Toxicity in Vitro in AGS Gastric Adenocarcinoma Cells and in Vivo in Mouse Gastric Mucosa

  • Zhang, Xulong;Bo, Agula;Chi, Baofeng;Xia, Yuan;Su, Xiong;Sun, Juan
    • Asian Pacific Journal of Cancer Prevention
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    • v.16 no.1
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    • pp.71-76
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    • 2015
  • Magnesium sulfate is widely used as a food additive and as an orally administered medication. The aim of this study was to evaluate the possible cytotoxicity of magnesium sulfate on AGS human gastric adenocarcinoma cells and gastric mucosa in mice. A trypan blue exclusion assay was used to determine the reduction in viability of AGS cells exposed to magnesium sulfate, and then effects on cell proliferation were quantified. The role of magnesium sulfate-mediated pro-inflammatory cytokine production in AGS cells was also investigated. mRNA expression for IL-$1{\beta}$, IL-6, IL-8, and TNF-${\alpha}$ was determined by RT-PCR, and secretion of these cytokines was measured by ELISA. Immunohistochemical evaluation of IL-$1{\beta}$, IL-6, and TNF-${\alpha}$ expression was conducted in mouse gastric mucosa. Addition of 3 to 50 mM magnesium sulfate to AGS cells inhibited both cell proliferation and cell viability in a dose-dependent manner. Magnesium sulfate had little effect on production of IL-$1{\beta}$ or IL-6 but significantly inhibited production of IL-8. The animal model demonstrated that magnesium sulfate induced production of IL-$1{\beta}$, IL-6, and TNF-${\alpha}$. These preliminary data suggest that magnesium sulfate had a direct effect on the stomach and initiates cytotoxicity in moderate concentrations and time periods by inhibiting viability a nd proliferation of AGS cells and by regulating expression and/or release of pro-inflammatory cytokines.

PLASTICITY-BASED WELDING DISTORTION ANALYSIS OF THIN PLATE CONNECTIONS

  • Jung, Gonghyun;Tsai, Chon L.
    • Proceedings of the KWS Conference
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    • 2002.10a
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    • pp.694-699
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    • 2002
  • In autobody assembly, thin-wall, tubular connections have been used for the frame structure. Recent interest in light materials, such as aluminum or magnesium alloys, has been rapidly growing for weight reduction and fuel efficiency. Due to higher thermal expansion coefficient, low stiffness/strength, and low softening temperature of aluminum and magnesium alloys, control of welding-induced distortion in these connections becomes a critical issue. In this study, the material sensitivity to welding distortion was investigated using a T-tubular connection of three types materials; low carbon steel (A500 Gr. A), aluminum alloy (5456-H116) and magnesium alloy (AZ91C-T6). An uncoupled thermal and mechanical finite element analysis scheme using the ABAQUS software program was developed to model and simulate the welding process, welding procedure and material behaviors. The predicted angular distortions were correlated to the cumulative plastic strains. A unique relationship between distortion and plastic strains exists for all three materials studied. The amount of distortion is proportional to the magnitude and distribution of the cumulative plastic strains in the weldment. The magnesium alloy has the highest distortion sensitivity, followed by the other two materials with the steel connection having the least distortion. Results from studies of thin-aluminum plates show that welding distortion can be minimized by reducing the cumulative plastic strains by preventing heat diffusion into the base metal using a strong heat sink placed directly beneath the weld. A rapid cooling method is recommended to reduce welding distortion of magnesium tubular connections.

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Effect of Strain Rate on Microstructure Formation Behavior of M1 Magnesium Alloy During High-temperature Deformation (변형속도에 따른 M1 마그네슘 합금의 고온변형 중 미세조직 형성 거동)

  • Lee, Kyujung;Kim, Kwonhoo
    • Journal of the Korean Society for Heat Treatment
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    • v.32 no.1
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    • pp.1-11
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    • 2019
  • In this study, microstructure evolution and crystallographic orientation are investigated under various deformation conditions in M1 magnesium alloy. M1 magnesium ingot was rolled at 673 K with the rolling reduction of 30%. The compression test specimens were machined out from rolled plate, and then the specimens were annealed at 823 K for 1h. Uniaxial compression tests were conducted at 723 K and under the strain rate ranging from $5.0{\times}10^{-4}s^{-1}$ to $5.0{\times}10^{-2}s^{-1}$ up to a true strain of -1.0. For observation of crystal orientation distribution, EBSD measurement was performed. Occurrence of the dynamic recrystallization and grain boundary migration were confirmed in all case of the specimens. The distribution of the grains is not uniformed in the experimental conditions.

A Study on Synthetic Method and Material Characteristics of Magnesium Ammine Chloride as Ammonia Transport Materials for Solid SCR (Solid SCR용 암모니아 저장물질인 Magnesium Ammine Chloride의 합성방법 및 물질특성 연구)

  • Shin, Jong Kook;Yoon, Cheon Seog;Kim, Hongsuk
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.39 no.11
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    • pp.843-851
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    • 2015
  • Among various ammonium salts and metal ammine chlorides used as solid materials for the sources of ammonia with solid SCR for lean NOx reduction, magnesium ammine chloride was taken up for study in this paper because of its ease of handling and safety. Lab-scale synthetic method of magnesium ammine chloride were studied for different durations, temperatures, and pressures with proper ammonia gas charged, as a respect of ammonia gas adsorption rate(%). To understand material characteristics for lab-made magnesium ammine chloride, DA, IC, FT-IR, XRD and SDT analyses were performed using the published data available in literature. From the analytical results, the water content in the lab-made magnesium ammine chloride can be determined. A new test procedure for water removal was proposed, by which the adsorption rate of lab-made sample was found to be approximately 100%.

Comparison of Two-Types Compositions of Mixed Salts in Fused Salt Electrolysis of Magnesium (마그네슘의 용융염전해시(熔融鹽電解時) 두 가지 염욕조성(鹽浴組成)의 비교실험)

  • Park, Hyung-Kyu;Park, Jin-Tae;Choi, Young-Yoon
    • Resources Recycling
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    • v.15 no.2 s.70
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    • pp.32-36
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    • 2006
  • Magnesium has been used as light and functional material, and its demand is increasing as a material for automobile engine and for mobile phone or notebook PC case. Fused salt electrolysis and thermal reduction are regarded as main methods for the extraction of magnesium, and choice for the method is firstly according to raw material. In this study, magnesium metal is obtained by an electrolysis of magnesium chloride. Two types of fused salt mixtures were used as electrolyte and electrolyzed at 7V with a graphite anode having the same depth, and their results were compared with each other. A mixed salt of $KCl/NaCl/MgCl_2$ was the more effective than $KCl/NaCl/CaCl_2/CaF_2/MgCl_2$ in current efficiency through the experiments at $760^{\circ}C$. Purity of the prepared magnesium metal was above 98%. Some basic data for scale-up of the magnesium electrolysis equipment, which would be necessary for a commercialization, could be obtained.

A Study on Flow Forming Process of Magnesium Road Wheel (마그네슘 로드 휠의 유동성형 가공에 관한 연구)

  • Kim, J.H.;Park, S.M.;Lee, J.J.;Yoon, H.S.
    • Transactions of Materials Processing
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    • v.23 no.2
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    • pp.116-121
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    • 2014
  • Low pressure die casting and flow forming have been successfully used to produce sound road wheels from magnesium alloy AM80. In the current study, high speed compression testing was initially conducted to simulate the flow forming of a Mg wheel. Subsequently the flow forming was simulated with "Forge$^{TM}$", an FEM software package. On the basis of flow forming simulations, the flow forming of the Mg wheel was performed under different conditions. For the flow forming experiments, the preform castings were made by low pressure die casting from AM80, a commercial magnesium alloy. In flow forming of the magnesium preform wheel, the flow forming of the Mg wheel was successfully accomplished when the feed rate was less than half that for the forming of an aluminum road wheel. The reduction in feed rate was 52%. Finally, a comparison with the flow forming simulations was made.

A Study on the Enhancement of Corrosion Resistance of Magnesium Alloy by Dry Plasma Process (건식플라즈마 표면처리법에 의한 마그네슘 합금의 내식특성 향상)

  • Yun, Yang-Sup
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.17 no.2
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    • pp.155-160
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    • 2011
  • In these days, there are increasing demands for weight reduction in many industrial fields including marine industries. Therefore, magnesium thin films for lightweight materials were prepared on magnesium alloy substrate. The influence of gas pressure and substrate bias voltages on the crystal orientation and morphology of the films was determined by using X-ray diffraction and FE-SEM, respectively. And the effect of crystal orientation and morphology of the magnesium thin films on corrosion behavior was estimated by measuring electro-chemical anodic polarization curves in deaerated 3% NaCl solution. From the results, corrosion resistance of Mg thin films was improved by controlling the crystal orientation and morphology of the films with effective use of plasma ion plating technique.